Hydroamination, Aminoboration, and Carboamination with Electrophilic Amination Reagents: Umpolung-Enabled Regio- and Stereoselective Synthesis of N-Containing Molecules from Alkenes and Alkynes

2022 ◽  
Author(s):  
Koji Hirano ◽  
Masahiro Miura
Keyword(s):  
Stereoselective Synthesis ◽  
Electrophilic Amination

Stereoselective amination via vinyl-silver intermediates derived from silver-catalyzed carboxylative cyclization of propargylamine

2020 ◽  
Vol 56 (66) ◽  
pp. 9517-9520
Author(s):  
Yuta Sadamitsu ◽  
Kodai Saito ◽  
Tohru Yamada
Keyword(s):  
Carbon Dioxide ◽  
Stereoselective Synthesis ◽  
Electrophilic Amination

The stereoselective synthesis of aminovinyloxazolidinones based on the electrophilic amination of a vinyl-silver intermediate, generated by silver-catalyzed carbon dioxide incorporation on a propargylamine, was achieved.

Sign in / Sign up

Export Citation Format

Share Document