Exceptional Hydrophobicity of a Large-Pore Metal–Organic Zeolite

2015 ◽  
Vol 137 (22) ◽  
pp. 7217-7223 ◽  
Author(s):  
Chun-Ting He ◽  
Lu Jiang ◽  
Zi-Ming Ye ◽  
Rajamani Krishna ◽  
Zhen-Song Zhong ◽  
...  
Keyword(s):  
Large Pore ◽  
Organic Zeolite ◽  
Metal Organic

scholarly journals Solvent-Free Powder Synthesis and MOF-CVD Thin Films of the Large-Pore Metal–Organic Framework MAF-6

2020 ◽  
Vol 32 (5) ◽  
pp. 1784-1793 ◽  
Author(s):  
Timothée Stassin ◽  
Ivo Stassen ◽  
João Marreiros ◽  
Alexander John Cruz ◽  
Rhea Verbeke ◽  
...  
Keyword(s):  
Thin Films ◽  
Metal Organic Framework ◽  
Solvent Free ◽  
Powder Synthesis ◽  
Large Pore ◽  
Metal Organic ◽  
Organic Framework

Combining Linker Design and Linker-Exchange Strategies for the Synthesis of a Stable Large-Pore Zr-Based Metal–Organic Framework

2018 ◽  
Vol 10 (41) ◽  
pp. 35462-35468 ◽  
Author(s):  
Hue T. T. Nguyen ◽  
Thach N. Tu ◽  
My V. Nguyen ◽  
Tien H. N. Lo ◽  
Hiroyasu Furukawa ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Large Pore ◽  
Metal Organic ◽  
Linker Exchange ◽  
Organic Framework

A robust large-pore zirconium carboxylate metal–organic framework for energy-efficient water-sorption-driven refrigeration

Nature Energy ◽  
2018 ◽  
Vol 3 (11) ◽  
pp. 985-993 ◽  
Author(s):  
Sujing Wang ◽  
Ji Sun Lee ◽  
Mohammad Wahiduzzaman ◽  
Jaedeuk Park ◽  
Mégane Muschi ◽  
...  
Keyword(s):  
Energy Efficient ◽  
Water Sorption ◽  
Metal Organic Framework ◽  
Large Pore ◽  
Metal Organic ◽  
Organic Framework

Encapsulating Pyrene in a Metal–Organic Zeolite for Optical Sensing of Molecular Oxygen

2015 ◽  
Vol 27 (24) ◽  
pp. 8255-8260 ◽  
Author(s):  
Jia-Wen Ye ◽  
Hao-Long Zhou ◽  
Si-Yang Liu ◽  
Xiao-Ning Cheng ◽  
Rui-Biao Lin ◽  
...  
Keyword(s):  
Molecular Oxygen ◽  
Optical Sensing ◽  
Organic Zeolite ◽  
Metal Organic

Large-Pore Apertures in a Series of Metal-Organic Frameworks

Science ◽  
2012 ◽  
Vol 336 (6084) ◽  
pp. 1018-1023 ◽  
Author(s):  
H. Deng ◽  
S. Grunder ◽  
K. E. Cordova ◽  
C. Valente ◽  
H. Furukawa ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Large Pore ◽  
Metal Organic

A New Type of Metal-Organic Large-Pore Zeotype

1999 ◽  
Vol 38 (1-2) ◽  
pp. 153-156 ◽  
Author(s):  
David M. L. Goodgame ◽  
David A. Grachvogel ◽  
David J. Williams
Keyword(s):  
Large Pore ◽  
Metal Organic ◽  
New Type

scholarly journals Predicting the Features of Methane Adsorption in Large Pore Metal-Organic Frameworks for Energy Storage

Nanomaterials ◽  
2018 ◽  
Vol 8 (10) ◽  
pp. 818 ◽  
Author(s):  
George Manos ◽  
Lawrence Dunne
Keyword(s):  
Gas Adsorption ◽  
Metal Organic Frameworks ◽  
Gas Storage ◽  
Methane Adsorption ◽  
Energy Applications ◽  
Adsorbed Gas ◽  
Theoretical Approaches ◽  
Large Pore ◽  
Metal Organic ◽  
Computer Simulation Studies

Currently, metal-organic frameworks (MOFs) are receiving significant attention as part of an international push to use their special properties in an extensive variety of energy applications. In particular, MOFs have exceptional potential for gas storage especially for methane and hydrogen for automobiles. However, using theoretical approaches to investigate this important problem presents various difficulties. Here we present the outcomes of a basic theoretical investigation into methane adsorption in large pore MOFs with the aim of capturing the unique features of this phenomenon. We have developed a pseudo one-dimensional statistical mechanical theory of adsorption of gas in a MOF with both narrow and large pores, which is solved exactly using a transfer matrix technique in the Osmotic Ensemble (OE). The theory effectively describes the distinctive features of adsorption of gas isotherms in MOFs. The characteristic forms of adsorption isotherms in MOFs reflect changes in structure caused by adsorption of gas and compressive stress. Of extraordinary importance for gas storage for energy applications, we find two regimes of Negative gas adsorption (NGA) where gas pressure causes the MOF to transform from the large pore to the narrow pore structure. These transformations can be induced by mechanical compression and conceivably used in an engine to discharge adsorbed gas from the MOF. The elements which govern NGA in MOFs with large pores are identified. Our study may help guide the difficult program of work for computer simulation studies of gas storage in MOFs with large pores.

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