Self-Assembled Monolayers Stabilized by Three-Dimensional Networks of Hydrogen Bonds

1998 ◽  
Vol 120 (10) ◽  
pp. 2486-2487 ◽  
Author(s):  
Robert S. Clegg ◽  
Scott M. Reed ◽  
James E. Hutchison
Keyword(s):  
Hydrogen Bonds ◽  
Three Dimensional ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Self Assembled

Self-assembled monolayers as two-dimensional crystals: relationship to three-dimensional crystals

CrystEngComm ◽  
2007 ◽  
Vol 9 (2) ◽  
pp. 176-180 ◽  
Author(s):  
Edwin C. Constable ◽  
Marc Häusler ◽  
B. A. Hermann ◽  
Catherine E. Housecroft ◽  
Markus Neuburger ◽  
...  
Keyword(s):  
Three Dimensional ◽  
Self Assembled Monolayers ◽  
Two Dimensional ◽  
Assembled Monolayers ◽  
Self Assembled

Strong Hydrogen Bonds at the Interface between Proton-Donating and -Accepting Self-Assembled Monolayers on Au(111)

Langmuir ◽  
2018 ◽  
Vol 34 (5) ◽  
pp. 2189-2197 ◽  
Author(s):  
Hiroyuki S. Kato ◽  
Shinya Yoshimoto ◽  
Akira Ueda ◽  
Susumu Yamamoto ◽  
Yusuke Kanematsu ◽  
...  
Keyword(s):  
Hydrogen Bonds ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Self Assembled

Analysis of structures with saturated hydrogen bonding

2007 ◽  
Vol 63 (1) ◽  
pp. 132-141 ◽  
Author(s):  
James H. Loehlin ◽  
Elizabeth L. N. Okasako
Keyword(s):  
Hydrogen Bond ◽  
Hydrogen Bonding ◽  
Hydrogen Bonds ◽  
Self Assembled Monolayers ◽  
Donor And Acceptor ◽  
Assembled Monolayers ◽  
Graph Set ◽  
Hydrogen Bond Patterns ◽  
Self Assembled ◽  
Acceptor Numbers

All simple structures with saturated hydrogen bonding (SHB) are classified into eight categories on the basis of the donor and acceptor numbers on the atoms at each end of the hydrogen bonds. Examples from the literature are included where known, along with seven structures investigated as part of this study (five have SHB). Graph-set descriptions of the hydrogen-bond patterns are given for each of these structures and for some selected literature examples. The structures presented are: piperazine (I), morpholinium chloride (II) and iodide (III) [(II) and (III) are not SHB], three 1:1 cocrystals of diols with 1,4-phenylenediamine (PDA) – PDA·1,8-octane diol (IV), PDA·1,10-decane diol (V), and PDA·1,12-dodecane diol (VI) and 6-amino-1-hexanol (VII). This study discusses some structures that show limitations of the graph-set model, along with possible suggestions to cover these limitations. The cocrystalline PDA·aliphatic diol structures may provide details applicable to the structure of self-assembled monolayers of aliphatic thiol molecules on Au(111) surfaces.

scholarly journals Self-assembled monolayers (SAMs) of carboxylic acids: an overview

2011 ◽  
Vol 9 (3) ◽  
pp. 369-378 ◽  
Author(s):  
Sushilkumar Jadhav
Keyword(s):  
Surface Modification ◽  
Carboxylic Acids ◽  
Organic Compounds ◽  
Efficient Method ◽  
Three Dimensional ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Self Assembled

AbstractThe field of self-assembled monolayers (SAMs) of organic compounds on different substrates is of importance because it provides a suitable and efficient method of surface modification. The formation of robust, stable monolayers from carboxylic acids on two and three dimensional surfaces of different substrates have been reported. Carboxylic acids are promising class of organic compounds for monolayer formations where traditional alkanethiols or alkoxysilanes show limitations.

Sign in / Sign up

Export Citation Format

Share Document