Catalytic Carbon−Carbon and Carbon−Hydrogen Bond Cleavage in Lower Alkanes. Low-Temperature Hydroxylations and Hydroxycarbonylations with Dioxygen as the Oxidant

1996 ◽  
Vol 118 (19) ◽  
pp. 4574-4580 ◽  
Author(s):  
Minren Lin ◽  
Terrence E. Hogan ◽  
Ayusman Sen
Keyword(s):  
Hydrogen Bond ◽  
Low Temperature ◽  
Bond Cleavage

scholarly journals Carbon-Hydrogen Bond Activation of Phenyldi(2- Thienyl)Phosphine at A Triruthenium Cluster Center

2012 ◽  
Vol 25 (1) ◽  
pp. 1-6 ◽  
Author(s):  
Shahed Rana ◽  
Shishir Ghosh ◽  
Shariff E Kabir
Keyword(s):  
Hydrogen Bond ◽  
Elemental Analysis ◽  
Bond Activation ◽  
Bond Cleavage ◽  
Chemical Society ◽  
Cluster Center ◽  
Carbon Hydrogen Bond Activation

Ketyl-initiated reaction between Ru3(CO)12 and phenyldi(2-thienyl)phosphine (PhPTh2) furnished simple phosphine-substituted triruthenium clusters [Ru3(CO)10(PhPTh2)21 and [Ru3(CO)9(PhPTh2)3] 2. Heating 1 in boiling benzene afforded [Ru3(CO)8{?3- PhThP(C4H2S)}(PhPTh2)] 3 by carbon-hydrogen bond cleavage of a coordinated thienylphosphine ligand. All three new clusters have been characterized by elemental analysis, IR and NMR spectroscopic data.DOI: http://dx.doi.org/10.3329/jbcs.v25i1.11764 Journal of Bangladesh Chemical Society, Vol. 25(1), 1-6, 2012

Dimerization and solvent-assisted proton dislocation in the low-barrier hydrogen bond of a Mannich base: a low-temperature NMR study

2001 ◽  
Vol 39 (S1) ◽  
pp. S81-S90 ◽  
Author(s):  
Maria Rospenk ◽  
Lucjan Sobczyk ◽  
Parwin Schah-Mohammedi ◽  
Hans-Heinrich Limbach ◽  
Nicolai S. Golubev ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Low Temperature ◽  
Mannich Base ◽  
Nmr Study

Phosphorus–hydrogen bond cleavage on a Ph2PH-substituted μ3-thioxo dicobalt–iron cluster as a route to bridging phosphido and thiophosphine ligands

2002 ◽  
Vol 642 (1-2) ◽  
pp. 227-236 ◽  
Author(s):  
Jason D King ◽  
Martin J Mays ◽  
Chi-Yu Mo ◽  
Gregory A Solan ◽  
Gráinne Conole ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Bond Cleavage ◽  
Iron Cluster
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