The Effect of Pressure on Cyclizations. The Ring-Size Dependent Reaction Volumes of the Cyclization of 1-Alkenes to Cycloalkanes. Experimental Measurement of Activation and Reaction Volumes of the Intramolecular Diels−Alder Reaction of 1,3,8-Nonatriene and 1,3,9-Decatriene. Temperature Dependence of Activation and Reaction Volumes

1998 ◽  
Vol 120 (25) ◽  
pp. 6212-6218 ◽  
Author(s):  
Matthias K. Diedrich ◽  
Frank-Gerrit Klärner
Keyword(s):  
Temperature Dependence ◽  
Experimental Measurement ◽  
Alder Reaction ◽  
Diels Alder ◽  
Ring Size ◽  
Effect Of Pressure ◽  
Size Dependent ◽  
Diels Alder Reaction ◽  
Reaction Volumes

Effect of pressure on the rate of the Diels-Alder reaction of diethyl azodicarboxylate with 9,10-dimethylanthracene

2014 ◽  
Vol 50 (4) ◽  
pp. 489-493 ◽  
Author(s):  
V. D. Kiselev ◽  
D. A. Kornilov ◽  
E. A. Kashaeva ◽  
L. N. Potapova ◽  
A. I. Konovalov
Keyword(s):  
Alder Reaction ◽  
Diels Alder ◽  
Effect Of Pressure ◽  
Diels Alder Reaction ◽  
Diethyl Azodicarboxylate

Diels-Alder reaction volumes in the solid state and solution

2004 ◽  
Vol 53 (11) ◽  
pp. 2490-2495 ◽  
Author(s):  
V. D. Kiselev ◽  
G. G. Iskhakova ◽  
E. A. Kashaeva ◽  
L. N. Potapova ◽  
A. I. Konovalov
Keyword(s):  
Solid State ◽  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction ◽  
Reaction Volumes

Vinylindenes and some heteroanalogues in the Diels-Alder reaction. VIII. 1-Benzyl-3-vinylindole as a diene

1981 ◽  
Vol 34 (7) ◽  
pp. 1483 ◽  
Author(s):  
JD Lambert ◽  
QN Porter
Keyword(s):  
Maleic Anhydride ◽  
Temperature Dependence ◽  
Alder Reaction ◽  
Diels Alder ◽  
Coupling Constants ◽  
Diels Alder Reaction ◽  
Benzyl Methylene

1-Benzyl-3-vinylindole gives stable adducts resulting from [2+4] cycloadditions with 1,4-benzo-quinone, 1,4-naphthoquinone, N- phenylmaleimide and maleic anhydride. Vicinal 1H n.m.r. coupling constants for protons on the cyclohexene rings are used to show that the first two adducts probably have half-chair conformations, while the last have boat conformations. Non-equivalence of the benzyl methylene protons of the benzoquinone adduct has been shown to display a surprising temperature dependence. The adduct of the vinylindole and ethenetetracarbonitrile is shown to be a cyclobutane resulting from a [2+2] cycloaddition.

The Effect of Pressure on the Diels-Alder Reaction

1974 ◽  
Vol 47 (9) ◽  
pp. 2242-2246 ◽  
Author(s):  
Kazuyoshi Seguchi ◽  
Akira Sera ◽  
Kazuhiro Maruyama
Keyword(s):  
Alder Reaction ◽  
Diels Alder ◽  
Effect Of Pressure ◽  
Diels Alder Reaction
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