Palladium-Catalyzed Direct α-Arylation of Ketones. Rate Acceleration by Sterically Hindered Chelating Ligands and Reductive Elimination from a Transition Metal Enolate Complex

1997 ◽  
Vol 119 (50) ◽  
pp. 12382-12383 ◽  
Author(s):  
Blake C. Hamann ◽  
John F. Hartwig
Keyword(s):  
Transition Metal ◽  
Reductive Elimination ◽  
Chelating Ligands ◽  
Rate Acceleration ◽  
Palladium Catalyzed ◽  
Sterically Hindered

scholarly journals Photolytic Reductive Elimination of White Phosphorus from a Mononuclear cyclo ‐P 4 Transition Metal Complex

2018 ◽  
Vol 131 (6) ◽  
pp. 1793-1797 ◽  
Author(s):  
Kyle A. Mandla ◽  
Curtis E. Moore ◽  
Arnold L. Rheingold ◽  
Joshua S. Figueroa
Keyword(s):  
Transition Metal ◽  
Metal Complex ◽  
Transition Metal Complex ◽  
Reductive Elimination ◽  
White Phosphorus

Computational Study of the Palladium-Catalyzed Carbonylative Synthesis of Aromatic Acid Chlorides: The Synergistic Effect of Pt Bu3 and CO on Reductive Elimination

2016 ◽  
Vol 22 (42) ◽  
pp. 15107-15118 ◽  
Author(s):  
Jeffrey S. Quesnel ◽  
Salvador Moncho ◽  
Kai E. O. Ylijoki ◽  
Gerardo Martin Torres ◽  
Edward N. Brothers ◽  
...  
Keyword(s):  
Synergistic Effect ◽  
Computational Study ◽  
Reductive Elimination ◽  
Aromatic Acid ◽  
Acid Chlorides ◽  
Palladium Catalyzed

One-pot transition-metal free transamidation to sterically hindered amides

2018 ◽  
Vol 5 (20) ◽  
pp. 2950-2954 ◽  
Author(s):  
Weijie Guo ◽  
Jingjun Huang ◽  
Hongxiang Wu ◽  
Tingting Liu ◽  
Zhongfeng Luo ◽  
...  
Keyword(s):  
Transition Metal ◽  
Good Yield ◽  
One Pot ◽  
Metal Free ◽  
Highly Efficient ◽  
Sterically Hindered

A highly efficient one-pot transamidation of primary amides has been developed under transition-metal free conditions, generating a variety of amides including hindered amides in good yield (up to 86%) catalyzed by CsF.

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