scholarly journals An [Fe4S4]3+–Alkyl Cluster Stabilized by an Expanded Scorpionate Ligand

2020 ◽  
Vol 142 (33) ◽  
pp. 14314-14323 ◽  
Author(s):  
Alex McSkimming ◽  
Arun Sridharan ◽  
Niklas B. Thompson ◽  
Peter Müller ◽  
Daniel L. M. Suess
Keyword(s):  
Scorpionate Ligand

NiII, CuII and ZnII complexes with a sterically hindered scorpionate ligand (TpmsPh) and catalytic application in the diasteroselective nitroaldol (Henry) reaction

2014 ◽  
Vol 43 (40) ◽  
pp. 15192-15200 ◽  
Author(s):  
Bruno G. M. Rocha ◽  
Tatiana C. O. Mac Leod ◽  
M. Fátima C. Guedes da Silva ◽  
Konstantin V. Luzyanin ◽  
Luísa M. D. R. S. Martins ◽  
...  
Keyword(s):  
Coordination Mode ◽  
Henry Reaction ◽  
Catalytic Application ◽  
Nitroaldol Reaction ◽  
Sterically Hindered ◽  
Scorpionate Ligand

The bulky (TpmsPh)− adapts its coordination mode to the electronic and steric preferences of the NiII, CuII or ZnII centre forming complexes which catalyse the nitroaldol reaction.

Photoinduced Reactivity of the Soft Hydrotris(6-tert-butyl-3-thiopyridazinyl)borate Scorpionate Ligand in Sodium, Potassium, and Thallium Salts

2015 ◽  
Vol 54 (17) ◽  
pp. 8168-8170 ◽  
Author(s):  
Michael Tüchler ◽  
Ferdinand Belaj ◽  
Georg Raber ◽  
Dmytro Neshchadin ◽  
Nadia C. Mösch-Zanetti
Keyword(s):  
Sodium Potassium ◽  
Tert Butyl ◽  
Scorpionate Ligand

scholarly journals Heavier group 2 metal complexes with a flexible scorpionate ligand based on 2-mercaptopyridine

RSC Advances ◽  
2015 ◽  
Vol 5 (63) ◽  
pp. 51413-51420 ◽  
Author(s):  
Kishor Naktode ◽  
Th. Dhileep N. Reddy ◽  
Hari Pada Nayek ◽  
Bhabani S. Mallik ◽  
Tarun K. Panda
Keyword(s):  
Metal Complexes ◽  
Alkaline Earth ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Structural Details ◽  
Group 2 ◽  
Scorpionate Ligand

Synthetic and structural details of flexible scorpionate ligand based on 2-mercaptopyridine (Bmp) supported heavier alkaline earth metal complexes with metal–sulfur bonds (metal = Sr, Ba) have been presented.

A New Perfluorinated F21-Tp Scorpionate Ligand: Enhanced Alkane Functionalization by Carbene Insertion with (F21-Tp)M Catalysts (M = Cu, Ag)

2008 ◽  
Vol 27 (18) ◽  
pp. 4779-4787 ◽  
Author(s):  
Emmanuelle Despagnet-Ayoub ◽  
Kane Jacob ◽  
Laure Vendier ◽  
Michel Etienne ◽  
Eleuterio Álvarez ◽  
...  
Keyword(s):  
Alkane Functionalization ◽  
Carbene Insertion ◽  
Scorpionate Ligand

Rare-Earth-Metal Methyl, Amide, and Imide Complexes Supported by a Superbulky Scorpionate Ligand

2014 ◽  
Vol 21 (2) ◽  
pp. 662-670 ◽  
Author(s):  
Dorothea Schädle ◽  
Cäcilia Maichle-Mössmer ◽  
Christoph Schädle ◽  
Reiner Anwander
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Scorpionate Ligand

Syntheses and crystal structures of lithium and niobium complexes containing a new type of monoanionic “scorpionate” ligand †

1999 ◽  
pp. 3537-3539 ◽  
Author(s):  
A. Otero ◽  
J. Fernández-Baeza ◽  
J. Tejeda ◽  
A. Antiñolo ◽  
F. Carrillo-Hermosilla ◽  
...  
Keyword(s):  
Crystal Structures ◽  
New Type ◽  
Niobium Complexes ◽  
Scorpionate Ligand

Coinage Metal Complexes of a Boron-Substituted Soft Scorpionate Ligand

2006 ◽  
Vol 45 (6) ◽  
pp. 2733-2741 ◽  
Author(s):  
Christopher A. Dodds ◽  
Mark Garner ◽  
John Reglinski ◽  
Mark D. Spicer
Keyword(s):  
Metal Complexes ◽  
Coinage Metal ◽  
Scorpionate Ligand

scholarly journals (Acetamide-κO){2,2′,2′′-boranetriyltris[6-tert-butyl-4-methylpyridazine-3(2H)-thione]-κ4 B,S,S′,S′′}copper(I) trifluoromethanesulfonate chloroform disolvate

IUCrData ◽  
2018 ◽  
Vol 3 (1) ◽  
Author(s):  
Stefan Holler ◽  
Ferdinand Belaj ◽  
Nadia C. Mösch-Zanetti
Keyword(s):  
Hydrogen Bond ◽  
Equatorial Plane ◽  
Complex Salt ◽  
Amide Group ◽  
Trigonal Bipyramid ◽  
Tert Butyl ◽  
Bifurcated Hydrogen Bond ◽  
Scorpionate Ligand

In the title solvated complex salt, [Cu(C27H39BN6S3)(C2H5NO)](CF3O3S)·2CHCl3, the CuI atom is coordinated by the three S atoms of the pyridazine-3-thione rings in the equatorial plane [Cu—S = 2.3072 (4)–2.3280 (4) Å] and the B atom of the scorpionate ligand and the O atom of an acetamide ligand as the apices of a trigonal bipyramid [Cu—B = 2.0456 (16) Å and Cu—O = 1.9957 (11) Å]. The amide group of the latter ligand is involved in a bifurcated hydrogen bond to the trifluoromethanesulfonate anion.

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