scholarly journals Fluorescence Patterns from Supramolecular Polymer Assembly and Disassembly for Sensing Metallo- and Nonmetalloproteins

2009 ◽  
Vol 131 (22) ◽  
pp. 7708-7716 ◽  
Author(s):  
Daniella C. González ◽  
Elamprakash N. Savariar ◽  
S. Thayumanavan
Keyword(s):  
Supramolecular Polymer ◽  
Polymer Assembly

scholarly journals Anisotropic hygro-expansion in hydrogel fibers owing to uniting 3D electrowriting and supramolecular polymer assembly

2020 ◽  
Vol 141 ◽  
pp. 110099
Author(s):  
Dan Jing Wu ◽  
Niels H. Vonk ◽  
Brigitte A.G. Lamers ◽  
Miguel Castilho ◽  
Jos Malda ◽  
...  
Keyword(s):  
Supramolecular Polymer ◽  
Polymer Assembly

Surface functionalized nanostructures via position registered supramolecular polymer assembly

Nanoscale ◽  
2018 ◽  
Vol 10 (14) ◽  
pp. 6333-6342 ◽  
Author(s):  
Suk Man Cho ◽  
Giyoung Song ◽  
Chanho Park ◽  
Yujeong Lee ◽  
Han Sol Kang ◽  
...  
Keyword(s):  
Polymer Blends ◽  
Supramolecular Assembly ◽  
Supramolecular Polymer ◽  
Surface Chemical ◽  
Polymer Assembly

Versatile control of cylindrical nanostructures formed by supramolecular assembly of end-functionalized polymer blends is demonstrated not only in their orientation but also in their surface chemical functionalities.

Molecular Approach to Supramolecular Polymer Assembly by Small Angle Neutron Scattering

2013 ◽  
Vol 46 (23) ◽  
pp. 9446-9454 ◽  
Author(s):  
Ana R. Brás ◽  
Claas H. Hövelmann ◽  
Wiebke Antonius ◽  
José Teixeira ◽  
Aurel Radulescu ◽  
...  
Keyword(s):  
Neutron Scattering ◽  
Small Angle ◽  
Small Angle Neutron Scattering ◽  
Supramolecular Polymer ◽  
Molecular Approach ◽  
Polymer Assembly

The Role of Hydrophobicity in Supramolecular Polymer/Surfactant Catalysts: An Understandable Model for Enzymatic Catalysis

2020 ◽  
Author(s):  
Paulo F.A. Costa ◽  
Rafael de Abreu ◽  
Andressa B. Fontana ◽  
Haidi D. Fiedler ◽  
Anthony J. Kirby ◽  
...  
Keyword(s):  
Enzymatic Catalysis ◽  
Supramolecular Polymer ◽  
Polymer Surfactant

scholarly journals Oriented arrangement of simple monomers enabled by confinement: towards living supramolecular polymerization

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Yingtong Zong ◽  
Si-Min Xu ◽  
Wenying Shi ◽  
Chao Lu
Keyword(s):  
Activation Barrier ◽  
Degree Of Polymerization ◽  
Supramolecular Polymer ◽  
Energy Principle ◽  
Spontaneous Nucleation ◽  
Pyrene Derivatives ◽  
Multifunctional Molecules ◽  
Double Hydroxide ◽  
Supramolecular Polymerization ◽  
Kinetics Of

AbstractThe living supramolecular polymerization technique provides an exciting research avenue. However, in comparison with the thermodynamic spontaneous nucleation, using simple monomers to realize living supramolecular polymerization is hardly possible from an energy principle. This is because the activation barrier of kinetically trapped simple monomer (nucleation step) is insufficiently high to control the kinetics of subsequent elongation. Here, with the benefit of the confinement from the layered double hydroxide (LDH) nanomaterial, various simple monomers, (such as benzene, naphthalene and pyrene derivatives) successfully form living supramolecular polymer (LSP) with length control and narrow dispersity. The degree of polymerization can reach ~6000. Kinetics studies reveal LDH overcomes a huge energy barrier to inhibit undesired spontaneous nucleation of monomers and disassembly of metastable states. The universality of this strategy will usher exploration into other multifunctional molecules and promote the development of functional LSP.

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