Pd-Catalyzed ipso,meta-Dimethylation of ortho-Substituted Iodoarenes via a Base-Controlled C–H Activation Cascade with Dimethyl Carbonate as the Methyl Source

2021 ◽  
Vol 143 (12) ◽  
pp. 4524-4530
Author(s):  
Zhuo Wu ◽  
Feng Wei ◽  
Bin Wan ◽  
Yanghui Zhang
Keyword(s):  
Dimethyl Carbonate ◽  
Activation Cascade

Synthesis of carbonate esters by carboxymethylation using NaAlO2 as a highly active heterogeneous catalyst

2018 ◽  
Author(s):  
Sreerangappa Ramesh ◽  
Kiran Indukuri ◽  
Olivier Riant ◽  
Damien Debecker
Keyword(s):  
Heterogeneous Catalyst ◽  
Dimethyl Carbonate ◽  
Sodium Aluminate ◽  
High Yield ◽  
Solid Catalyst ◽  
Highly Active ◽  
Aromatic Alcohols ◽  
Green Conditions ◽  
Mixed Carbonate

<p>Sodium aluminate is presented as a highly active heterogeneous catalyst able to convert a range of alcohols into the corresponding mixed carbonate esters, in high yield and under green conditions. The reaction is carried out using dimethyl carbonate both as a reactant and solvent, at 90°C. Allylic, aliphatic and aromatic alcohols are converted in good yields. The solid catalyst is shown to be truly heterogeneous, resistant to leaching, and recyclable. </p>

scholarly journals Greener production of dimethyl carbonate by the Power-to-Fuel concept: a comparative techno-economic analysis

2021 ◽  
Author(s):  
Hong Huang ◽  
Remzi Can Samsun ◽  
Ralf Peters ◽  
Detlef Stolten
Keyword(s):  
Economic Analysis ◽  
Dimethyl Carbonate ◽  
Carbonate Production

Techno-economic performances of four different dimethyl carbonate production pathways are analysed based on the Power-to-Fuel concept.

Synthesis of 2-amino-4,6-dimethoxypyrimidine with dimethyl carbonate as methylating agent

2013 ◽  
Vol 40 (5) ◽  
pp. 1789-1797 ◽  
Author(s):  
Zhen Xiong ◽  
Minghao Zhou ◽  
Guomin Xiao
Keyword(s):  
Dimethyl Carbonate
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