Oriented Electrostatic Effects on O2 and CO2 Reduction by a Polycationic Iron Porphyrin

2021 ◽  
Author(s):  
Daniel J. Martin ◽  
James M. Mayer
Keyword(s):  
Co2 Reduction ◽  
Iron Porphyrin ◽  
Electrostatic Effects

An NADH-Inspired Redox Mediator Strategy to Promote Second-Sphere Electron and Proton Transfer for Cooperative Electrochemical CO2 Reduction Catalyzed by Iron Porphyrin

2020 ◽  
Author(s):  
Peter T. Smith ◽  
Sophia Weng ◽  
Christopher Chang
Keyword(s):  
Proton Transfer ◽  
Co2 Reduction ◽  
Iron Porphyrin ◽  
Redox Mediators ◽  
Reservoir Properties ◽  
Proton Reduction ◽  
Electrochemical Co2 Reduction ◽  
Starting Point ◽  
Rate Improvement ◽  
Molecular Catalysts

We present a bioinspired strategy for enhancing electrochemical carbon dioxide reduction catalysis by cooperative use of base-metal molecular catalysts with intermolecular second-sphere redox mediators that facilitate both electron and proton transfer. Functional synthetic mimics of the biological redox cofactor NADH, which are electrochemically stable and are capable of mediating both electron and proton transfer, can enhance the activity of an iron porphyrin catalyst for electrochemical reduction of CO<sub>2</sub> to CO, achieving a 13-fold rate improvement without altering the intrinsic high selectivity of this catalyst platform for CO<sub>2</sub> versus proton reduction. Evaluation of a systematic series of NADH analogs and redox-inactive control additives with varying proton and electron reservoir properties reveals that both electron and proton transfer contribute to the observed catalytic enhancements. This work establishes that second-sphere dual control of electron and proton inventories is a viable design strategy for developing more effective electrocatalysts for CO<sub>2</sub> reduction, providing a starting point for broader applications of this approach to other multi-electron, multi-proton transformations.

Effects of Appended Poly(ethylene glycol) on Electrochemical CO2 Reduction by an Iron Porphyrin Complex

2021 ◽  
Vol 60 (6) ◽  
pp. 3843-3850
Author(s):  
Ashwin Chaturvedi ◽  
Caroline K. Williams ◽  
Nilakshi Devi ◽  
Jianbing “Jimmy” Jiang
Keyword(s):  
Ethylene Glycol ◽  
Co2 Reduction ◽  
Iron Porphyrin ◽  
Poly Ethylene Glycol ◽  
Porphyrin Complex ◽  
Electrochemical Co2 Reduction ◽  
Poly Ethylene

Syntheses and CO2 reduction activities of π-expanded/extended iron porphyrin complexes

2017 ◽  
Vol 22 (5) ◽  
pp. 713-725 ◽  
Author(s):  
Yuki Okabe ◽  
Sze Koon Lee ◽  
Mio Kondo ◽  
Shigeyuki Masaoka
Keyword(s):  
Co2 Reduction ◽  
Iron Porphyrin ◽  
Iron Porphyrin Complexes

scholarly journals Intramolecular Electrostatic Effects on O2, CO2, and Acetate Binding to a Cationic Iron Porphyrin

2020 ◽  
Vol 59 (23) ◽  
pp. 17402-17414
Author(s):  
Daniel J. Martin ◽  
Samantha I. Johnson ◽  
Brandon Q. Mercado ◽  
Simone Raugei ◽  
James M. Mayer
Keyword(s):  
Iron Porphyrin ◽  
Electrostatic Effects

An NADH-Inspired Redox Mediator Strategy to Promote Second-Sphere Electron and Proton Transfer for Cooperative Electrochemical CO2 Reduction Catalyzed by Iron Porphyrin

2020 ◽  
Author(s):  
Peter T. Smith ◽  
Sophia Weng ◽  
Christopher Chang
Keyword(s):  
Proton Transfer ◽  
Co2 Reduction ◽  
Iron Porphyrin ◽  
Redox Mediators ◽  
Reservoir Properties ◽  
Proton Reduction ◽  
Electrochemical Co2 Reduction ◽  
Starting Point ◽  
Rate Improvement ◽  
Molecular Catalysts

We present a bioinspired strategy for enhancing electrochemical carbon dioxide reduction catalysis by cooperative use of base-metal molecular catalysts with intermolecular second-sphere redox mediators that facilitate both electron and proton transfer. Functional synthetic mimics of the biological redox cofactor NADH, which are electrochemically stable and are capable of mediating both electron and proton transfer, can enhance the activity of an iron porphyrin catalyst for electrochemical reduction of CO<sub>2</sub> to CO, achieving a 13-fold rate improvement without altering the intrinsic high selectivity of this catalyst platform for CO<sub>2</sub> versus proton reduction. Evaluation of a systematic series of NADH analogs and redox-inactive control additives with varying proton and electron reservoir properties reveals that both electron and proton transfer contribute to the observed catalytic enhancements. This work establishes that second-sphere dual control of electron and proton inventories is a viable design strategy for developing more effective electrocatalysts for CO<sub>2</sub> reduction, providing a starting point for broader applications of this approach to other multi-electron, multi-proton transformations.

Controlled electropolymerisation of a carbazole-functionalised iron porphyrin electrocatalyst for CO2 reduction

2016 ◽  
Vol 52 (34) ◽  
pp. 5864-5867 ◽  
Author(s):  
Xin-Ming Hu ◽  
Zakaria Salmi ◽  
Mie Lillethorup ◽  
Emil B. Pedersen ◽  
Marc Robert ◽  
...  
Keyword(s):  
Co2 Reduction ◽  
Iron Porphyrin ◽  
Microporous Material ◽  
Electrochemical Approach

A straightforward electrochemical approach is presented by which iron porphyrin catalysts may be immobilised inside a CO2 absorbing microporous material.

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