Kinetics and Mechanism of Reversible Oxidative Addition of Hydrogen across the Metal−Metal Bond of (μ-H)2Ru3(CO)8(μ-P(t-Bu)2)2. Steric Promotion of Metal−Metal Bond Cleavage But a CO Dissociative Mechanism

1996 ◽  
Vol 118 (47) ◽  
pp. 11805-11812 ◽  
Author(s):  
Fred J. Safarowic ◽  
David J. Bierdeman ◽  
Jerome B. Keister
Keyword(s):  
Bond Cleavage ◽  
Oxidative Addition ◽  
Kinetics And Mechanism ◽  
Dissociative Mechanism ◽  
Metal Bond ◽  
Metal Metal

Ultrafast studies of metal-metal bond cleavage in Fe3(CO)12 in solution

1995 ◽  
Vol 229 (1-2) ◽  
pp. 469-471 ◽  
Author(s):  
N.J. Tro ◽  
J.C. King ◽  
C.B. Harris
Keyword(s):  
Bond Cleavage ◽  
Metal Bond ◽  
Metal Metal

Reductive elimination of [AlH2]+ from a cationic Ga-Al dihydride

2021 ◽  
Author(s):  
Jun Okuda ◽  
Louis J. Morris ◽  
Laurent Maron ◽  
Ambre Carpentier
Keyword(s):  
Oxidative Addition ◽  
Reductive Elimination ◽  
Metal Bond ◽  
Metal Metal

Oxidative addition of TMEDA-supported [AlH2]+ to [{BDI}Ga] (BDI = {HC(C(CH3)N(2,6-iPr2-C6H3))2) provides [{BDI}Ga(H)-Al(H)(tmeda)]¬[B(C6H3-3,5-Me2)4] (TMEDA = N,N,N’N’-tetramethylethylene¬diamine) with a covalent metal-metal bond. The reaction is readily reversed by substituting TMEDA for an...

Metal-metal bond cleavage in [Cp(CO)2Fe-Fe(CO)2Cp] under the action of organotellurium(IV)tribromides

2012 ◽  
Vol 38 (3) ◽  
pp. 219-223 ◽  
Author(s):  
Y. V. Torubaev ◽  
A. V. Pavlova ◽  
A. A. Pasynskii
Keyword(s):  
Bond Cleavage ◽  
Metal Bond ◽  
Metal Metal
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