anti-Diastereo- and Enantioselective Carbonyl Crotylation from the Alcohol or Aldehyde Oxidation Level Employing a Cyclometallated Iridium Catalyst: α-Methyl Allyl Acetate as a Surrogate to Preformed Crotylmetal Reagents

In Su Kim; Soo Bong Han; Michael J. Krische

doi:10.1021/ja808857w

anti-Diastereo- and Enantioselective Carbonyl Crotylation from the Alcohol or Aldehyde Oxidation Level Employing a Cyclometallated Iridium Catalyst: α-Methyl Allyl Acetate as a Surrogate to Preformed Crotylmetal Reagents

Journal of the American Chemical Society ◽

10.1021/ja808857w ◽

2009 ◽

Vol 131 (7) ◽

pp. 2514-2520 ◽

Cited By ~ 131

Author(s):

In Su Kim ◽

Soo Bong Han ◽

Michael J. Krische

Keyword(s):

Allyl Acetate ◽

Oxidation Level ◽

Iridium Catalyst ◽

Aldehyde Oxidation

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ChemInform Abstract: anti-Diastereo- and Enantioselective Carbonyl Crotylation from the Alcohol or Aldehyde Oxidation Level Employing a Cyclometalated Iridium Catalyst: α-Methyl Allyl Acetate as a Surrogate to Preformed Crotylmetal Reagents.

ChemInform ◽

10.1002/chin.200927059 ◽

2009 ◽

Vol 40 (27) ◽

Author(s):

In Su Kim ◽

Soo Bong Han ◽

Michael J. Krische

Keyword(s):

Allyl Acetate ◽

Oxidation Level ◽

Iridium Catalyst ◽

Aldehyde Oxidation

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Enantioselective Iridium-Catalyzed Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level via Transfer Hydrogenative Coupling of Allyl Acetate: Departure from Chirally Modified Allyl Metal Reagents in Carbonyl Addition

Journal of the American Chemical Society ◽

10.1021/ja805722e ◽

2008 ◽

Vol 130 (44) ◽

pp. 14891-14899 ◽

Cited By ~ 197

Author(s):

In Su Kim ◽

Ming-Yu Ngai ◽

Michael J. Krische

Keyword(s):

Allyl Acetate ◽

Oxidation Level ◽

Carbonyl Addition ◽

Carbonyl Allylation ◽

Aldehyde Oxidation ◽

Metal Reagents

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Enantioselective Iridium-Catalyzed Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level Using Allyl Acetate as an Allyl Metal Surrogate

Journal of the American Chemical Society ◽

10.1021/ja802001b ◽

2008 ◽

Vol 130 (20) ◽

pp. 6340-6341 ◽

Cited By ~ 170

Author(s):

In Su Kim ◽

Ming-Yu Ngai ◽

Michael J. Krische

Keyword(s):

Allyl Acetate ◽

Oxidation Level ◽

Carbonyl Allylation ◽

Aldehyde Oxidation

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ChemInform Abstract: Enantioselective Iridium-Catalyzed Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level via Transfer Hydrogenation Coupling of Allyl Acetate: Departure from Chirally Modified Allyl Metal Reagents in Carbonyl Addition.

ChemInform ◽

10.1002/chin.200912053 ◽

2009 ◽

Vol 40 (12) ◽

Author(s):

In Su Kim ◽

Ming-Yu Ngai ◽

Michael J. Krische

Keyword(s):

Transfer Hydrogenation ◽

Allyl Acetate ◽

Oxidation Level ◽

Carbonyl Addition ◽

Carbonyl Allylation ◽

Aldehyde Oxidation ◽

Metal Reagents

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ChemInform Abstract: Enantioselective Iridium-Catalyzed Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level Using Allyl Acetate as an Allyl Metal Surrogate.

ChemInform ◽

10.1002/chin.200840075 ◽

2008 ◽

Vol 39 (40) ◽

Author(s):

In Su Kim ◽

Ming-Yu Ngai ◽

Michael J. Krische

Keyword(s):

Allyl Acetate ◽

Oxidation Level ◽

Carbonyl Allylation ◽

Aldehyde Oxidation

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Iridium-Catalyzedanti-Diastereo- and Enantioselective Carbonyl (Trimethylsilyl)allylation from the Alcohol or Aldehyde Oxidation Level

Journal of the American Chemical Society ◽

10.1021/ja103299f ◽

2010 ◽

Vol 132 (26) ◽

pp. 9153-9156 ◽

Cited By ~ 58

Author(s):

Soo Bong Han ◽

Xin Gao ◽

Michael J. Krische

Keyword(s):

Oxidation Level ◽

Aldehyde Oxidation

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Diene Hydroacylation from the Alcohol or Aldehyde Oxidation Level via Ruthenium-Catalyzed C−C Bond-Forming Transfer Hydrogenation: Synthesis of β,γ-Unsaturated Ketones

Journal of the American Chemical Society ◽

10.1021/ja805356j ◽

2008 ◽

Vol 130 (43) ◽

pp. 14120-14122 ◽

Cited By ~ 150

Author(s):

Fumitoshi Shibahara ◽

John F. Bower ◽

Michael J. Krische

Keyword(s):

Transfer Hydrogenation ◽

Unsaturated Ketones ◽

Oxidation Level ◽

Bond Forming ◽

Aldehyde Oxidation

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Iridium-Catalyzed anti-Diastereo- and Enantioselective Carbonyl (α-Trifluoromethyl)allylation from the Alcohol or Aldehyde Oxidation Level

Angewandte Chemie International Edition ◽

10.1002/anie.201008296 ◽

2011 ◽

Vol 50 (18) ◽

pp. 4173-4175 ◽

Cited By ~ 36

Author(s):

Xin Gao ◽

Yong Jian Zhang ◽

Michael J. Krische

Keyword(s):

Oxidation Level ◽

Aldehyde Oxidation

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Diastereo- and Enantioselective Iridium-Catalyzed Carbonyl Propargylation from the Alcohol or Aldehyde Oxidation Level: 1,3-Enynes as Allenylmetal Equivalents

Angewandte Chemie International Edition ◽

10.1002/anie.201200239 ◽

2012 ◽

Vol 51 (12) ◽

pp. 2972-2976 ◽

Cited By ~ 79

Author(s):

Laina M. Geary ◽

Sang Kook Woo ◽

Joyce C. Leung ◽

Michael J. Krische

Keyword(s):

Oxidation Level ◽

Aldehyde Oxidation

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Ruthenium-Catalyzed C−C Bond Forming Transfer Hydrogenation: Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level Employing Acyclic 1,3-Dienes as Surrogates to Preformed Allyl Metal Reagents

Journal of the American Chemical Society ◽

10.1021/ja801213x ◽

2008 ◽

Vol 130 (20) ◽

pp. 6338-6339 ◽

Cited By ~ 136

Author(s):

Fumitoshi Shibahara ◽

John F. Bower ◽

Michael J. Krische

Keyword(s):

Transfer Hydrogenation ◽

Oxidation Level ◽

Bond Forming ◽

Carbonyl Allylation ◽

Aldehyde Oxidation ◽

Metal Reagents

Download Full-text