Unexpected Formation of NHC-Stabilized Hydrosilylyne Complexes via Alkane Elimination from NHC-Stabilized Hydrido(alkylsilylene) Complexes

2015 ◽  
Vol 137 (34) ◽  
pp. 10906-10909 ◽  
Author(s):  
Tetsuya Fukuda ◽  
Hisako Hashimoto ◽  
Hiromi Tobita
Keyword(s):  
Unexpected Formation ◽  
Alkane Elimination

scholarly journals Synthesis and Characterisation of Molecular Polarised-Covalent Thorium-Rhenium and -Ruthenium Bonds

Inorganics ◽  
2021 ◽  
Vol 9 (5) ◽  
pp. 30
Author(s):  
Joseph P. A. Ostrowski ◽  
Ashley J. Wooles ◽  
Stephen T. Liddle
Keyword(s):  
Quantum Chemical Calculations ◽  
Quantum Chemical ◽  
Spectroscopic Data ◽  
Raman Spectroscopic ◽  
Ir And Raman ◽  
Alkane Elimination

Separate reactions of [Th{N(CH2CH2NSiMe2But)2(CH2CH2NSi(Me)(But)(μ-CH2)]2 (1) with [Re(η5-C5H5)2(H)] (2) or [Ru(η5-C5H5)(H)(CO)2] (3) produced, by alkane elimination, [Th(TrenDMBS)Re(η5-C5H5)2] (ThRe, TrenDMBS = {N(CH2CH2NSiMe2But)3}3-), and [Th(TrenDMBS)Ru(η5-C5H5)(CO)2] (ThRu), which were isolated in crystalline yields of 71% and 62%, respectively. Complex ThRe is the first example of a molecular Th-Re bond to be structurally characterised, and ThRu is only the second example of a structurally authenticated Th-Ru bond. By comparison to isostructural U-analogues, quantum chemical calculations, which are validated by IR and Raman spectroscopic data, suggest that the Th-Re and Th-Ru bonds reported here are more ionic than the corresponding U-Re and U-Ru bonds.

scholarly journals Effect of strain-induced anisotropy on magnetization dynamics in Y3Fe5O12 films recrystallized on a lattice-mismatched substrate

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Adam Krysztofik ◽  
Sevgi Özoğlu ◽  
Robert D. McMichael ◽  
Emerson Coy
Keyword(s):  
Dispersion Model ◽  
Perpendicular Magnetic Anisotropy ◽  
Negative Slope ◽  
Recrystallization Process ◽  
Induced Anisotropy ◽  
Magnetization Dynamics ◽  
Unexpected Formation ◽  
Lattice Matched ◽  
Ferromagnetic Resonance Linewidth ◽  
Lattice Mismatched Substrate

AbstractWe report on the correlation of structural and magnetic properties of Y3Fe5O12 (YIG) films deposited on Y3Al5O12 substrates using pulsed laser deposition. The recrystallization process leads to an unexpected formation of interfacial tensile strain and consequently strain-induced anisotropy contributing to the perpendicular magnetic anisotropy. The ferromagnetic resonance linewidth of YIG is significantly increased in comparison to a film on a lattice-matched Gd3Ga5O12 substrate. Notably, the linewidth dependency on frequency has a negative slope. The linewidth behavior is explained with the proposed anisotropy dispersion model.

Unexpected formation of root‐like structures subsequent to the avulsion of immature permanent teeth: Case report

2021 ◽  
Author(s):  
Giselle Emilãine da Silva Reis ◽  
Juliana Feltrin de Souza ◽  
Denis Emílio Nascimento Santos ◽  
José Vitor Nogara Borges de Menezes ◽  
Fabian Calixto Fraiz ◽  
...  
Keyword(s):  
Case Report ◽  
Permanent Teeth ◽  
Unexpected Formation

scholarly journals Unexpected Formation of 1,2- and 1,4-Bismethoxyl Sc3N@Ih-C80 Derivatives via Regioselective Anion Addition: Unambiguous Structural Identification and Mechanism Study

2021 ◽  
Author(s):  
Yajing Hu ◽  
Yang-Rong Yao ◽  
Xuechen Liu ◽  
Ao Yu ◽  
Xiao-Ming Xie ◽  
...  
Keyword(s):  
Structural Identification ◽  
Mechanism Study ◽  
Tetrabutylammonium Hydroxide ◽  
Unexpected Formation

An attempt to achieve heterocyclic cycloadducts of Sc3N@Ih-C80 via the reaction with Ph2C=O, PhC≡CPh or PhC≡N in the presence of tetrabutylammonium hydroxide (TBAOH) stored in CH3OH led to the formation...

The unexpected formation of a lithium-enolate from bis2-[(dimethylamino)methyl]phenyl copper lithium. X-ray structure of Li4[OC(CH2)C6H4CH2NMe2-2]4

1985 ◽  
Vol 292 (3) ◽  
pp. 319-324 ◽  
Author(s):  
Johann T.B.H. Jastrzebski ◽  
Gerard Van Koten ◽  
Martin J.N. Christophersen ◽  
Casper H. Stam
Keyword(s):  
Unexpected Formation ◽  
X Ray ◽  
Lithium Enolate ◽  
Methyl Phenyl

Unexpected formation of derivatives of cyclobutene and thiacyclobutane from the reaction between dilithiated benzylacetylene and isothiocyanates

2001 ◽  
Vol 42 (28) ◽  
pp. 4687-4689 ◽  
Author(s):  
Lambert Brandsma ◽  
Anthony L Spek ◽  
Boris A Trofimov ◽  
Ol'ga A Tarasova ◽  
Nina A Nedolya ◽  
...  
Keyword(s):  
Unexpected Formation ◽  
Derivatives Of
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