scholarly journals Addition to “Preassembly Strategy To Fabricate Porous Hollow Carbonitride Spheres Inlaid with Single Cu–N3 Sites for Selective Oxidation of Benzene to Phenol”

Author(s):  
Ting Zhang ◽  
Di Zhang ◽  
Xinghua Han ◽  
Ting Dong ◽  
Xinwen Guo ◽  
...  
1996 ◽  
Vol 25 (12) ◽  
pp. 1115-1116 ◽  
Author(s):  
Atsushi Satsuma ◽  
Sakae Takenaka ◽  
Tsunehiro Tanaka ◽  
Shigeru Nojima ◽  
Yoshiya Kera ◽  
...  

2019 ◽  
Vol 370 ◽  
pp. 332-346 ◽  
Author(s):  
Wondemagegn Hailemichael Wanna ◽  
Ravirala Ramu ◽  
Damodar Janmanchi ◽  
Yi-Fang Tsai ◽  
Natarajan Thiyagarajan ◽  
...  

2003 ◽  
Vol 244 (1) ◽  
pp. 11-17 ◽  
Author(s):  
Tong Ren ◽  
Liang Yan ◽  
Xiaoming Zhang ◽  
Jishuan Suo

2020 ◽  
Vol 10 (1) ◽  
pp. 196-206 ◽  
Author(s):  
Noelia Losada-García ◽  
Alba Rodríguez-Otero ◽  
Jose M. Palomo

A new strategy has been developed for the tailor-made synthesis of copper nanoparticle (CuNPs)-enzyme biohybrids in aqueous media for selective benzene monohydroxylation.


2019 ◽  
Author(s):  
Noelia Losada-Garcia ◽  
Alba Rodriguez-Otero ◽  
Jose M Palomo

Novel heterogeneous nanocatalysts has been synthesized in aqueous media at multimilligram scale for highly selective direct oxidation of benzene to phenol in aqueous media. The synthesis of a novel biohybrids containing copper nanoparticles (CuNPs) by an efficient and green technology have been described. The methodology involves the combination of an enzyme and a copper salt in aqueous media at room temperature. It was possible to control the copper species and nanoparticle size depending on the experimental conditions, e.g. pH, reducing step, amount of enzyme, obtaining novel heterogeneous nanobiohybrids containing exclusively Cu (0)NPs, Cu2O (Cu(i)) NPs or very crystalline Cu3(PO4)2 (Cu (ii)) NPs. Very small dispersed copper nanoparticles were formed in all cases (from 3 to 15 nm). These novel CuNPs biohybrids were evaluated as catalyst in the selective oxidation of benzene to phenol in water at 30ºC using hydrogen peroxide as oxidant, obtaining excellent yields and selectivity of phenol (>80% yield, >95% selectivity). <br>


2020 ◽  
Vol 388 ◽  
pp. 124248 ◽  
Author(s):  
Jiaxin Li ◽  
Yanqi Xu ◽  
Zhongzhen Ding ◽  
Abdul Hanif Mahadi ◽  
Yufei Zhao ◽  
...  

RSC Advances ◽  
2013 ◽  
Vol 3 (15) ◽  
pp. 5121 ◽  
Author(s):  
Pengfei Zhang ◽  
Yutong Gong ◽  
Haoran Li ◽  
Zhirong Chen ◽  
Yong Wang

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