Surface-Seal Encapsulation of a Homogeneous Catalyst in a Mesoporous Metal–Organic Framework

2022 ◽  
Author(s):  
Dongxu Wang ◽  
Siqi Li ◽  
Chunhui Wu ◽  
Tao Li
Keyword(s):  
Metal Organic Framework ◽  
Homogeneous Catalyst ◽  
Metal Organic ◽  
Mesoporous Metal ◽  
Organic Framework

Solvent-Free Powder Synthesis and MOF-CVD Thin Films of the Mesoporous Metal-Organic Framework MAF-6

2019 ◽  
Author(s):  
Timothée Stassin ◽  
Ivo Stassen ◽  
Joao Marreiros ◽  
Alexander John Cruz ◽  
Rhea Verbeke ◽  
...  
Keyword(s):  
Vapor Phase ◽  
Metal Organic Framework ◽  
Chemical Vapor ◽  
Uptake Capacity ◽  
Powder Synthesis ◽  
Crystalline Films ◽  
Metal Organic ◽  
Mesoporous Metal ◽  
First Time ◽  
Organic Framework

A simple solvent- and catalyst-free method is presented for the synthesis of the mesoporous metal-organic framework (MOF) MAF-6 (RHO-Zn(eIm)2) based on the reaction of ZnO with 2-ethylimidazole vapor at temperatures ≤ 100 °C. By translating this method to a chemical vapor deposition (CVD) protocol, mesoporous crystalline films could be deposited for the first time entirely from the vapor phase. A combination of PALS and Kr physisorption measurements confirmed the porosity of these MOF-CVD films and the size of the MAF-6 supercages (diam. ~2 nm), in close agreement with powder data and calculations. MAF-6 powders and films were further characterized by XRD, TGA, SEM, FTIR, PDF and EXAFS. The exceptional uptake capacity of the mesoporous MAF-6 in comparison to the microporous ZIF-8 is demonstrated by vapor-phase loading of a molecule larger than the ZIF-8 windows.

scholarly journals Recyclable Catalysts for Alkyne Functionalization

Molecules ◽  
2021 ◽  
Vol 26 (12) ◽  
pp. 3525
Author(s):  
Leslie Trigoura ◽  
Yalan Xing ◽  
Bhanu P. S. Chauhan
Keyword(s):  
Supported Catalysts ◽  
Metal Organic Framework ◽  
Metal Nanoparticle ◽  
Homogeneous Catalyst ◽  
Catalyst Recycling ◽  
Catalytic Systems ◽  
Recyclable Catalysts ◽  
Metal Organic ◽  
Porous Organic Framework ◽  
Organic Framework

In this review, we present an assessment of recent advances in alkyne functionalization reactions, classified according to different classes of recyclable catalysts. In this work, we have incorporated and reviewed the activity and selectivity of recyclable catalytic systems such as polysiloxane-encapsulated novel metal nanoparticle-based catalysts, silica–copper-supported nanocatalysts, graphitic carbon-supported nanocatalysts, metal organic framework (MOF) catalysts, porous organic framework (POP) catalysts, bio-material-supported catalysts, and metal/solvent free recyclable catalysts. In addition, several alkyne functionalization reactions have been elucidated to demonstrate the success and efficiency of recyclable catalysts. In addition, this review also provides the fundamental knowledge required for utilization of green catalysts, which can combine the advantageous features of both homogeneous (catalyst modulation) and heterogeneous (catalyst recycling) catalysis.

scholarly journals Highly Efficient Adsorption of Aqueous Pb(II) with Mesoporous Metal-Organic Framework-5: An Equilibrium and Kinetic Study

2016 ◽  
Vol 2016 ◽  
pp. 1-9 ◽  
Author(s):  
José María Rivera ◽  
Susana Rincón ◽  
Cherif Ben Youssef ◽  
Alejandro Zepeda
Keyword(s):  
Kinetic Study ◽  
Photoelectron Spectroscopy ◽  
Metal Organic Framework ◽  
Isotherm Models ◽  
Ionic Exchange ◽  
Order Kinetic ◽  
X Ray ◽  
Metal Organic ◽  
Mesoporous Metal ◽  
Organic Framework

Mesoporous metal-organic framework-5 (MOF-5), with the composition Zn4O(BDC)3, showed a high capacity for the adsorptive removal of Pb(II) from 100% aqueous media. After the adsorption process, changes in both morphology and composition were detected using a scanning electron microscope (SEM) equipped with an energy dispersive X-ray (EDX) system, Fourier transform infrared spectroscopy (FTIR), and X-ray photoelectron spectroscopy (XPS) analysis. The experimental evidence showed that Zn(II) liberation from MOF-5 structure was provoked by the water effect demonstrating that Pb(II) removal is not due to ionic exchange with Zn. A kinetic study showed that Pb(II) removal was carried out in 30 min with a behavior of pseudo-second-order kinetic model. The experimental data on Pb(II) adsorption were adequately fit by both the Langmuir and BET isotherm models with maximum adsorption capacities of 658.5 and 412.7 mg/g, respectively, at pH 5 and 45°C. The results of this work demonstrate that the use of MOF-5 has great potential for applications in environmental protection, especially regarding the removal of the lead present in industrial wastewaters and tap waters.

Mesoporous metal–organic framework MIL-100(Fe) as drug carrier

Adsorption ◽  
2021 ◽  
Author(s):  
Paulo G. M. Mileo ◽  
Diony N. Gomes ◽  
Daniel V. Gonçalves ◽  
Sebastião M. P. Lucena
Keyword(s):  
Metal Organic Framework ◽  
Drug Carrier ◽  
Metal Organic ◽  
Mesoporous Metal ◽  
Organic Framework

Stepwise adsorption in a mesoporous metal–organic framework: experimental and computational analysis

2012 ◽  
Vol 48 (27) ◽  
pp. 3297 ◽  
Author(s):  
Daqiang Yuan ◽  
Rachel B. Getman ◽  
Zhangwen Wei ◽  
Randall Q. Snurr ◽  
Hong-Cai Zhou
Keyword(s):  
Computational Analysis ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Mesoporous Metal ◽  
Organic Framework

Titelbild: Crystal Structure and Guest Uptake of a Mesoporous Metal–Organic Framework Containing Cages of 3.9 and 4.7 nm in Diameter (Angew. Chem. 43/2007)

2007 ◽  
Vol 119 (43) ◽  
pp. 8237-8237 ◽  
Author(s):  
Young Kwan Park ◽  
Sang Beom Choi ◽  
Hyunuk Kim ◽  
Kimoon Kim ◽  
Byoung-Ho Won ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Mesoporous Metal ◽  
Organic Framework
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