PrototropicvsWhole Water Exchange Contributions to the Solvent Relaxation Enhancement in the Aqueous Solution of a Cationic Gd3+Macrocyclic Complex

1997 ◽  
Vol 119 (20) ◽  
pp. 4767-4768 ◽  
Author(s):  
Silvio Aime ◽  
Alessandro Barge ◽  
Mauro Botta ◽  
David Parker ◽  
Alvaro S. De Sousa
Keyword(s):  
Aqueous Solution ◽  
Water Exchange ◽  
Macrocyclic Complex ◽  
Solvent Relaxation

Structure and water exchange of the hydrated thiosulfate ion in aqueous solution using QMCF MD simulation and large angle X-ray scattering

2014 ◽  
Vol 43 (33) ◽  
pp. 12711-12720 ◽  
Author(s):  
Lars Eklund ◽  
Tomas S. Hofer ◽  
Alexander K. H. Weiss ◽  
Andreas O. Tirler ◽  
Ingmar Persson
Keyword(s):  
Aqueous Solution ◽  
Sulfur Atom ◽  
Md Simulation ◽  
Water Exchange ◽  
Large Angle ◽  
Sulfate Ion ◽  
Simulation Data ◽  
X Ray ◽  
X Ray Scattering ◽  
Hydration Structure

Experimental and simulation data of the thiosulfate ion show large similarities in hydration structure and mechanism with the sulfate ion but with weaker hydration of the terminal sulfur atom in thiosulfate.

Water Exchange Dynamics of Lithium(I) Ion in Aqueous Solution

2006 ◽  
Vol 110 (11) ◽  
pp. 5690-5696 ◽  
Author(s):  
Hannes H. Loeffler ◽  
Yasuhiro Inada ◽  
Shigenobu Funahashi
Keyword(s):  
Aqueous Solution ◽  
Water Exchange

Theoretical exploration of the water exchange mechanism of the polyoxocation GaO4Al12(OH)24(H2O)127+ in aqueous solution

2009 ◽  
Vol 73 (6) ◽  
pp. 1588-1596 ◽  
Author(s):  
Zhaosheng Qian ◽  
Hui Feng ◽  
Zhenjiang Zhang ◽  
Wenjing Yang ◽  
Miao Wang ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Water Exchange ◽  
Exchange Mechanism ◽  
Water Exchange Mechanism

Rates of Water Exchange for Two Cobalt(II) Heteropolyoxotungstate Compounds in Aqueous Solution

2011 ◽  
Vol 17 (16) ◽  
pp. 4408-4417 ◽  
Author(s):  
C. André Ohlin ◽  
Stephen J. Harley ◽  
J. Gregory McAlpin ◽  
Rosalie K. Hocking ◽  
Brandon Q. Mercado ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Water Exchange

Water exchange on [Gd(H2O)8]3+ and [Gd(PDTA)(H2O)2]- in aqueous solution: A variable-pressure, -temperature and -magnetic field17O NMR study

1993 ◽  
Vol 31 (11) ◽  
pp. 1011-1020 ◽  
Author(s):  
Károly Micskei ◽  
D. Hugh Powell ◽  
Lothar Helm ◽  
Ernö Brücher ◽  
André E. Merbach
Keyword(s):  
Aqueous Solution ◽  
Water Exchange ◽  
Variable Pressure ◽  
Nmr Study

scholarly journals Structure and water exchange dynamics of hydrated oxo halo ions in aqueous solution using QMCF MD simulation, large angle X-ray scattering and EXAFS

2015 ◽  
Vol 44 (4) ◽  
pp. 1816-1828 ◽  
Author(s):  
Lars Eklund ◽  
Tomas S. Hofer ◽  
Ingmar Persson
Keyword(s):  
Aqueous Solution ◽  
Md Simulation ◽  
Water Exchange ◽  
Pure Water ◽  
Large Angle ◽  
Water Molecules ◽  
Surrounding Water ◽  
X Ray ◽  
X Ray Scattering ◽  
Ray Methods

The structure and water exchange dynamics of the hydrated oxo halo ions in aqueous solution, studied by QMCF MD simulation and experimental X-ray methods, show that they are all structure breakers, thus the hydrogen bonding between the ion and surrounding water molecules is weaker than between water molecules in pure water.

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