SmI2-Catalyzed Intermolecular Coupling of Cyclopropyl Ketones and Alkynes: A Link between Ketone Conformation and Reactivity

Soumitra Agasti; Nicholas A. Beattie; Joseph J. W. McDouall; David J. Procter

doi:10.1021/jacs.1c01356

SmI2-Catalyzed Intermolecular Coupling of Cyclopropyl Ketones and Alkynes: A Link between Ketone Conformation and Reactivity

Journal of the American Chemical Society ◽

10.1021/jacs.1c01356 ◽

2021 ◽

Vol 143 (9) ◽

pp. 3655-3661

Author(s):

Soumitra Agasti ◽

Nicholas A. Beattie ◽

Joseph J. W. McDouall ◽

David J. Procter

Keyword(s):

Cyclopropyl Ketones ◽

Intermolecular Coupling

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ChemInform Abstract: Domino Carbocationic Cyclization of Functionalized Cyclopropyl Ketones: Facile One-Pot Access to Peri- and Angularly Fused Polycyclic Aromatic and Heteroaromatic Frameworks.

ChemInform ◽

10.1002/chin.200248031 ◽

2010 ◽

Vol 33 (48) ◽

pp. no-no

Author(s):

Sukumar Nandi ◽

U. K. Syam Kumar ◽

Hiriyakkanavar Ila ◽

Hiriyakkanavar Junjappa

Keyword(s):

One Pot ◽

Polycyclic Aromatic ◽

Cyclopropyl Ketones

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Samarium Diiodide Induced Reactions of Cyclopropyl Ketones: Reductive Ring Cleavage and Dimerization Leading to 1,8-Diketones — Scope, Limitations, Mechanisms.

ChemInform ◽

10.1002/chin.200631064 ◽

2006 ◽

Vol 37 (31) ◽

Author(s):

Francesca Aulenta ◽

Alexandra Hoelemann ◽

Hans-Ulrich Reissig

Keyword(s):

Ring Cleavage ◽

Samarium Diiodide ◽

Cyclopropyl Ketones

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Tuning the Regioselectivity in the Palladium(II)-Catalyzed Isomerization of Alkylidene Cyclopropyl Ketones: A Dramatic Salt Effect.

ChemInform ◽

10.1002/chin.200319043 ◽

2003 ◽

Vol 34 (19) ◽

Author(s):

Shengming Ma ◽

Junliang Zhang

Keyword(s):

Salt Effect ◽

Cyclopropyl Ketones

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ChemInform Abstract: A Novel Route to Cyclopropyl Ketones, Aldehydes, and Carboxylic Acids.

ChemInform ◽

10.1002/chin.199202158 ◽

2010 ◽

Vol 23 (2) ◽

pp. no-no

Author(s):

K. E. RODRIGUES

Keyword(s):

Carboxylic Acids ◽

Cyclopropyl Ketones

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Evidence for resonant intermolecular coupling in liquid benzene and pyridine from Raman difference spectroscopy of isotopic mixtures

The Journal of Chemical Physics ◽

10.1063/1.452697 ◽

1987 ◽

Vol 86 (9) ◽

pp. 4762-4767 ◽

Cited By ~ 23

Author(s):

N. Meinander ◽

M. M. Strube ◽

A. N. Johnson ◽

J. Laane

Keyword(s):

Difference Spectroscopy ◽

Liquid Benzene ◽

Intermolecular Coupling

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The photochemistry of two rigid β,γ-cyclopropyl ketones, exo- and endo-tricyclo[3,2,1,02,4]octan-6-one

Journal of the Chemical Society Chemical Communications ◽

10.1039/c39750000509 ◽

1975 ◽

pp. 509-510 ◽

Cited By ~ 5

Author(s):

Amos B. Smith ◽

Lee Brodsky ◽

Steven Wolff ◽

William C. Agosta

Keyword(s):

Cyclopropyl Ketones

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Possible intermediates in the photoreduction of conjugated cyclopropyl ketones in isopropyl alcohol

The Journal of Organic Chemistry ◽

10.1021/jo01261a007 ◽

1969 ◽

Vol 34 (9) ◽

pp. 2512-2517 ◽

Cited By ~ 24

Author(s):

William G. Dauben ◽

Leonard Schutte ◽

Richard E. Wolf ◽

E. John Deviny

Keyword(s):

Isopropyl Alcohol ◽

Cyclopropyl Ketones

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Raman Spectral Studies of Intermolecular Coupling in Aqueous Selenious Acid Solutions

The Journal of Chemical Physics ◽

10.1063/1.1840947 ◽

1967 ◽

Vol 46 (5) ◽

pp. 1870-1877 ◽

Cited By ~ 14

Author(s):

G. E. Walrafen

Keyword(s):

Spectral Studies ◽

Acid Solutions ◽

Selenious Acid ◽

Raman Spectral ◽

Intermolecular Coupling

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Strategic Application and Transformation of ortho-Disubstituted Phenyl and Cyclopropyl Ketones To Expand the Scope of Hydrogen Borrowing Catalysis

Journal of the American Chemical Society ◽

10.1021/jacs.5b11196 ◽

2015 ◽

Vol 137 (50) ◽

pp. 15664-15667 ◽

Cited By ~ 62

Author(s):

James R. Frost ◽

Choon Boon Cheong ◽

Wasim M. Akhtar ◽

Dimitri F. J. Caputo ◽

Neil G. Stevenson ◽

...

Keyword(s):

Cyclopropyl Ketones

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Trapping the intermediate involved in the intramolecular cyclisation of cyclopropyl ketones. A convenient preparation of open-chain γ-hydroxy ketones

Tetrahedron Letters ◽

10.1016/s0040-4039(00)78730-2 ◽

1980 ◽

Vol 21 (36) ◽

pp. 3517-3520 ◽

Cited By ~ 5

Author(s):

William S. Murphy ◽

Sompong Wattanasin

Keyword(s):

Open Chain ◽

Hydroxy Ketones ◽

Cyclopropyl Ketones ◽

Convenient Preparation

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