Pd Nanoparticles Embedded into a Metal-Organic Framework: Synthesis, Structural Characteristics, and Hydrogen Sorption Properties

2010 ◽  
Vol 132 (9) ◽  
pp. 2991-2997 ◽  
Author(s):  
Claudia Zlotea ◽  
Renato Campesi ◽  
Fermin Cuevas ◽  
Eric Leroy ◽  
Philippe Dibandjo ◽  
...  
Keyword(s):  
Structural Characteristics ◽  
Metal Organic Framework ◽  
Pd Nanoparticles ◽  
Sorption Properties ◽  
Hydrogen Sorption ◽  
Metal Organic ◽  
Organic Framework

Synthesis and Hydrogen Sorption Properties of Carborane Based Metal−Organic Framework Materials

2007 ◽  
Vol 129 (42) ◽  
pp. 12680-12681 ◽  
Author(s):  
Omar K. Farha ◽  
Alexander M. Spokoyny ◽  
Karen L. Mulfort ◽  
M. Frederick Hawthorne ◽  
Chad A. Mirkin ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Sorption Properties ◽  
Hydrogen Sorption ◽  
Framework Materials ◽  
Metal Organic ◽  
Organic Framework

Nanopore Structure and Sorption Properties of Cu−BTC Metal−Organic Framework

Nano Letters ◽  
2003 ◽  
Vol 3 (6) ◽  
pp. 713-718 ◽  
Author(s):  
Aleksey Vishnyakov ◽  
Peter I. Ravikovitch ◽  
Alexander V. Neimark ◽  
Martin Bülow ◽  
Qing Min Wang
Keyword(s):  
Metal Organic Framework ◽  
Sorption Properties ◽  
Metal Organic ◽  
Nanopore Structure ◽  
Structure And Sorption Properties ◽  
Organic Framework

scholarly journals In Situ Time-Resolved Decomposition of β-Hydride Phase in Palladium Nanoparticles Coated with Metal-Organic Framework

Metals ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 810
Author(s):  
Mikhail V. Kirichkov ◽  
Aram L. Bugaev ◽  
Alina A. Skorynina ◽  
Vera V. Butova ◽  
Andriy P. Budnyk ◽  
...  
Keyword(s):  
Phase Transition ◽  
Particle Size ◽  
Hydrogen Adsorption ◽  
Metal Organic Framework ◽  
Pd Nanoparticles ◽  
Time Resolved ◽  
Metal Organic ◽  
Hydride Phases ◽  
Organic Framework

The formation of palladium hydrides is a well-known phenomenon, observed for both bulk and nanosized samples. The kinetics of hydrogen adsorption/desorption strongly depends on the particle size and shape, as well as the type of support and/or coating of the particles. In addition, the structural properties of hydride phases and their distribution also depend on the particle size. In this work, we report on the in situ characterization of palladium nanocubes coated with HKUST-1 metal-organic framework (Pd@HKUST-1) during desorption of hydrogen by means of synchrotron-based time-resolved X-ray powder diffraction. A slower hydrogen desorption, compared to smaller sized Pd nanoparticles was observed. Rietveld refinement of the time-resolved data revealed the remarkable stability of the lattice parameters of α- and β-hydride phases of palladium during the α- to β- phase transition, denoting the behavior more similar to the bulk materials than nanoparticles. The stability in the crystal sizes for both α- and β-hydride phases during the phase transition indicates that no sub-domains are formed within a single particle during the phase transition.

Understanding Hydrogen Sorption in In-soc-MOF: A Charged Metal-Organic Framework with Open-Metal Sites, Narrow Channels, and Counterions

2015 ◽  
Vol 15 (3) ◽  
pp. 1460-1471 ◽  
Author(s):  
Tony Pham ◽  
Katherine A. Forrest ◽  
Adam Hogan ◽  
Brant Tudor ◽  
Keith McLaughlin ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Hydrogen Sorption ◽  
Narrow Channels ◽  
Open Metal Sites ◽  
Metal Organic ◽  
Organic Framework

Understanding Hydrogen Sorption in a Metal–Organic Framework with Open-Metal Sites and Amide Functional Groups

2013 ◽  
Vol 117 (18) ◽  
pp. 9340-9354 ◽  
Author(s):  
Tony Pham ◽  
Katherine A. Forrest ◽  
Patrick Nugent ◽  
Youssef Belmabkhout ◽  
Ryan Luebke ◽  
...  
Keyword(s):  
Functional Groups ◽  
Metal Organic Framework ◽  
Hydrogen Sorption ◽  
Open Metal Sites ◽  
Metal Organic ◽  
Organic Framework

Flexibility in metal-organic framework materials: Impact on sorption properties

2005 ◽  
Vol 178 (8) ◽  
pp. 2491-2510 ◽  
Author(s):  
Ashleigh J. Fletcher ◽  
K. Mark Thomas ◽  
Matthew J. Rosseinsky
Keyword(s):  
Metal Organic Framework ◽  
Sorption Properties ◽  
Framework Materials ◽  
Metal Organic ◽  
Organic Framework
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