scholarly journals Difluorocarbene Generation from TMSCF3: Kinetics and Mechanism of NaI-Mediated and Si-Induced Anionic Chain Reactions

2020 ◽  
Vol 142 (34) ◽  
pp. 14649-14663 ◽  
Author(s):  
Andrés García-Domínguez ◽  
Thomas H. West ◽  
Johann J. Primozic ◽  
Katie M. Grant ◽  
Craig P. Johnston ◽  
...  
Keyword(s):  
Kinetics And Mechanism ◽  
Chain Reactions ◽  
Anionic Chain

Kinetics and mechanism of laser-driven powder synthesis from organosilane precursors

1989 ◽  
Vol 4 (6) ◽  
pp. 1538-1548 ◽  
Author(s):  
G. W. Rice ◽  
R. L. Woodin
Keyword(s):  
Free Radical ◽  
Bond Cleavage ◽  
Kinetics And Mechanism ◽  
Organosilicon Compounds ◽  
Qualitative Model ◽  
Powder Synthesis ◽  
Radical Chain ◽  
Chain Reactions ◽  
Large Molecules ◽  
Organosilicon Polymers

Laser-driven synthesis of refractory powders from the organosilicon compounds ((CH3)3Si)2NH and ((CH3)3Si)2O has been studied as prototypical of powder syntheses from large molecules. A cw CO2 laser is used for powder syntheses and pulsed TEA CO2 laser-driven homogeneous pyrolysis is used to study the initiation chemistry. Initial decomposition of the organosilanes by Si–C bond cleavage initiates free radical chain reactions which produce organosilicon polymers and subsequent refractory phases. A qualitative model is proposed which provides a framework for understanding the parameters influencing powder synthesis from large molecules.

Kinetics and mechanism for oxime formation from 2-quinolinecarboxaldehyde

10.1002/kin.7 ◽  
1996 ◽  
Vol 28 (9) ◽  
pp. 687-691 ◽  
Author(s):  
M. Calzadilla ◽  
A. Malpica ◽  
P. M. Diaz
Keyword(s):  
Kinetics And Mechanism ◽  
Oxime Formation

Kinetics and mechanism of the reduction of selenium (IV) by iron (II) in presence of sodium fluoride

1973 ◽  
Vol 70 ◽  
pp. 918-922 ◽  
Author(s):  
R. K. Srivastava ◽  
V. K. Srivastava ◽  
M. N. Srivastava ◽  
B. B. L. Saxena
Keyword(s):  
Sodium Fluoride ◽  
Kinetics And Mechanism

Phenotyping and Genotyping of Coagulation Factor V Leiden

1996 ◽  
Vol 75 (02) ◽  
pp. 267-269 ◽  
Author(s):  
H Engel ◽  
L Zwang ◽  
H H D M van Vliet ◽  
J J Michiles ◽  
J Stibbe ◽  
...  
Keyword(s):  
Factor V Leiden ◽  
Coagulation Factor ◽  
Diagnostic Value ◽  
Resistance Test ◽  
Amplification Refractory Mutation System ◽  
Factor V ◽  
Chain Reactions ◽  
Apc Resistance ◽  
Specificity And Sensitivity ◽  
Coagulation Factor V

SummaryThe currently used activated Protein C resistance test demonstrated to be of limited diagnostic value for the detection of the mutant Factor V Leiden. Moreover, this assay is not useful for patients under anticoagulant therapy. A modification of the APC resistance test, applying Factor V deficient plasma is described which demonstrates a specificity and sensitivity of 1.0. The superiority of the modified APC resistance test over the existing APC resistance test was verified by genotyping.For that purpose, the Amplification Refractory Mutation System (ARMS) was applied to the detection of the G to A mutation at position 1691 in the gene encoding coagulation Factor V. The mutation at that position could be easily detected by using each of two allele-specific oligonucleotide primers concomitantly with one common primer in two separate polymerase chain reactions, thereby amplifying a fragment of 186 base-pairs of the Factor V gene.

Kinetics and mechanism of photoinduced orientation of bisazodioksodibenzothiophene in thin films

2016 ◽  
Vol 2 (4) ◽  
pp. 39-45 ◽  
Author(s):  
J.D Chaplanova ◽  
S.N. Larykava ◽  
V.E Agabekov ◽  
I.N. Kukhta
Keyword(s):  
Thin Films ◽  
Kinetics And Mechanism

Present-day theory of chain reactions

1966 ◽  
Vol 88 (4) ◽  
pp. 769-781 ◽  
Author(s):  
V.N. Kondrat'ev
Keyword(s):  
Chain Reactions
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