A New Class of Self-Assembled Monolayers: closo-B12H11S3-on Gold

1998 ◽  
Vol 120 (38) ◽  
pp. 9961-9962 ◽  
Author(s):  
Laura J. Yeager ◽  
Fusayo Saeki ◽  
Kenneth Shelly ◽  
M. Frederick Hawthorne ◽  
Robin L. Garrell
2014 ◽  
Vol 69 (11-12) ◽  
pp. 1164-1180 ◽  
Author(s):  
Philipp Stock ◽  
Andreas Erbe ◽  
Manfred Buck ◽  
Dennis Wiedemann ◽  
Hervé Ménard ◽  
...  

Abstract The formation of self-assembled monolayers (SAMs) on Au(111) from solution has been investigated for two ionic iron(II) complexes of the type [Fe(L)](BF4)2, where L is tripodal hexadentate and contains three thiocyanate anchor groups. The ligands (L1, L2; donor set: N6) are obtained by Schiff base condensation of a tripodal triamine (L1: tris-(2-aminoethyl)amine, ‘tren’; L2: 1,1′,1″- trimethyl(thiophosphoryl)trihydrazide) with 5-(4-thiocyanatobutoxy) pyridine-2-carbaldehyde. Layers of the complexes adsorbed on Au(111) from methanol solution have been characterised using scanning tunnelling microscopy (STM), infrared reflectance absorbance (IRRAS), X-ray photoelectron (XPS) and UV=Vis reflectance spectroscopies, as well as ellipsometry. Complex [Fe(L1)](BF4)2 deposits intact on a gold surface and retains its optical addressability. Elaboration of this result may provide access to a new class of self-assembled layers, employing salt-like tripodal coordination compounds with thiocyanate anchors. The second complex, [Fe(L2)](BF4)2, which contains a sulphur atom in the ligand backbone, is not sufficiently stable under the same conditions.


1992 ◽  
Vol 114 (4) ◽  
pp. 1514-1515 ◽  
Author(s):  
C. Wade Sheen ◽  
Jing Xuan Shi ◽  
Jan Maartensson ◽  
Atul N. Parikh ◽  
David L. Allara

ChemInform ◽  
2010 ◽  
Vol 30 (2) ◽  
pp. no-no
Author(s):  
L. J. YEAGER ◽  
F. SAEKI ◽  
K. SHELLY ◽  
M. F. HAWTHORNE ◽  
R. L. GARRELL

ChemInform ◽  
2010 ◽  
Vol 23 (23) ◽  
pp. no-no
Author(s):  
C. W. SHEEN ◽  
J.-X. SHI ◽  
J. MARTENSSON ◽  
A. N. PARIKH ◽  
D. L. ALLARA

1998 ◽  
Vol 95 (6) ◽  
pp. 1339-1342 ◽  
Author(s):  
R. Michalitsch ◽  
A. El Kassmi ◽  
P. Lang ◽  
A. Yassar ◽  
F. Garnier

2003 ◽  
Vol 104 ◽  
pp. 459-462 ◽  
Author(s):  
R. Klauser ◽  
M. Zharnikov ◽  
I.-H. Hong ◽  
S.-C. Wang ◽  
A. Gölzhäuser ◽  
...  

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