Scope and Mechanistic Analysis for Chemoselective Hydrogenolysis of Carbonyl Compounds Catalyzed by a Cationic Ruthenium Hydride Complex with a Tunable Phenol Ligand

Nishantha Kalutharage; Chae S. Yi

doi:10.1021/jacs.5b06097

Scope and Mechanistic Analysis for Chemoselective Hydrogenolysis of Carbonyl Compounds Catalyzed by a Cationic Ruthenium Hydride Complex with a Tunable Phenol Ligand

Journal of the American Chemical Society ◽

10.1021/jacs.5b06097 ◽

2015 ◽

Vol 137 (34) ◽

pp. 11105-11114 ◽

Cited By ~ 35

Author(s):

Nishantha Kalutharage ◽

Chae S. Yi

Keyword(s):

Carbonyl Compounds ◽

Ruthenium Hydride ◽

Hydride Complex ◽

Mechanistic Analysis

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A substrate-dependent mechanism for the reactions of a hydrido(hydrosilylene)ruthenium complex with carbonyl compounds: insights from quantum chemical calculations

New Journal of Chemistry ◽

10.1039/c6nj02361d ◽

2017 ◽

Vol 41 (1) ◽

pp. 198-203

Author(s):

Jian Kuang ◽

Yang Li ◽

Lihong Wang ◽

Zunyi Wu ◽

Qunfang Lei ◽

...

Keyword(s):

Quantum Chemical Calculations ◽

Carbonyl Compounds ◽

Quantum Chemical ◽

Ruthenium Complex ◽

Hydride Complex ◽

Dependent Mechanism

The reactivity difference between ketones and aldehydes towards the ruthenium silylene hydride complex is dependent on the substituents of the carbonyl substrates.

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Efficient Dehydrogenation of Amines and Carbonyl Compounds Catalyzed by a Tetranuclear Ruthenium-μ-oxo-μ-hydroxo-hydride Complex

Organometallics ◽

10.1021/om8010883 ◽

2009 ◽

Vol 28 (4) ◽

pp. 947-949 ◽

Cited By ~ 82

Author(s):

Chae S. Yi ◽

Do W. Lee

Keyword(s):

Carbonyl Compounds ◽

Hydride Complex

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Ruthenium-mediated selective head-to-tail dimerization of acrylic and α,β-unsaturated carbonyl compounds: generation of an acrylate-hydride complex C5Me5Ru(PCy3)(CH2CHCO2Et)H

Journal of Organometallic Chemistry ◽

10.1016/s0022-328x(97)00591-3 ◽

1998 ◽

Vol 553 (1-2) ◽

pp. 157-161 ◽

Cited By ~ 8

Author(s):

Chae S Yi ◽

Nianhong Liu

Keyword(s):

Carbonyl Compounds ◽

Hydride Complex

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Intermolecular Coupling Reaction of Cyclic Amines and Alkenes Catalyzed by a Ruthenium-Hydride Complex (PCy3)2(CO)RuHCl

Organometallics ◽

10.1021/om0401206 ◽

2004 ◽

Vol 23 (23) ◽

pp. 5392-5395 ◽

Cited By ~ 47

Author(s):

Chae S. Yi ◽

Sang Young Yun ◽

Ilia A. Guzei

Keyword(s):

Coupling Reaction ◽

Ruthenium Hydride ◽

Hydride Complex ◽

Cyclic Amines ◽

Intermolecular Coupling

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ChemInform Abstract: Hydrovinylation of Alkenes Catalyzed by the Ruthenium-Hydride Complex Formed in situ from (PCy3)2(CO)RuHCl and HBF4×OEt2.

ChemInform ◽

10.1002/chin.200124077 ◽

2010 ◽

Vol 32 (24) ◽

pp. no-no

Author(s):

Chae S. Yi ◽

Zhengjie He ◽

Do W. Lee

Keyword(s):

Ruthenium Hydride ◽

Hydride Complex

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Chain-Selective and Regioselective Ethylene and Styrene Dimerization Reactions Catalyzed by a Well-Defined Cationic Ruthenium Hydride Complex: New Insights on the Styrene Dimerization Mechanism

Organometallics ◽

10.1021/om100468q ◽

2010 ◽

Vol 29 (15) ◽

pp. 3413-3417 ◽

Cited By ~ 27

Author(s):

Do W. Lee ◽

Chae S. Yi

Keyword(s):

Ruthenium Hydride ◽

Hydride Complex

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Regioselective Intermolecular Coupling Reaction of Arylketones and Alkenes Involving C−H Bond Activation Catalyzed by anin SituFormed Cationic Ruthenium Hydride Complex

Organometallics ◽

10.1021/om900416k ◽

2009 ◽

Vol 28 (15) ◽

pp. 4266-4268 ◽

Cited By ~ 34

Author(s):

Chae S. Yi ◽

Do W. Lee

Keyword(s):

Bond Activation ◽

Coupling Reaction ◽

Ruthenium Hydride ◽

Hydride Complex ◽

Intermolecular Coupling

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Ruthenium Hydride Complex Supported on Gold Nanoparticle Cored Triazine Dendrimers for C–C Coupling Reactions

Organometallics ◽

10.1021/acs.organomet.6b00163 ◽

2016 ◽

Vol 35 (11) ◽

pp. 1747-1755 ◽

Cited By ~ 12

Author(s):

Anahita Daneshvar ◽

Majid Moghadam ◽

Shahram Tangestaninejad ◽

Valiollah Mirkhani ◽

Iraj Mohammadpoor-Baltork ◽

...

Keyword(s):

Gold Nanoparticle ◽

Coupling Reactions ◽

Ruthenium Hydride ◽

Hydride Complex

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Mechanism of co-dimerization of vinylboronates with terminal alkynes catalyzed by ruthenium-hydride complex

Journal of Molecular Catalysis A Chemical ◽

10.1016/j.molcata.2014.09.040 ◽

2015 ◽

Vol 396 ◽

pp. 239-244 ◽

Cited By ~ 5

Author(s):

Jadwiga Pyziak ◽

Jędrzej Walkowiak ◽

Marcin Hoffmann ◽

Bogdan Marciniec

Keyword(s):

Terminal Alkynes ◽

Ruthenium Hydride ◽

Hydride Complex

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Hydrogen Bonding and Proton Transfer to Ruthenium Hydride Complex CpRuH(dppe): Metal and Hydride Dichotomy

Inorganic Chemistry ◽

10.1021/ic301585k ◽

2013 ◽

Vol 52 (4) ◽

pp. 1787-1797 ◽

Cited By ~ 17

Author(s):

Gleb A. Silantyev ◽

Oleg A. Filippov ◽

Peter M. Tolstoy ◽

Natalia V. Belkova ◽

Lina M. Epstein ◽

...

Keyword(s):

Hydrogen Bonding ◽

Proton Transfer ◽

Ruthenium Hydride ◽

Hydride Complex

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