Ligand Field Circular Dichroism and Magnetic Circular Dichroism Studies of Component B and Substrate Binding to the Hydroxylase Component of Methane Monooxygenase

1997 ◽  
Vol 119 (2) ◽  
pp. 387-395 ◽  
Author(s):  
Sabine Coates Pulver ◽  
Wayne A. Froland ◽  
John D. Lipscomb ◽  
Edward I. Solomon
Keyword(s):  
Circular Dichroism ◽  
Magnetic Circular Dichroism ◽  
Substrate Binding ◽  
Methane Monooxygenase ◽  
Ligand Field ◽  
Circular Dichroïsm

Magnetic circular dichroism spectra of cobalt(III) amine complexes of photochemical importance

1985 ◽  
Vol 63 (7) ◽  
pp. 1918-1921 ◽  
Author(s):  
Bryan R. Hollebone ◽  
Cooper H. Langford ◽  
Aramice Y. S. Malkhasian
Keyword(s):  
Circular Dichroism ◽  
Magnetic Circular Dichroism ◽  
High Energy ◽  
Absorption Feature ◽  
Ligand Field ◽  
Circular Dichroism Spectra ◽  
Ligand Field Parameters ◽  
Circular Dichroïsm ◽  
Best Fit ◽  
Magnetic Circular Dichroism Spectra

Magnetic circular dichroism spectra of several acidoamine cobalt(III) complexes are reported which reveal B terms for the spin allowed bands and A terms for the spin forbidden bands. It is shown that ligand field parameters derived from fitting of a full set of spin forbidden bands, including the quintet, gives Racah B and C electron repulsion parameters closer to those anticipated from theory than has been common using mainly the singlets and a single weak low energy absorption feature assigned to a triplet. The spectra indicate that the quintet which has figured in numerous photochemical speculations lies at relatively high energy. This conclusion is a consequence of both the recognition of an A term assignable to the quintet and the best fit ligand field parameters for all bands.

scholarly journals Soft x-ray absorption spectroscopy and magnetic circular dichroism as operando probes of complex oxide electrolyte gate transistors

2020 ◽  
Vol 116 (20) ◽  
pp. 201905
Author(s):  
Biqiong Yu ◽  
Guichuan Yu ◽  
Jeff Walter ◽  
Vipul Chaturvedi ◽  
Joseph Gotchnik ◽  
...  
Keyword(s):  
Circular Dichroism ◽  
Absorption Spectroscopy ◽  
Magnetic Circular Dichroism ◽  
Complex Oxide ◽  
X Ray ◽  
X Ray Absorption ◽  
Circular Dichroïsm ◽  
Oxide Electrolyte
Sign in / Sign up

Export Citation Format

Share Document