Physical Organic Chemistry of Transition Metal Carbene Complexes. 12.1Spectroscopic Detection and Kinetic Characterization of the Intermediate in the Nucleophilic Substitution Reaction of (CO)5CrC(OCH3)Ph with Thiolate Ions in Aqueous Acetonitrile

Claude F. Bernasconi; Francis X. Flores; Kevin W. Kittredge

doi:10.1021/ja9812655

Physical Organic Chemistry of Transition Metal Carbene Complexes. 12.1Spectroscopic Detection and Kinetic Characterization of the Intermediate in the Nucleophilic Substitution Reaction of (CO)5CrC(OCH3)Ph with Thiolate Ions in Aqueous Acetonitrile

Journal of the American Chemical Society ◽

10.1021/ja9812655 ◽

1998 ◽

Vol 120 (31) ◽

pp. 7983-7984 ◽

Cited By ~ 5

Author(s):

Claude F. Bernasconi ◽

Francis X. Flores ◽

Kevin W. Kittredge

Keyword(s):

Organic Chemistry ◽

Transition Metal ◽

Nucleophilic Substitution ◽

Substitution Reaction ◽

Kinetic Characterization ◽

Physical Organic Chemistry ◽

Carbene Complexes ◽

Aqueous Acetonitrile ◽

Physical Organic

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Physical Organic Chemistry of Transition Metal Carbene Complexes. 27.†Substituent Effects on the Nucleophilic Substitution of [Aryl(thiomethyl)carbene]pentacarbonylchromium(0) Complexes by Amines in Aqueous Acetonitrile

Organometallics ◽

10.1021/om020955l ◽

2003 ◽

Vol 22 (6) ◽

pp. 1310-1313 ◽

Cited By ~ 9

Author(s):

Claude F. Bernasconi ◽

Santanu Bhattacharya

Keyword(s):

Organic Chemistry ◽

Transition Metal ◽

Nucleophilic Substitution ◽

Substituent Effects ◽

Physical Organic Chemistry ◽

Carbene Complexes ◽

Aqueous Acetonitrile ◽

Physical Organic

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Physical Organic Chemistry of Transition Metal Carbene Complexes. 8.1Kinetic and Thermodynamic Acidities of Alkoxyalkylcarbene Pentacarbonyl Complexes of Cr, Mo, and W in Aqueous Acetonitrile. Dependence on Metal, Alkyl Group, and Alkoxy Group

Organometallics ◽

10.1021/om960936+ ◽

1997 ◽

Vol 16 (9) ◽

pp. 1926-1932 ◽

Cited By ~ 13

Author(s):

Claude F. Bernasconi ◽

Weitao Sun

Keyword(s):

Organic Chemistry ◽

Transition Metal ◽

Alkyl Group ◽

Alkoxy Group ◽

Physical Organic Chemistry ◽

Carbene Complexes ◽

Aqueous Acetonitrile ◽

Physical Organic

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Physical Organic Chemistry of Transition Metal Carbene Complexes. 25. Kinetic and Thermodynamic Acidities of Substituted (Methylthiophenylcarbene)pentacarbonyl Tungsten(0) and (Benzoxymethylcarbene)pentacarbonyl Tungsten(0) in Aqueous Acetonitrile. Evidence for Transition State Imbalances†

Journal of the American Chemical Society ◽

10.1021/ja020665w ◽

2002 ◽

Vol 124 (50) ◽

pp. 14968-14976 ◽

Cited By ~ 11

Author(s):

Claude F. Bernasconi ◽

Viola Ruddat

Keyword(s):

Organic Chemistry ◽

Transition Metal ◽

Transition State ◽

Physical Organic Chemistry ◽

Carbene Complexes ◽

Aqueous Acetonitrile ◽

Physical Organic

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Physical Organic Chemistry of Transition Metal Carbene Complexes. 9.1Thermodynamic and Kinetic Acidity of (2-Oxacyclopentylidene)pentacarbonylchromium(0) in Aqueous Acetonitrile

Journal of the American Chemical Society ◽

10.1021/ja964069b ◽

1997 ◽

Vol 119 (22) ◽

pp. 5169-5175 ◽

Cited By ~ 13

Author(s):

Claude F. Bernasconi ◽

Aquiles E. Leyes

Keyword(s):

Organic Chemistry ◽

Transition Metal ◽

Physical Organic Chemistry ◽

Carbene Complexes ◽

Aqueous Acetonitrile ◽

Physical Organic ◽

Kinetic Acidity

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Physical Organic Chemistry of Transition Metal Carbene Complexes. 22.1Substituent Effects on the Reversible Cyclization of Fischer Carbene Complexes (CO)5WC(SCH2CH2OH)C6H4Z in Aqueous Acetonitrile

Organometallics ◽

10.1021/om010364f ◽

2001 ◽

Vol 20 (16) ◽

pp. 3383-3389 ◽

Cited By ~ 5

Author(s):

Claude F. Bernasconi ◽

Mahammad Ali

Keyword(s):

Organic Chemistry ◽

Transition Metal ◽

Physical Organic Chemistry ◽

Fischer Carbene Complexes ◽

Carbene Complexes ◽

Aqueous Acetonitrile ◽

Fischer Carbene ◽

Physical Organic ◽

Reversible Cyclization

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Physical organic chemistry of transition metal carbene complexes. 2. Kinetics and mechanism of reactions of [methoxy(phenyl)carbene]pentacarbonylchromium(0) with primary aliphatic amines in aqueous acetonitrile

Journal of the American Chemical Society ◽

10.1021/ja00057a017 ◽

1993 ◽

Vol 115 (4) ◽

pp. 1341-1346 ◽

Cited By ~ 23

Author(s):

Claude F. Bernasconi ◽

Michael W. Stronach

Keyword(s):

Organic Chemistry ◽

Transition Metal ◽

Kinetics And Mechanism ◽

Aliphatic Amines ◽

Physical Organic Chemistry ◽

Carbene Complexes ◽

Aqueous Acetonitrile ◽

Physical Organic ◽

Primary Aliphatic Amines

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Physical Organic Chemistry of Transition Metal Carbene Complexes. 6. Kinetics and Mechanism of the Thermal and Photochemical Hydrolysis of (CO)5M:C(OMe)CH2Ph (M = Cr, W) in Aqueous Acetonitrile

Organometallics ◽

10.1021/om00012a030 ◽

1995 ◽

Vol 14 (12) ◽

pp. 5615-5621 ◽

Cited By ~ 6

Author(s):

Claude F. Bernasconi ◽

Weitao Sun

Keyword(s):

Organic Chemistry ◽

Transition Metal ◽

Kinetics And Mechanism ◽

Physical Organic Chemistry ◽

Carbene Complexes ◽

Aqueous Acetonitrile ◽

Physical Organic ◽

Hydrolysis Of

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ChemInform Abstract: Physical Organic Chemistry of Transition Metal Carbene Complexes. Part 11. Kinetics and Mechanism of the Hydrolysis of (2-Oxacyclopentylidene) pentacarbonylchromium(0) in Aqueous Acetonitrile.

ChemInform ◽

10.1002/chin.199748219 ◽

2010 ◽

Vol 28 (48) ◽

pp. no-no

Author(s):

C. F. BERNASCONI ◽

A. E. LEYES

Keyword(s):

Organic Chemistry ◽

Transition Metal ◽

Kinetics And Mechanism ◽

Physical Organic Chemistry ◽

Carbene Complexes ◽

Aqueous Acetonitrile ◽

Physical Organic ◽

Hydrolysis Of

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ChemInform Abstract: Physical Organic Chemistry of Transition-Metal Carbene Complexes. Part 10. Opposing Effects of α-Alkyl Groups on the Thermodynamic and Kinetic Acidities of (CO)5Cr=C(OMe)CHR′R′′-Type Fischer Carbene Complexes in Aqueous Acetonitrile.

ChemInform ◽

10.1002/chin.199741100 ◽

2010 ◽

Vol 28 (41) ◽

pp. no-no

Author(s):

C. F. BERNASCONI ◽

W. SUN ◽

L. GARCIA-RIO ◽

K. YAN ◽

K. KITTREDGE

Keyword(s):

Organic Chemistry ◽

Transition Metal ◽

Physical Organic Chemistry ◽

Fischer Carbene Complexes ◽

Carbene Complexes ◽

Aqueous Acetonitrile ◽

Fischer Carbene ◽

Physical Organic ◽

Alkyl Groups ◽

Opposing Effects

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Physical Organic Chemistry of Transition Metal Carbene Complexes. 13.1Kinetics of Proton Transfer from (5-Methyl-2-oxacyclopentylidene)pentacarbonylchromium(0) and Hydrolysis of Its Conjugate Anion in Aqueous Acetonitrile

Organometallics ◽

10.1021/om980444s ◽

1998 ◽

Vol 17 (23) ◽

pp. 4940-4945 ◽

Cited By ~ 6

Author(s):

Claude F. Bernasconi ◽

Aquiles E. Leyes ◽

Luis García-Río

Keyword(s):

Organic Chemistry ◽

Transition Metal ◽

Proton Transfer ◽

Physical Organic Chemistry ◽

Carbene Complexes ◽

Aqueous Acetonitrile ◽

Physical Organic ◽

Hydrolysis Of

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