In Situ Single-Crystal Diffraction Studies of the Structural Transition of Metal−Organic Framework Copper 5-Sulfoisophthalate, Cu-SIP-3

2010 ◽  
Vol 132 (10) ◽  
pp. 3605-3611 ◽  
Author(s):  
Phoebe K. Allan ◽  
Bo Xiao ◽  
Simon J. Teat ◽  
Jason W. Knight ◽  
Russell E. Morris
Keyword(s):  
Single Crystal ◽  
Structural Transition ◽  
Metal Organic Framework ◽  
Single Crystal Diffraction ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Enhanced proton conductivity in a flexible metal–organic framework promoted by single-crystal-to-single-crystal transformation

2021 ◽  
Vol 57 (1) ◽  
pp. 65-68
Author(s):  
Xi Chen ◽  
Zhongyue Zhang ◽  
Jin Chen ◽  
Sergei Sapchenko ◽  
Xue Han ◽  
...  
Keyword(s):  
Single Crystal ◽  
Proton Conductivity ◽  
Structural Transition ◽  
Metal Organic Framework ◽  
Crystal Transformation ◽  
P Transformation ◽  
Metal Organic ◽  
Flexible Metal ◽  
Organic Framework

Transformation of MFM-722(Pb)-DMA to MFM-722(Pb)-H2O leads to an increase in proton conductivity linked to a structural transition.

scholarly journals Structural characterization of framework–gas interactions in the metal–organic framework Co2(dobdc) by in situ single-crystal X-ray diffraction

2017 ◽  
Vol 8 (6) ◽  
pp. 4387-4398 ◽  
Author(s):  
Miguel I. Gonzalez ◽  
Jarad A. Mason ◽  
Eric D. Bloch ◽  
Simon J. Teat ◽  
Kevin J. Gagnon ◽  
...  
Keyword(s):  
Single Crystal ◽  
Structural Characterization ◽  
Metal Organic Framework ◽  
X Ray Diffraction ◽  
X Ray ◽  
Metal Organic ◽  
Gas Interactions ◽  
Organic Framework

In situ single-crystal X-ray diffraction experiments enable the direct observation of weak metal–gas interactions in a metal–organic framework.

A versatile environmental control cell forin situguest exchange single-crystal diffraction

2015 ◽  
Vol 48 (2) ◽  
pp. 578-581 ◽  
Author(s):  
Jordan M. Cox ◽  
Ian M. Walton ◽  
Cassidy A. Benson ◽  
Yu-Sheng Chen ◽  
Jason B. Benedict
Keyword(s):  
Single Crystal ◽  
Gas Flow ◽  
Environmental Control ◽  
Metal Organic Framework ◽  
Control Cell ◽  
Single Crystal Sample ◽  
Single Crystal Diffraction ◽  
Crystal Sample ◽  
Metal Organic

In situsingle-crystal diffraction experiments provide researchers with the opportunity to study the response of crystalline systems, including metal–organic frameworks and other nanoporous materials, to changing local microenvironments. This paper reports a new environmental control cell that is remarkably easy to use, completely reusable, and capable of delivering static or dynamic vacuum, liquids or gases to a single-crystal sample. Furthermore the device is nearly identical in size to standard single-crystal mounts so a full unrestricted range of motion is expected for most commercial goniometers.In situsingle-crystal X-ray diffraction experiments performed under dynamic gas-flow conditions revealed the cell was capable of stabilizing a novel metastable intermediate in the dehydration reaction of a previously reported metal–organic framework.

scholarly journals Backbonding contributions to small molecule chemisorption in a metal–organic framework with open copper(i) centers

2021 ◽  
Author(s):  
Gregory M. Su ◽  
Han Wang ◽  
Brandon R. Barnett ◽  
Jeffrey R. Long ◽  
David Prendergast ◽  
...  
Keyword(s):  
Fine Structure ◽  
Small Molecule ◽  
Metal Organic Framework ◽  
X Ray ◽  
Metal Site ◽  
Absorption Fine ◽  
Metal Organic ◽  
X Ray Absorption ◽  
Organic Framework

In situ near edge X-ray absorption fine structure spectroscopy directly probes unoccupied states associated with backbonding interactions between the open metal site in a metal–organic framework and various small molecule guests.

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