Subcomponent Self-Assembly of Covalent Metallacycles Templated by Catalytically Active Seven-Coordinate Transition Metal Centers

2020 ◽  
Vol 142 (16) ◽  
pp. 7283-7288 ◽  
Author(s):  
Zhi-Wei Li ◽  
Xin Wang ◽  
Lian-Qiang Wei ◽  
Ivana Ivanović-Burmazović ◽  
Gao-Feng Liu
Keyword(s):  
Transition Metal ◽  
Self Assembly ◽  
Metal Centers ◽  
Catalytically Active

scholarly journals Aggregation of catalytically active Ru nanoparticles to inactive bulk, monitored in situ during an allylic isomerization reaction. Influence of solvent, surfactant and stirring

RSC Advances ◽  
2018 ◽  
Vol 8 (3) ◽  
pp. 1481-1492 ◽  
Author(s):  
M. Hitrik ◽  
Y. Sasson
Keyword(s):  
Transition Metal ◽  
Self Assembly ◽  
Isomerization Reaction ◽  
Bulk Metal ◽  
Ru Nanoparticles ◽  
Catalytically Active ◽  
Influence Of Solvent

To explain the decay of the activity of Ru-NPs catalysts, that formed in situ during allylic isomerization, we add a new step to a classic mechanism of transition-metal NPs self-assembly: the aggregation of two catalytically active NPs (C) to inactive bulk-metal (D).

Methane activation by ZSM-5-supported transition metal centers

2021 ◽  
Author(s):  
Daniyal Kiani ◽  
Sagar Sourav ◽  
Yadan Tang ◽  
Jonas Baltrusaitis ◽  
Israel E. Wachs
Keyword(s):  
Transition Metal ◽  
Methane Activation ◽  
Group V ◽  
Metal Centers ◽  
Methane Dehydroaromatization

The literature on methane dehydroaromatization (MDA) to benzene using ZSM-5 supported, group V–VIII transition metal-based catalysts (MOx/ZSM-5) is critically reviewed with a focus on in situ and operando molecular insights.

Dioxygen splitting at room temperature over distant binuclear transition metal centers in zeolites for direct oxidation of methane to methanol

2021 ◽  
Author(s):  
Kinga Mlekodaj ◽  
Mariia Lemishka ◽  
Stepan Sklenak ◽  
Jiri Dedecek ◽  
Edyta Tabor
Keyword(s):  
Transition Metal ◽  
Room Temperature ◽  
Direct Oxidation ◽  
Metal Centers ◽  
Oxidation Of Methane ◽  
First Time

Here we demonstrate for the first time the splitting of dioxygen at RT over distant binuclear transition metal (M = Ni, Mn, and Co) centers stabilized in ferrierite zeolite. Cleaved...

First-principles screening of single transition metal atoms anchored on two-dimensional C9N4 for the nitrogen reduction reaction

2021 ◽  
Vol 23 (14) ◽  
pp. 8784-8791
Author(s):  
Qingling Meng ◽  
Ling Zhang ◽  
Jinge Wu ◽  
Shuwei Zhai ◽  
Xiamin Hao ◽  
...  
Keyword(s):  
Nitrogen Fixation ◽  
Transition Metal ◽  
First Principles ◽  
Reduction Reaction ◽  
Single Atom ◽  
Two Dimensional ◽  
Metal Atoms ◽  
Transition Metal Atoms ◽  
Catalytically Active ◽  
Single Transition

Theoretical screening of transition metal atoms anchored on monolayer C9N4 as highly stable, catalytically active and selective single-atom catalysts for nitrogen fixation.

New self-assembly hybrid compounds based on arsenic–vanadium clusters and transition metal mixed-organic-ligand complexes

CrystEngComm ◽  
2016 ◽  
Vol 18 (4) ◽  
pp. 566-579 ◽  
Author(s):  
Hai-Yang Guo ◽  
Zhi-Fang Li ◽  
Xiao Zhang ◽  
Li-Wei Fu ◽  
Yang-Yang Hu ◽  
...  
Keyword(s):  
Transition Metal ◽  
Self Assembly ◽  
Organic Ligand ◽  
Hybrid Compounds ◽  
Novel Structures

Seven compounds exhibiting novel structures constructed from arsenic–vanadium polyoxoanions and metal mixed-organic-ligand complexes have been synthesized and characterized.

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