Dipnictogen f-Element Chemistry: A Diphosphorus Uranium Complex

Author(s):  
Jingzhen Du ◽  
David Hunger ◽  
John A. Seed ◽  
Jonathan D. Cryer ◽  
David M. King ◽  
...  
2018 ◽  
Author(s):  
Casey Beaudoin ◽  
◽  
G. Nelson Eby

2015 ◽  
Vol 39 (10) ◽  
pp. 7539-7539 ◽  
Author(s):  
Frank T. Edelmann ◽  
Peter Junk
Keyword(s):  

A collection of papers presented at the Pacifichem 2015 symposium "Frontiers of Organo-f-Element Chemistry" held in Honolulu, Hawaii, USA.


1980 ◽  
Vol 43 (330) ◽  
pp. 765-770 ◽  
Author(s):  
A. M. Duncan ◽  
R. M. F. Preston

SummaryThe chemical variation of clinopyroxene phenocrysts from the trachybasaltic lavas of Etna volcano is described. The phenocrysts show a limited, but distinct trend in chemical variation from calcic-augite in the hawaiites to augite in the benmoreites. The trend of this variation is unusual, being one of Mg-enrichment with differentiation of the magma. Ca shows a steady decrease in the clinopyroxenes from the hawaiites to the benmoreites. Na, however, shows little chemical variation in the pyroxenes. The trace element chemistry is briefly examined. The clinopyroxenes show well-developed oscillatory and sector zoning. The basal {11} sectors are enriched in Si and Mg and depleted in Ti, Al, and Fe relative to the {100}, {110}, and {010} prism sectors.


1978 ◽  
Vol 42 (322) ◽  
pp. 209-220 ◽  
Author(s):  
Stefán Arnórsson

SummaryHigh-temperature geothermal fields in Iceland represent localized anomalies of hot, altered rock in the uppermost part of the crust, which coincide with points of maximum tectonic/magmatic activity. These points correspond to the intersection of oblique fault swarms to the plate boundaries. Geothermal activity under mid-ocean ridges follows probably similar tectonic/magmatic anomalies.Due to high permeability sea-water invades the bed-rock of the Reykjanes Peninsula, Iceland, and is overlain by a variably thick lens of dilute ground water of meteoric origin. The variable degree of salinity of geothermal waters in the Reykjanes Peninsula has resulted from different degree of mixing of fresh ground water with the underlying sea-water-ground-water in the downflow zones around the geothermal fields. At Reykjanes the geothermal water represents heated sea-water without any freshwater mixing. The difference in the composition of sea-water or sea-water/fresh water mixtures and the geothermal waters is due to basalt/water interaction at elevated temperatures. The major-element chemistry of the geothermal water represents an equilibrium composition at the relevant aquifer temperatures. The activities of silica, calcium, sulphate, and carbonate are thus limited by the solubilities of quartz, anhydrite, and calcite. Fluoride activity is thought to be controlled by an ionic exchange reaction where it substitutes for hydroxyl groups in phyllosilicates. The ratios of individual cations and hydrogen ion are governed by ionic exchange equilibria with hydrothermal minerals, probably smectite and chlorite. The equilibrium pH for the Reykjanes and Svartsengi geothermal waters is 5·5 and 5·1 respectively. Sea-water will become somewhat acid upon heating to more than about 300 °C and equilibration with basalt, the acidity increasing with temperature.


1994 ◽  
Vol 62 (1-4) ◽  
pp. 429-452 ◽  
Author(s):  
Christopher J. Nye ◽  
Samuel E. Swanson ◽  
Victoria F. Avery ◽  
Thomas P. Miller

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