A Computational Study of Reductive Elimination Reactions to Form C−H Bonds from Pt(II) and Pt(IV) Centers. Why Does Ligand Loss Precede Reductive Elimination from Six-Coordinate but Not Four-Coordinate Platinum?

2000 ◽  
Vol 122 (7) ◽  
pp. 1456-1465 ◽  
Author(s):  
Kevin L. Bartlett ◽  
Karen I. Goldberg ◽  
Weston Thatcher Borden
Keyword(s):  
Computational Study ◽  
Reductive Elimination ◽  
Elimination Reactions

scholarly journals Force-modulated reductive elimination from platinum(ii) diaryl complexes

2021 ◽  
Author(s):  
Yichen Yu ◽  
Chenxu Wang ◽  
Liqi Wang ◽  
Cai-Li Sun ◽  
Roman Boulatov ◽  
...  
Keyword(s):  
Transition State ◽  
Reductive Elimination ◽  
Mechanical Force ◽  
Elimination Reactions

The influence of mechanical force on the rates of model reductive elimination reactions depends on the structure of the force-transducing ligand and provides a measure of geometry changes upon reaching the transition state.

Diverse mechanisms of carbon-hydrogen bond formation through binuclear reductive elimination reactions

1982 ◽  
Vol 104 (2) ◽  
pp. 619-621 ◽  
Author(s):  
Mario J. Nappa ◽  
Roberto Santi ◽  
Steven P. Diefenbach ◽  
Jack Halpern
Keyword(s):  
Hydrogen Bond ◽  
Bond Formation ◽  
Reductive Elimination ◽  
Hydrogen Bond Formation ◽  
Elimination Reactions

Computational Study of the Palladium-Catalyzed Carbonylative Synthesis of Aromatic Acid Chlorides: The Synergistic Effect of Pt Bu3 and CO on Reductive Elimination

2016 ◽  
Vol 22 (42) ◽  
pp. 15107-15118 ◽  
Author(s):  
Jeffrey S. Quesnel ◽  
Salvador Moncho ◽  
Kai E. O. Ylijoki ◽  
Gerardo Martin Torres ◽  
Edward N. Brothers ◽  
...  
Keyword(s):  
Synergistic Effect ◽  
Computational Study ◽  
Reductive Elimination ◽  
Aromatic Acid ◽  
Acid Chlorides ◽  
Palladium Catalyzed

scholarly journals Carbon–sulfur bond formation by reductive elimination of gold(iii) thiolates

2018 ◽  
Vol 47 (18) ◽  
pp. 6333-6343 ◽  
Author(s):  
Lucy Currie ◽  
Luca Rocchigiani ◽  
David L. Hughes ◽  
Manfred Bochmann
Keyword(s):  
Bond Formation ◽  
Reductive Elimination ◽  
Pincer Complexes ◽  
Elimination Reactions ◽  
Sulfur Bond

Thiols were found to cleave Au–C bonds in (C^N^C)gold(iii) pincer complexes and to induce C–S reductive elimination reactions, to give aryl thioethers.

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