Significant Enhancement of the Electrical Conductivity of Conjugated Polymers by Post-Processing Side Chain Removal

2022 ◽  
Author(s):  
James F. Ponder ◽  
Shawn A. Gregory ◽  
Amalie Atassi ◽  
Akanksha K. Menon ◽  
Augustus W. Lang ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Conjugated Polymers ◽  
Significant Enhancement ◽  
Side Chain ◽  
Post Processing

Significant enhancement of photodetector performance by subtle changes in the side chains of dithienopyrrole-based polymers

RSC Advances ◽  
2016 ◽  
Vol 6 (27) ◽  
pp. 22494-22499 ◽  
Author(s):  
Liuyong Hu ◽  
Wenqiang Qiao ◽  
Ji Qi ◽  
Xiaoqin Zhang ◽  
Jinfeng Han ◽  
...  
Keyword(s):  
Significant Enhancement ◽  
Side Chain ◽  
Side Chains

The insertion of phenylene unit at side chain reduces π–π distance and promotes morphology, resulting in significant increase in responsivity.

Revealing the Side‐Chain Dependent Ordering Transition of Highly‐Crystalline Double‐Cable Conjugated Polymers

2021 ◽  
Author(s):  
Guitao Feng ◽  
Wenliang Tan ◽  
Safakath Karuthedath ◽  
Cheng Li ◽  
Xuechen Jiao ◽  
...  
Keyword(s):  
Conjugated Polymers ◽  
Side Chain ◽  
Ordering Transition

Side chain triphenylamine-based conjugated polymers for the preparation of efficient heterojunction solar cells

2018 ◽  
Vol 30 (3) ◽  
pp. 2235-2245
Author(s):  
Wenjie Deng ◽  
Yuancheng Qin ◽  
Shanshan Lin ◽  
Dezhong Song ◽  
Sha Xu ◽  
...  
Keyword(s):  
Solar Cells ◽  
Conjugated Polymers ◽  
Side Chain ◽  
Heterojunction Solar Cells

scholarly journals The Role of the Side Chain on the Performance of N-type Conjugated Polymers in Aqueous Electrolytes

2018 ◽  
Vol 30 (9) ◽  
pp. 2945-2953 ◽  
Author(s):  
Alexander Giovannitti ◽  
Iuliana P. Maria ◽  
David Hanifi ◽  
Mary J. Donahue ◽  
Daniel Bryant ◽  
...  
Keyword(s):  
Conjugated Polymers ◽  
Side Chain ◽  
Aqueous Electrolytes

scholarly journals Side-chain conjugated polymers for use in the active layers of hybrid semiconducting polymer/quantum dot light emitting diodes

2016 ◽  
Vol 7 (1) ◽  
pp. 101-112 ◽  
Author(s):  
Ana Fokina ◽  
Yeonkyung Lee ◽  
Jun Hyuk Chang ◽  
Lydia Braun ◽  
Wan Ki Bae ◽  
...  
Keyword(s):  
Quantum Dot ◽  
Conjugated Polymers ◽  
Light Emitting Diodes ◽  
Side Chain ◽  
Hybrid Polymer ◽  
Semiconducting Polymer ◽  
Light Emitting ◽  
Active Layers

Three monomers,M1–M3, with modified carbazole cores and styrene functionality were polymerized by RAFT. The polymers were then used in the active layers of hybrid polymer/quantum dot light emitting diodes.

Effects of Side-Chain Topology on Aggregation of Conjugated Polymers

2018 ◽  
Vol 51 (7) ◽  
pp. 2580-2590 ◽  
Author(s):  
Brenden McDearmon ◽  
Eunhee Lim ◽  
In-Hwan Lee ◽  
Lisa M. Kozycz ◽  
Kathryn O’Hara ◽  
...  
Keyword(s):  
Conjugated Polymers ◽  
Side Chain

scholarly journals DFT Prediction of Factors Affecting the Structural Characteristics, the Transition Temperature and the Electronic Density of Some New Conjugated Polymers

Polymers ◽  
2020 ◽  
Vol 12 (6) ◽  
pp. 1207
Author(s):  
Quoc-Trung Vu ◽  
Thi-Thuy-Duong Tran ◽  
Thuy-Chinh Nguyen ◽  
Thien Vuong Nguyen ◽  
Hien Nguyen ◽  
...  
Keyword(s):  
Phase Transition ◽  
Transition Temperature ◽  
Conjugated Polymers ◽  
Bond Length ◽  
Density Functional ◽  
Structural Characteristics ◽  
Side Chain ◽  
Electronic Density ◽  
Energy Field ◽  
Energy Bandgap

Conjugated polymers are promising materials for various cutting-edge technologies, especially for organic conducting materials and in the energy field. In this work, we have synthesized a new conjugated polymer and investigated the effect of distance between bond layers, side-chain functional groups (H, Br, OH, OCH3 and OC2H5) on structural characteristics, phase transition temperature (T), and electrical structure of C13H8OS using Density Functional Theory (DFT). The structural characteristics were determined by the shape, network constant (a, b and c), bond length (C–C, C–H, C–O, C–S, C–Br and O–H), phase transition temperatures, and the total energy (Etot) on a base cell. Our finding shows that the increase of layer thickness (h) of C13H8OS–H has a negligible effect on the transition temperature, while the energy bandgap (Eg) increases from 1.646 eV to 1.675 eV. The calculation of bond length with different side chain groups was carried out for which C13H8OS–H has C–H = 1.09 Å; C13H8OS–Br has C–Br = 1.93 Å; C13H8OS–OH has C–O = 1.36 Å, O–H = 0.78 Å; C13H8OS–OCH3 has C–O = 1.44 Å, O–H =1.10 Å; C13H8OS–OC2H5 has C–O = 1.45 Å, C–C = 1.51Å, C–H = 1.10 Å. The transition temperature (T) for C13H8OS–H was 500 K < T < 562 K; C13H8OS–Br was 442 K < T < 512 K; C13H8OS–OH was 487 K < T < 543 K; C13H8OS–OCH3 was 492 K < T < 558 K; and C13H8OS–OC2H5 was 492 K < T < 572 K. The energy bandgap (Eg) of Br is of Eg = 1.621 eV, the doping of side chain groups H, OH, OCH3, and OC2H5, leads to an increase of Eg from 1.621 eV to 1.646, 1.697, 1.920, and 2.04 eV, respectively.

Significant improvement of photocatalytic hydrogen evolution of diketopyrrolopyrrole-based donor–acceptor conjugated polymers through side-chain engineering

2019 ◽  
Vol 10 (47) ◽  
pp. 6473-6480 ◽  
Author(s):  
Ruimin Diao ◽  
Haonan Ye ◽  
Zhicheng Yang ◽  
Shicong Zhang ◽  
Kangyi Kong ◽  
...  
Keyword(s):  
Absorption Spectrum ◽  
Conjugated Polymers ◽  
Hydrogen Evolution ◽  
Evolution Rate ◽  
Side Chain ◽  
Photocatalytic Hydrogen Evolution ◽  
Hydrogen Evolution Rate ◽  
Donor Acceptor

The hydrogen evolution rate of PDPP3B-O4 with butoxy chain was 5.53 mmol h−1 g−1 with 1% Pt loading (λ > 400 nm), increased 110 times than PDPP3B-C8 with octyl chain due to wider absorption spectrum and better wettability via side chain engineering.

scholarly journals Defining side chain successions in anthracene-based poly(arylene ethynylene)-alt-poly(phenylene vinylene)s: probing structure–property relationships

2019 ◽  
Vol 10 (39) ◽  
pp. 5339-5347
Author(s):  
Christoph Ulbricht ◽  
Nassima Bouguerra ◽  
Samuel Inack Ngi ◽  
Oliver Brüggemann ◽  
Daniel A. M. Egbe
Keyword(s):  
Conjugated Polymers ◽  
Spectroscopic Study ◽  
Side Chain ◽  
Phenylene Vinylene ◽  
Structure Property ◽  
Structure Property Relationships

A detailed spectroscopic study of nine conjugated polymers with various octyloxy/2-ethylhexyloxy side chain sequences prepared using optimized regio-selective synthetic pathways.

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