scholarly journals Tuning Catalytic Sites on Zr6O8 Metal–Organic Framework Nodes via Ligand and Defect Chemistry Probed with tert-Butyl Alcohol Dehydration to Isobutylene

2020 ◽  
Vol 142 (17) ◽  
pp. 8044-8056 ◽  
Author(s):  
Dong Yang ◽  
Carlo Alberto Gaggioli ◽  
Debmalya Ray ◽  
Melike Babucci ◽  
Laura Gagliardi ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Defect Chemistry ◽  
Butyl Alcohol ◽  
Alcohol Dehydration ◽  
Tert Butyl ◽  
Tert Butyl Alcohol ◽  
Catalytic Sites ◽  
Metal Organic ◽  
Organic Framework

Molecular Mobility of Tert‐butyl Alcohol Confined in a Breathing MIL‐53 (Al) Metal‐Organic Framework

ChemPhysChem ◽  
2020 ◽  
Vol 21 (17) ◽  
pp. 1951-1956
Author(s):  
Alexander E. Khudozhitkov ◽  
Alexander V. Toktarev ◽  
Sergei S. Arzumanov ◽  
Anton A. Gabrienko ◽  
Daniil I. Kolokolov ◽  
...  
Keyword(s):  
Molecular Mobility ◽  
Metal Organic Framework ◽  
Butyl Alcohol ◽  
Tert Butyl ◽  
Tert Butyl Alcohol ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Well-Defined Rhodium–Gallium Catalytic Sites in a Metal–Organic Framework: Promoter-Controlled Selectivity in Alkyne Semihydrogenation toE-Alkenes

2018 ◽  
Vol 140 (45) ◽  
pp. 15309-15318 ◽  
Author(s):  
Sai Puneet Desai ◽  
Jingyun Ye ◽  
Jian Zheng ◽  
Magali S. Ferrandon ◽  
Thomas E. Webber ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Catalytic Sites ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Facile isolation of a stable S6-symmetric methanol hexamer using the guest-free microporous metal-organic framework: zinc 5-tert-butyl isophthalate

2018 ◽  
Vol 233 (6) ◽  
pp. 429-435
Author(s):  
Samaila A. Jovial ◽  
James Raftery ◽  
Michael W. Anderson ◽  
Martin P. Attfield
Keyword(s):  
Metal Organic Framework ◽  
Structural Effect ◽  
Molecular Clusters ◽  
Ordered Structure ◽  
Framework Structure ◽  
Void Space ◽  
Tert Butyl ◽  
Metal Organic ◽  
Organic Framework

Abstract The ordered structure of the guest-free microporous metal-organic framework zinc 5-tert-butyl isophthalate {Zn[(CH3)3CC6H3(CO2)2]} has been determined and shown to be easily loaded with methanol to form {Zn[(CH3)3CC6H3(CO2)2]}·CH3OH. The methanol forms a S6-symmetric hexamer within the pores of the material that is uniquely defined by the void space and exerts a subtle structural effect on the framework structure of the host. The work demonstrates the use of this type of metal-organic framework as a matrix to isolate unique molecular clusters in a facile manner.

scholarly journals Tuning Zr12O22 Node Defects as Catalytic Sites in the Metal–Organic Framework hcp UiO-66

ACS Catalysis ◽  
2020 ◽  
Vol 10 (5) ◽  
pp. 2906-2914 ◽  
Author(s):  
Xi Chen ◽  
Yinghui Lyu ◽  
Zhengyan Wang ◽  
Xu Qiao ◽  
Bruce C. Gates ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Catalytic Sites ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Origin of highly active metal–organic framework catalysts: defects? Defects!

2016 ◽  
Vol 45 (10) ◽  
pp. 4090-4099 ◽  
Author(s):  
J. Canivet ◽  
M. Vandichel ◽  
D. Farrusseng
Keyword(s):  
Metal Organic Framework ◽  
Comprehensive Review ◽  
Highly Active ◽  
Active Metal ◽  
Catalytic Sites ◽  
Metal Organic ◽  
Organic Framework

This article provides a comprehensive review of the nature of catalytic sites in MOFs.

scholarly journals Dialing in Catalytic Sites on Metal Organic Framework Nodes: MIL-53(Al) and MIL-68(Al) Probed with Methanol Dehydration Catalysis

2020 ◽  
Vol 12 (47) ◽  
pp. 53537-53546
Author(s):  
Zhengyan Wang ◽  
Melike Babucci ◽  
Yafeng Zhang ◽  
Yujie Wen ◽  
Luming Peng ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Methanol Dehydration ◽  
Catalytic Sites ◽  
Metal Organic ◽  
Organic Framework
Sign in / Sign up

Export Citation Format

Share Document