Visible Light Driven Nanosecond Bromide Oxidation by a Ru Complex with Subsequent Br–Br Bond Formation

2015 ◽  
Vol 137 (26) ◽  
pp. 8321-8323 ◽  
Author(s):  
Guocan Li ◽  
William M. Ward ◽  
Gerald J. Meyer
Keyword(s):  
Visible Light ◽  
Bond Formation ◽  
Ru Complex ◽  
Visible Light Driven

Visible Light-Driven Photoenergy Storage and Photocatalysis Using Polyoxometallates Coupled with a Ru Complex

2017 ◽  
Vol 121 (25) ◽  
pp. 13515-13523 ◽  
Author(s):  
Kota Kumamoto ◽  
Kenta Tsuchibashi ◽  
Azzah Dyah Pramata ◽  
Masayoshi Yuasa ◽  
Kengo Shimanoe ◽  
...  
Keyword(s):  
Visible Light ◽  
Ru Complex ◽  
Visible Light Driven

Visible light-driven cross-coupling reactions of alkyl halides with phenylacetylene derivatives for C(sp3)–C(sp) bond formation catalyzed by a B12 complex

2019 ◽  
Vol 55 (87) ◽  
pp. 13070-13073 ◽  
Author(s):  
Li Chen ◽  
Yohei Kametani ◽  
Kenji Imamura ◽  
Tsukasa Abe ◽  
Yoshihito Shiota ◽  
...  
Keyword(s):  
Visible Light ◽  
Room Temperature ◽  
Bond Formation ◽  
Cross Coupling ◽  
Alkyl Halides ◽  
Coupling Reactions ◽  
Cross Coupling Reactions ◽  
Visible Light Driven

Visible light-driven cross-coupling reactions of alkyl halides with phenylacetylene and its derivatives catalyzed by the cobalamin derivative (B12) with the [Ir(dtbbpy)(ppy)2]PF6 photocatalyst at room temperature are reported.

Catalyst-free and additive-free reactions enabling C–C bond formation: a journey towards a sustainable future

2021 ◽  
Vol 19 (6) ◽  
pp. 1191-1229
Author(s):  
Biswajita Baruah ◽  
Mohit L. Deb
Keyword(s):  
Visible Light ◽  
Bond Formation ◽  
Coupling Reactions ◽  
Catalyst Free ◽  
Sustainable Future ◽  
Visible Light Driven ◽  
Uv Visible

Construction of C–C bonds in the absence of a catalyst and an additive by means of various name reactions including C–H functionalizations, coupling reactions and UV-visible-light-driven reactions is discussed here.

Visible light-driven selective carbon–carbon bond formation for the production of vicinal diols

2020 ◽  
Vol 4 (11) ◽  
pp. 5488-5492
Author(s):  
Peng Bai ◽  
Xinli Tong ◽  
Yiqi Gao ◽  
Song Xue
Keyword(s):  
Visible Light ◽  
Visible Light Irradiation ◽  
Bond Formation ◽  
Light Irradiation ◽  
Carbon Bond ◽  
Benzylic Alcohols ◽  
Radical Coupling ◽  
Carbon Carbon Bond ◽  
Visible Light Driven ◽  
Vicinal Diols

A green and sustainable production of vicinal diols via the photocatalytic radical coupling of benzylic alcohols has been developed under visible light irradiation.

Visible-light-driven metal-free aerobic synthesis of highly diastereoselective phosphinoylpyrroloindoles

2020 ◽  
Vol 18 (7) ◽  
pp. 1354-1358 ◽  
Author(s):  
Ramesh Gorre ◽  
Damodar Enagandhula ◽  
Sridhar Balasubramanian ◽  
Srirama Murthy Akondi
Keyword(s):  
Visible Light ◽  
Room Temperature ◽  
Bond Formation ◽  
Metal Free ◽  
Visible Light Driven

A tandem C–P and C–C bond formation promoted by visible light at room temperature in a highly diastereoselective manner is described.

scholarly journals Z-Schematic and visible-light-driven CO2 reduction using H2O as an electron donor by a particulate mixture of a Ru-complex/(CuGa)1−xZn2xS2 hybrid catalyst, BiVO4 and an electron mediator

2018 ◽  
Vol 54 (72) ◽  
pp. 10199-10202 ◽  
Author(s):  
Tomiko M. Suzuki ◽  
Shunya Yoshino ◽  
Tomoaki Takayama ◽  
Akihide Iwase ◽  
Akihiko Kudo ◽  
...  
Keyword(s):  
Visible Light ◽  
Electron Donor ◽  
Aqueous Suspension ◽  
Co2 Reduction ◽  
Metal Sulfide ◽  
Electron Mediator ◽  
Ru Complex ◽  
Particulate Metal ◽  
Visible Light Driven ◽  
Hybrid Photocatalyst

Visible-light-driven Z-schematic CO2 reduction using H2O as an electron donor was achieved by an aqueous suspension of a particulate metal-sulfide/molecular hybrid photocatalyst.

scholarly journals Transition-Metal-Free, Visible-Light-Promoted C–S Cross-Coupling through Intermolecular Charge Transfer

Synlett ◽  
2018 ◽  
Vol 29 (19) ◽  
pp. 2449-2455 ◽  
Author(s):  
Garret Miyake ◽  
Bin Liu ◽  
Chern-Hooi Lim
Keyword(s):  
Transition Metal ◽  
Visible Light ◽  
Materials Science ◽  
Bond Formation ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Cross Coupling Reactions ◽  
Visible Light Driven ◽  
Metal Catalyzed ◽  
Historical Developments

C–S cross-couplings are an important class of reactions ­applied across organic synthesis, materials science, and pharma­ceuticals. Several different methodologies have been developed to achieve this significant transformation. However, currently available synthetic procedures significantly rely on transition metals. This article describes historical developments in the field of transition-metal-catalyzed C–S cross-coupling reactions, the development of a visible-light-driven and catalyst-free approach to C–S bond formation, and future outlooks.

scholarly journals Construction of C-N Bond Via Visible-Light-Mediated Difunctionalization of Alkenes

2021 ◽  
Author(s):  
Bhisma K. Patel ◽  
Tipu Alam ◽  
Amitava Rakshit
Keyword(s):  
Electron Transfer ◽  
Double Bond ◽  
Visible Light ◽  
Functional Groups ◽  
Organic Synthesis ◽  
Bond Formation ◽  
Building Blocks ◽  
Environmental Friendliness ◽  
Visible Light Driven ◽  
Interesting Area

In the last few years, the photo-redox process via single-electron transfer (SET) has received substantial attention for the synthesis of targeted organic compounds due to its environmental friendliness and sustainability. Of late visible-light-mediated difunctionalization of alkenes has gained much attention because of its step economy, which allows the consecutive installation of two functional groups across the C=C bond in a single operation. The construction of N-containing compounds has always been important in organic synthesis. Molecules containing C-N bonds are found in many building blocks and are important precursors to other functional groups. Meanwhile, C-N bond formation via the addition of the C=C double bond is gaining prominence. Therefore, considering the influence and synthetic potential of the C-N bond, here we provide a summary of the state of the art on visible-light-driven difunctionalizations of alkene. We hope that the construction of the C-N bond via visible-light-mediated difunctionalization of alkenes will be useful for medicinal and synthetic organic chemists and will inspire further reaction development in this interesting area.

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