C−H Activation at Pt(II) To Form Stable Pt(IV) Alkyl Hydrides

1997 ◽  
Vol 119 (42) ◽  
pp. 10235-10236 ◽  
Author(s):  
Douglas D. Wick ◽  
Karen I. Goldberg
Keyword(s):  
Alkyl Hydrides

UV photoelectron spectra of group IV alkyl hydrides

1980 ◽  
Vol 18 (1) ◽  
pp. 153-159 ◽  
Author(s):  
G. Beltram ◽  
T.P. Fehlner ◽  
K. Mochida ◽  
J.K. Kochi
Keyword(s):  
Group Iv ◽  
Photoelectron Spectra ◽  
Alkyl Hydrides

scholarly journals Cover Picture: High-Pressure Raman and Calorimetry Studies of Vanadium(III) Alkyl Hydrides for Kubas-Type Hydrogen Storage (ChemPhysChem 6/2016)

ChemPhysChem ◽  
2016 ◽  
Vol 17 (6) ◽  
pp. 778-778 ◽  
Author(s):  
Leah Morris ◽  
Michel L. Trudeau ◽  
Daniel Reed ◽  
David Book ◽  
David M. Antonelli
Keyword(s):  
High Pressure ◽  
Hydrogen Storage ◽  
And Calorimetry ◽  
Alkyl Hydrides

High-Pressure Raman and Calorimetry Studies of Vanadium(III) Alkyl Hydrides for Kubas-Type Hydrogen Storage

ChemPhysChem ◽  
2016 ◽  
Vol 17 (6) ◽  
pp. 822-828 ◽  
Author(s):  
Leah Morris ◽  
Michel L. Trudeau ◽  
Daniel Reed ◽  
David Book ◽  
David M. Antonelli
Keyword(s):  
High Pressure ◽  
Hydrogen Storage ◽  
And Calorimetry ◽  
Alkyl Hydrides

Approaches to alkane functionalization with Tp′Pt and (nacnac)Pt reagents

2009 ◽  
Vol 87 (1) ◽  
pp. 288-296 ◽  
Author(s):  
Nathan M West ◽  
Joseph L Templeton
Keyword(s):  
Oxidation State ◽  
Coordination Mode ◽  
Reductive Elimination ◽  
Binding Modes ◽  
Acid Base ◽  
The Past ◽  
Alkane Functionalization ◽  
Tightly Coupled ◽  
Scorpionate Ligand ◽  
Alkyl Hydrides

In this perspective article we give an overview of our studies of C–H activation with platinum over the past decade. The scorpionate ligand Tp′ (Tp′ = hydrotris(3,5-dimethylpyrazolyl)borate) has exhibited the ability to stabilize both Pt(IV) and Pt(II) complexes due to flexibility between κ3 and κ2 binding modes. Control of the Tp′ coordination mode and Pt oxidation state is tightly coupled with acid/base chemistry. This ability allowed us to model a spectrum of intermediates in C–H activation reactions, including Pt(IV) alkyl hydrides, five-coordinate Pt(IV) silyl hydrides, and Pt(II) benzene complexes. We have been able to observe sturdy Pt(II) benzene complexes and probe their equilibria with the respective C–H activated Pt(IV) species in the presence of an added ligand. We have also taken steps toward functionalizing hydrocarbons with Tp′Pt by dehydrogenation of alkanes and by arylation of olefins. We have recently turned to bidentate nacnac (nacnac = N-phenyl-β-enamineimine) ligands in the hopes of catalytically functionalizing hydrocarbons.Key words: C–H activation, reductive elimination, Tp′Pt, five-coordinate, β-diiminate.

Anionic d8 Alkyl Hydrides - Selective Formation and Reactivity of Anionic cis-PtII Methyl Hydride

2010 ◽  
Vol 2010 (13) ◽  
pp. 1991-1999 ◽  
Author(s):  
Elena Poverenov ◽  
Mark A. Iron ◽  
Mark Gandelman ◽  
Yehoshoa Ben-David ◽  
David Milstein
Keyword(s):  
Selective Formation ◽  
Alkyl Hydrides

Hydrogenation of d0 complexes: zirconium(IV) alkyl hydrides

1978 ◽  
Vol 100 (10) ◽  
pp. 3246-3248 ◽  
Author(s):  
Kerrie I. Gell ◽  
Jeffrey Schwartz
Keyword(s):  
Alkyl Hydrides
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