Helical Chirality Induction by Point Chirality at Helix Terminal

1999 ◽  
Vol 121 (4) ◽  
pp. 754-759 ◽  
Author(s):  
Tadashi Mizutani ◽  
Shigeyuki Yagi ◽  
Tomoko Morinaga ◽  
Tetsutaro Nomura ◽  
Toru Takagishi ◽  
...  
Inorganics ◽  
2018 ◽  
Vol 6 (4) ◽  
pp. 111
Author(s):  
Toshiyuki Moriuchi ◽  
Satoshi Ohmura ◽  
Takayo Moriuchi-Kawakami

Considerable attention has been given to the research field of bioorganometallic chemistry, which is a hybrid chemistry field between biology and organometallic chemistry. The introduction of biomolecules, which have hydrogen bonding sites and chiral centers, into organometallic compounds is a promising strategy to construct chirality-organized bioorganometallic conjugates. This feature paper sketches an outline of induction of helical chirality into bioorganometallic conjugates by the control of a torsional twist of the organometallic moiety. Topics covered included control of the helical chirality of 1,n′-disubstituted ferrocene moieties in ferrocene-dipeptide conjugates, and the chirality induction of the Au(I)–Au(I) axis in the dinuclear organogold(I)-uracil conjugates.


1998 ◽  
Vol 63 (24) ◽  
pp. 8769-8784 ◽  
Author(s):  
Tadashi Mizutani ◽  
Shigeyuki Yagi ◽  
Atsushi Honmaru ◽  
Shinji Murakami ◽  
Masaru Furusyo ◽  
...  

Author(s):  
Toshiyuki Moriuchi ◽  
Satoshi D. Ohmura ◽  
Takayo Moriuchi-Kawakami

Considerable attention has been given to the research field of bioorganometallic chemistry, which is a hybrid chemistry field between biology and organometallic chemistry. The introduction of biomolecules, which have hydrogen bonding sites and chiral centers, into organometallic compounds is considered to be a promising strategy to construct chirality-organized bioorganometallic conjugates. This feature paper sketches an outline of induction of helical chirality into bioorganometallic conjugates. Topics covered include control of the helical chirality of 1,n’-disubstituted ferrocene moieties in ferrocene-dipeptide conjugates and the chirality induction of the Au(I)–Au(I) axis in the dinuclear organogold(I)-uracil conjugates.


2005 ◽  
Vol 109 (28) ◽  
pp. 13445-13450 ◽  
Author(s):  
Wenyong Duan ◽  
Shu Kitamura ◽  
Ichiro Uechi ◽  
Akio Katsuki ◽  
Yoshifumi Tanimoto

2017 ◽  
Vol 55 (15) ◽  
pp. 2458-2466 ◽  
Author(s):  
Yan Zhang ◽  
Jingang Hu ◽  
Guang Yang ◽  
Hongli Zhang ◽  
Qijin Zhang ◽  
...  
Keyword(s):  

2018 ◽  
Vol 54 (95) ◽  
pp. 13447-13450 ◽  
Author(s):  
Qi Lin ◽  
Lei Gao ◽  
Brice Kauffmann ◽  
Jiajia Zhang ◽  
Chunmiao Ma ◽  
...  
Keyword(s):  

The helical chirality can be tuned by both the size and number of anion guests.


Sign in / Sign up

Export Citation Format

Share Document