Iron-Catalyzed Regiodivergent Alkyne Hydrosilylation

2020 ◽  
Vol 142 (39) ◽  
pp. 16894-16902 ◽  
Author(s):  
Meng-Yang Hu ◽  
Peng He ◽  
Tian-Zhang Qiao ◽  
Wei Sun ◽  
Wen-Tao Li ◽  
...  
Keyword(s):  
Alkyne Hydrosilylation

scholarly journals β-(Z) Selectivity Control by Cyclometalated Rhodium(III)–Triazolylidene Homogeneous and Heterogeneous Terminal Alkyne Hydrosilylation Catalysts

ACS Catalysis ◽  
2020 ◽  
Vol 10 (22) ◽  
pp. 13334-13351
Author(s):  
Beatriz Sánchez-Page ◽  
Julen Munarriz ◽  
M. Victoria Jiménez ◽  
Jesús J. Pérez-Torrente ◽  
Javier Blasco ◽  
...  
Keyword(s):  
Terminal Alkyne ◽  
Selectivity Control ◽  
Alkyne Hydrosilylation ◽  
Heterogeneous Terminal

scholarly journals Hybrid Catalysts Comprised of Graphene Modified with Rhodium-Based N-Heterocyclic Carbenes for Alkyne Hydrosilylation

2020 ◽  
Vol 3 (2) ◽  
pp. 1640-1655 ◽  
Author(s):  
Beatriz Sánchez-Page ◽  
M. Victoria Jiménez ◽  
Jesús J. Pérez-Torrente ◽  
Vincenzo Passarelli ◽  
Javier Blasco ◽  
...  
Keyword(s):  
Heterocyclic Carbenes ◽  
Hybrid Catalysts ◽  
Alkyne Hydrosilylation

Alkyne hydrosilylation catalyzed by nickel complexes of N-heterocyclic carbenes

Tetrahedron ◽  
2006 ◽  
Vol 62 (32) ◽  
pp. 7560-7566 ◽  
Author(s):  
Mani Raj Chaulagain ◽  
Gireesh M. Mahandru ◽  
John Montgomery
Keyword(s):  
Nickel Complexes ◽  
Heterocyclic Carbenes ◽  
Alkyne Hydrosilylation

scholarly journals Correction: Cobalt-catalyzed alkyne hydrosilylation as a new frontier to selectively access silyl-hydrocarbons

2022 ◽  
Author(s):  
Jung-Woo Park
Keyword(s):  
New Frontier ◽  
Alkyne Hydrosilylation

Correction for ‘Cobalt-catalyzed alkyne hydrosilylation as a new frontier to selectively access silyl-hydrocarbons’ by Jung-Woo Park et al., Chem. Commun., 2022, DOI: 10.1039/d1cc06214j.

scholarly journals Highly Efficient and Reusable Alkyne Hydrosilylation Catalysts Based on Rhodium Complexes Ligated by Imidazolium-Substituted Phosphine

Catalysts ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 608
Author(s):  
Olga Bartlewicz ◽  
Magdalena Jankowska-Wajda ◽  
Hieronim Maciejewski
Keyword(s):  
Good Alternative ◽  
Rhodium Complexes ◽  
Multiple Use ◽  
Homogeneous Catalysts ◽  
Highly Efficient ◽  
Alkyne Hydrosilylation

Rhodium complexes ligated by imidazolium-substituted phosphine were used as catalysts in the hydrosilylation of alkynes (1-heptyne, 1-octyne, and phenylacetylene) with 1,1,1,3,5,5,5-heptamethyltrisiloxane (HMTS) or triethylsilane (TES). In all cases, the above complexes showed higher activity and selectivity compared to their precursors ([Rh(PPh3)3Cl] and [{Rh(µ-Cl)(cod)}2]). In the reactions with aliphatic alkynes (both when HMTS and TES were used as hydrosilylating agents), β(Z) isomer was mainly formed, but, in the reaction of phenylacetylene with TES, the β(E) product was formed. The catalysts are very durable, stable in air and first and foremost insoluble in the reactants which facilitated their isolation and permitted their multiple use in subsequent catalytic runs. They make a very good alternative to the commonly used homogeneous catalysts.

Catalysed stereodivergent hydrosilylation with Onium Salts stabilised M(0) nanocatalysts prepared in scCO2

RSC Advances ◽  
2014 ◽  
Vol 4 (104) ◽  
pp. 59953-59960 ◽  
Author(s):  
O. Pascu ◽  
V. Liautard ◽  
M. Vaultier ◽  
M. Pucheault ◽  
C. Aymonier
Keyword(s):  
Hydrosilylation Reaction ◽  
Onium Salt ◽  
Onium Salts ◽  
Original Preparation ◽  
Alkyne Hydrosilylation

M(0) nanocatalysts stabilised in Onium Salt were synthesised using an original preparation and their effectiveness in catalysing the challenging selective sterodivergent alkyne hydrosilylation reaction was studied.

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