Electrochemical Proton-Coupled Electron Transfer of an Osmium Aquo Complex: Theoretical Analysis of Asymmetric Tafel Plots and Transfer Coefficients

2010 ◽  
Vol 132 (4) ◽  
pp. 1234-1235 ◽  
Author(s):  
Michelle K. Ludlow ◽  
Alexander V. Soudackov ◽  
Sharon Hammes-Schiffer
Keyword(s):  
Electron Transfer ◽  
Theoretical Analysis ◽  
Transfer Coefficients ◽  
Proton Coupled Electron Transfer ◽  
Aquo Complex

Theoretical Analysis of Proton Relays in Electrochemical Proton-Coupled Electron Transfer

2011 ◽  
Vol 133 (21) ◽  
pp. 8282-8292 ◽  
Author(s):  
Benjamin Auer ◽  
Laura E. Fernandez ◽  
Sharon Hammes-Schiffer
Keyword(s):  
Electron Transfer ◽  
Theoretical Analysis ◽  
Proton Coupled Electron Transfer

scholarly journals Theoretical analysis of the inverted region in photoinduced proton-coupled electron transfer

2019 ◽  
Vol 216 ◽  
pp. 363-378 ◽  
Author(s):  
Zachary K. Goldsmith ◽  
Alexander V. Soudackov ◽  
Sharon Hammes-Schiffer
Keyword(s):  
Electron Transfer ◽  
Theoretical Analysis ◽  
Energy Conversion ◽  
Rate Constant ◽  
Inverted Region ◽  
Significant Challenge ◽  
Proton Coupled Electron Transfer ◽  
Wide Range ◽  
Design Systems

Photoinduced proton-coupled electron transfer (PCET) plays a key role in a wide range of energy conversion processes, and understanding how to design systems to control the PCET rate constant is a significant challenge.

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