scholarly journals Charge Density-Dependent Modifications of Hydration Shell Waters by Hofmeister Ions

2009 ◽  
Vol 131 (31) ◽  
pp. 11010-11018 ◽  
Author(s):  
Feng Guo ◽  
Joel M. Friedman
Keyword(s):  
Charge Density ◽  
Hydration Shell ◽  
Density Dependent

Charge-Density-Dependent Partitioning of Cs+and K+into Nickel Hexacyanoferrate Matrixes

Langmuir ◽  
2002 ◽  
Vol 18 (9) ◽  
pp. 3620-3625 ◽  
Author(s):  
Kavita M. Jeerage ◽  
William A. Steen ◽  
Daniel T. Schwartz
Keyword(s):  
Charge Density ◽  
Nickel Hexacyanoferrate ◽  
Density Dependent

Non-Gaussian elasticity and charge density-dependent swelling of strong polyelectrolyte poly(N-isopropylacrylamide-co-sodium acrylate) hydrogels

Soft Matter ◽  
2017 ◽  
Vol 13 (47) ◽  
pp. 9046-9059
Author(s):  
Nermin Orakdogen ◽  
Talin Boyacı
Keyword(s):  
Elastic Modulus ◽  
Charge Density ◽  
Density Dependence ◽  
Sodium Acrylate ◽  
Density Dependent ◽  
Volume Dependence ◽  
Non Gaussian

The charge density dependence of swelling and volume dependence of the elastic modulus were investigated with a predicted course of non-Gaussian elasticity ofN-isopropylacrylamide-based hydrogels.

Operation Mechanism of Organic Electrochemical Transistors as Redox Chemical Transducers

2021 ◽  
Author(s):  
Siew Ting Melissa Tan ◽  
Scott Keene ◽  
Alexander Giovannitti ◽  
Armantas Melianas ◽  
Maximilian Moser ◽  
...  
Keyword(s):  
Charge Density ◽  
Operation Mechanism ◽  
Density Dependent ◽  
Redox Active ◽  
Electrochemical Redox ◽  
Redox Sensors ◽  
Mixed Ionic Electronic Conductors ◽  
Chemical Transducers ◽  
Electronic Conductors ◽  
Organic Electrochemical Transistors

The ability to control the charge density of organic mixed ionic electronic conductors (OMIECs) via reactions with redox-active analytes has enabled applications as electrochemical redox sensors. Their charge density-dependent conductivity...

scholarly journals On the elusive anti-bayerite structure

2020 ◽  
Author(s):  
Georgios S.E. Antipas
Keyword(s):  
Density Functional Theory ◽  
Hydrogen Bonds ◽  
Charge Density ◽  
Density Functional ◽  
Hydration Shell ◽  
Isomer Ratio ◽  
Energy Decomposition ◽  
Functional Theory ◽  
Deformation Density ◽  
A Charge

Sequential deprotonation of the Cr3+ hexahydrate in an alkaline environment up to the stage of a charge-neutral active hydroxide was studied via density functional theory. The deprotonation could be characterized as autocatalytic since upon completion of every H-abstraction stage, Cr was found to mediate O-H dissociation in the next stage by pre-conditioning the ligand O atom that contributes the highest 2s density into Cr-4s based molecular orbitals; the latter amounts to a greater Cr-O distance due to increased charge density along the Cr-O axis. A direct effect of such Cr-4s/O-2s mixing is the reduction of electronegativity of the ligand-O atom and a corresponding high Voronoi deformation density (VDD) of the attached ligand-H atoms. Based on bonding energy decomposition, a facial to meridional isomer ratio of between 2:1 and 3:1 was derived as the most probable stereochemical mix of the active hydroxide; the latter forms, by mutual donation and acceptance, six hydrogen bonds with second hydration shell molecules.

scholarly journals Simultaneous extraction of charge density dependent mobility and variable contact resistance from thin film transistors

2014 ◽  
Vol 104 (19) ◽  
pp. 193501 ◽  
Author(s):  
Riccardo Di Pietro ◽  
Deepak Venkateshvaran ◽  
Andreas Klug ◽  
Emil J. W. List-Kratochvil ◽  
Antonio Facchetti ◽  
...  
Keyword(s):  
Thin Film ◽  
Contact Resistance ◽  
Charge Density ◽  
Thin Film Transistors ◽  
Simultaneous Extraction ◽  
Density Dependent
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