Synthesis of Optically Active α-Hydroxy Carbonyl Compounds by the Catalytic, Enantioselective Oxidation of Silyl Enol Ethers and Ketene Acetals with (Salen)manganese(III) Complexes

Waldemar Adam; Rainer T. Fell; Veit R. Stegmann; Chantu R. Saha-Möller

doi:10.1021/ja9726668

Synthesis of Optically Active α-Hydroxy Carbonyl Compounds by the Catalytic, Enantioselective Oxidation of Silyl Enol Ethers and Ketene Acetals with (Salen)manganese(III) Complexes

Journal of the American Chemical Society ◽

10.1021/ja9726668 ◽

1998 ◽

Vol 120 (4) ◽

pp. 708-714 ◽

Cited By ~ 96

Author(s):

Waldemar Adam ◽

Rainer T. Fell ◽

Veit R. Stegmann ◽

Chantu R. Saha-Möller

Keyword(s):

Carbonyl Compounds ◽

Optically Active ◽

Enol Ethers ◽

Enantioselective Oxidation ◽

Silyl Enol Ethers ◽

Ketene Acetals

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ChemInform Abstract: Synthesis of Optically Active α-Hydroxy Carbonyl Compounds by the Catalytic, Enantioselective Oxidation of Silyl Enol Ethers and Ketene Acetals with (Salen)manganese(III) Complexes.

ChemInform ◽

10.1002/chin.199825104 ◽

2010 ◽

Vol 29 (25) ◽

pp. no-no

Author(s):

W. ADAM ◽

R. T. FELL ◽

V. R. STEGMANN ◽

C. R. SAHA-MOELLER

Keyword(s):

Carbonyl Compounds ◽

Optically Active ◽

Enol Ethers ◽

Enantioselective Oxidation ◽

Silyl Enol Ethers ◽

Ketene Acetals

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Oxygenation of Silyl Enol Ethers and Silyl Ketene Acetals with Molecular Oxygen and Aldehyde Catalyzed by Nickel(II) Complex. A Convenient Method for the Preparation of α-Hydroxy Carbonyl Compounds

Chemistry Letters ◽

10.1246/cl.1991.281 ◽

1991 ◽

Vol 20 (2) ◽

pp. 281-284 ◽

Cited By ~ 35

Author(s):

Toshihiro Takai ◽

Tohru Yamada ◽

Oliver Rhode ◽

Teruaki Mukaiyama

Keyword(s):

Molecular Oxygen ◽

Convenient Method ◽

Carbonyl Compounds ◽

Enol Ethers ◽

Silyl Enol Ethers ◽

Ketene Acetals ◽

Silyl Ketene Acetals

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ChemInform Abstract: Synthesis of Optically Active α-Hydroxy Ketones by Enantioselective Oxidation of Silyl Enol Ethers with a Fructose-Derived Dioxirane.

ChemInform ◽

10.1002/chin.199828106 ◽

2010 ◽

Vol 29 (28) ◽

pp. no-no

Author(s):

W. ADAM ◽

R. T. FELL ◽

C. R. SAHA-MOELLER ◽

C.-G. ZHAO

Keyword(s):

Optically Active ◽

Enol Ethers ◽

Enantioselective Oxidation ◽

Silyl Enol Ethers ◽

Hydroxy Ketones

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α-Allylation of Carbonyl Compounds via Silyl Enol Ethers and Silyl Ketene Acetals using a Hypervalent Iodine Reagent†

Journal of Chemical Research Synopses ◽

10.1039/a701224a ◽

1997 ◽

pp. 262-263 ◽

Cited By ~ 9

Author(s):

Robert M. Moriarty ◽

Widanagamage R. Epa ◽

Om Prakash

Keyword(s):

Carbonyl Compounds ◽

Hypervalent Iodine ◽

Enol Ethers ◽

Silyl Enol Ethers ◽

Ketene Acetals ◽

Silyl Ketene Acetals

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ChemInform Abstract: α-Allylation of Carbonyl Compounds via Silyl Enol Ethers and Silyl Ketene Acetals Using a Hypervalent Iodine Reagent.

ChemInform ◽

10.1002/chin.199748068 ◽

2010 ◽

Vol 28 (48) ◽

pp. no-no

Author(s):

R. M. MORIARTY ◽

W. R. EPA ◽

O. PRAKASH

Keyword(s):

Carbonyl Compounds ◽

Hypervalent Iodine ◽

Enol Ethers ◽

Silyl Enol Ethers ◽

Ketene Acetals ◽

Silyl Ketene Acetals

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Synthesis of optically active α-hydroxy ketones by enantioselective oxidation of silyl enol ethers with a fructose-derived dioxirane

Tetrahedron Asymmetry ◽

10.1016/s0957-4166(98)00005-6 ◽

1998 ◽

Vol 9 (3) ◽

pp. 397-401 ◽

Cited By ~ 51

Author(s):

Waldemar Adam ◽

Rainer T. Fell ◽

Chantu R. Saha-Möller ◽

Cong-Gui Zhao

Keyword(s):

Optically Active ◽

Enol Ethers ◽

Enantioselective Oxidation ◽

Silyl Enol Ethers ◽

Hydroxy Ketones

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Clay Montmorillonite: An Efficient, Heterogeneous Catalyst for Michael Reactions of Silyl Ketene Acetals and Silyl Enol Ethers with α,β-Unsaturated Carbonyl Compounds

Bulletin of the Chemical Society of Japan ◽

10.1246/bcsj.61.2157 ◽

1988 ◽

Vol 61 (6) ◽

pp. 2157-2164 ◽

Cited By ~ 49

Author(s):

Motomitsu Kawai ◽

Makoto Onaka ◽

Yusuke Izumi

Keyword(s):

Heterogeneous Catalyst ◽

Carbonyl Compounds ◽

Enol Ethers ◽

Silyl Enol Ethers ◽

Michael Reactions ◽

Ketene Acetals ◽

Silyl Ketene Acetals ◽

Efficient Heterogeneous Catalyst

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Synthesis of optically active α-hydroxycarbonyl compounds by (salen)Mn(III)-catalyzed oxidation of silyl enol ethers and silyl ketene acetals

Tetrahedron Letters ◽

10.1016/0040-4039(96)01441-4 ◽

1996 ◽

Vol 37 (36) ◽

pp. 6531-6534 ◽

Cited By ~ 31

Author(s):

Waldemar Adam ◽

Rainer T. Fell ◽

Cordula Mock-Knoblauch ◽

Chatu R. Saha-Möller

Keyword(s):

Optically Active ◽

Enol Ethers ◽

Silyl Enol Ethers ◽

Ketene Acetals ◽

Silyl Ketene Acetals ◽

Catalyzed Oxidation

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ChemInform Abstract: Clay Montmorillonite: An Efficient, Heterogeneous Catalyst for Michael Reactions of Silyl Ketene Acetals and Silyl Enol Ethers with α,β-Unsaturated Carbonyl Compounds.

ChemInform ◽

10.1002/chin.198843125 ◽

1988 ◽

Vol 19 (43) ◽

Author(s):

M. KAWAI ◽

M. ONAKA ◽

Y. IZUMI

Keyword(s):

Heterogeneous Catalyst ◽

Carbonyl Compounds ◽

Enol Ethers ◽

Silyl Enol Ethers ◽

Michael Reactions ◽

Ketene Acetals ◽

Silyl Ketene Acetals ◽

Efficient Heterogeneous Catalyst

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ChemInform Abstract: Oxygenation of Silyl Enol Ethers (I) and Silyl Ketene Acetals (III) with Molecular Oxygen and Aldehyde Catalyzed by Nickel(II) Complex. A Convenient Method for the Preparation of α-Hydroxy Carbonyl Compounds (II), (IV).

ChemInform ◽

10.1002/chin.199244092 ◽

2010 ◽

Vol 23 (44) ◽

pp. no-no

Author(s):

T. TAKAI ◽

Y. YAMADA ◽

O. RHODE ◽

T. MUKAIYAMA

Keyword(s):

Molecular Oxygen ◽

Convenient Method ◽

Carbonyl Compounds ◽

Enol Ethers ◽

Silyl Enol Ethers ◽

Ketene Acetals ◽

Silyl Ketene Acetals

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