In Situ Generated Bulky Palladium Hydride Complexes as Catalysts for the Efficient Isomerization of Olefins. Selective Transformation of Terminal Alkenes to 2-Alkenes

2010 ◽  
Vol 132 (23) ◽  
pp. 7998-8009 ◽  
Author(s):  
Delphine Gauthier ◽  
Anders T. Lindhardt ◽  
Esben P. K. Olsen ◽  
Jacob Overgaard ◽  
Troels Skrydstrup
Keyword(s):  
Palladium Hydride ◽  
Hydride Complexes ◽  
Selective Transformation ◽  
Terminal Alkenes

ChemInform Abstract: In situ Generated Bulky Palladium Hydride Complexes as Catalysts for the Efficient Isomerization of Olefins. Selective Transformation of Terminal Alkenes to 2-Alkenes.

ChemInform ◽  
2010 ◽  
Vol 41 (39) ◽  
pp. no-no
Author(s):  
Delphine Gauthier ◽  
Anders T. Lindhardt ◽  
Esben P. K. Olsen ◽  
Jacob Overgaard ◽  
Troels Skrydstrup
Keyword(s):  
Palladium Hydride ◽  
Hydride Complexes ◽  
Selective Transformation ◽  
Terminal Alkenes

Rh(III) catalyzed allylic C-H amidation of unactivated alkenes with in situ generated iminoiodinanes

2021 ◽  
Author(s):  
Masilamani Jeganmohan ◽  
Pinki Sihag
Keyword(s):  
Terminal Alkenes

A Rh(III) catalyzed allylic C H amidation of substituted alkenes with in situ generated iminoiodinanes is demonstrated. The present protocol is compatible with differently functionalized unactivated terminal alkenes and internal...

Facile synthesis of air-stable heterobimetallic osmium-silver hydride complexes

2021 ◽  
Author(s):  
Haiyu Zhou ◽  
Tongtong Bai ◽  
Yanlin Pan ◽  
Yongliang Wei ◽  
Tongdao Wang
Keyword(s):  
Synthesis And Characterization ◽  
Facile Synthesis ◽  
Hydride Complexes

The synthesis and characterization of air-stable heterobimetallic Os-Ag hydrides were described. All of the new heterobimetallic Os-Ag hydrides are neutral, and the in-situ generated and presynthesized cis-[Os](H)-C≡C-R units in these...

Formation of palladium hydride nanoparticles in Pd/C catalyst as evidenced by in situ XAS data

2009 ◽  
Vol 58 (2) ◽  
pp. 280-283 ◽  
Author(s):  
A. Yu. Stakheev ◽  
I. C. Mashkovskii ◽  
O. P. Tkachenko ◽  
K. V. Klementiev ◽  
W. Grünert ◽  
...  
Keyword(s):  
Palladium Hydride ◽  
In Situ Xas

Tethered NHC Ligands for Stereoselective Alkyne Semihydrogenations

Synthesis ◽  
2017 ◽  
Vol 49 (11) ◽  
pp. 2470-2482 ◽  
Author(s):  
Felix Pape ◽  
Johannes Teichert
Keyword(s):  
Selective Transformation ◽  
Internal Alkynes

A copper(I)-catalyzed semihydrogenation of internal alkynes has been developed. A variety of oxygen- and nitrogen-tethered N-heterocyclic carbene (NHC) complexes have been investigated, leading to a highly Z-selective transformation. The catalyst is generated from inexpensive copper(I) chloride in situ and allows catalytic semihydrogenation down to 10 bar H2.

Fe–S Catalyst Generated In Situ from Fe(III)- and S3•–-Promoted Aerobic Oxidation of Terminal Alkenes

2021 ◽  
Author(s):  
Jing-Jing Ai ◽  
Bei-Bei Liu ◽  
Jian Li ◽  
Fei Wang ◽  
Cheng-Mi Huang ◽  
...  
Keyword(s):  
Aerobic Oxidation ◽  
Terminal Alkenes
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