C−H Bond Functionalization via Hydride Transfer: Lewis Acid Catalyzed Alkylation Reactions by Direct Intramolecular Coupling of sp3C−H Bonds and Reactive Alkenyl Oxocarbenium Intermediates

Kevin M. McQuaid; Dalibor Sames

doi:10.1021/ja806068h

C−H Bond Functionalization via Hydride Transfer: Lewis Acid Catalyzed Alkylation Reactions by Direct Intramolecular Coupling of sp3C−H Bonds and Reactive Alkenyl Oxocarbenium Intermediates

Journal of the American Chemical Society ◽

10.1021/ja806068h ◽

2009 ◽

Vol 131 (2) ◽

pp. 402-403 ◽

Cited By ~ 165

Author(s):

Kevin M. McQuaid ◽

Dalibor Sames

Keyword(s):

Lewis Acid ◽

Hydride Transfer ◽

Bond Functionalization ◽

Acid Catalyzed ◽

Alkylation Reactions

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ChemInform Abstract: C-H Bond Functionalization via Hydride Transfer: Lewis Acid Catalyzed Alkylation Reactions by Direct Intramolecular Coupling of sp3C-H Bonds and Reactive Alkenyl Oxocarbenium Intermediates.

ChemInform ◽

10.1002/chin.200922130 ◽

2009 ◽

Vol 40 (22) ◽

Author(s):

Kevin M. McQuaid ◽

Dalibor Sames

Keyword(s):

Lewis Acid ◽

Hydride Transfer ◽

Bond Functionalization ◽

Acid Catalyzed ◽

Alkylation Reactions

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Lewis Acid Catalyzed C-H Bond Functionalization/Hydride Transfer

Synfacts ◽

10.1055/s-0028-1087906 ◽

2009 ◽

Vol 2009 (04) ◽

pp. 0407-0407

Keyword(s):

Lewis Acid ◽

Hydride Transfer ◽

Bond Functionalization ◽

Acid Catalyzed

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Lewis Acid Catalyzed Benzylic C-H Bond Functionalization of Azaarenes; Addition to Imines and Enones

Synthesis ◽

10.1055/s-0031-1291041 ◽

2012 ◽

Vol 44 (14) ◽

pp. 2185-2194 ◽

Cited By ~ 25

Author(s):

Shigeki Matsunaga ◽

Motomu Kanai ◽

Hirotomo Komai ◽

Tatsuhiko Yoshino

Keyword(s):

Lewis Acid ◽

Bond Functionalization ◽

Acid Catalyzed

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Lewis acid catalyzed formation of 3-amino-3-carboxy-tetrahydroquinoline derivatives via tandem 1,5-hydride transfer/cyclization process

Tetrahedron ◽

10.1016/j.tet.2013.06.047 ◽

2013 ◽

Vol 69 (34) ◽

pp. 7019-7025 ◽

Cited By ~ 11

Author(s):

Wen-Yong Han ◽

Jian Zuo ◽

Zhi-Jun Wu ◽

Xiao-Mei Zhang ◽

Wei-Cheng Yuan

Keyword(s):

Lewis Acid ◽

Hydride Transfer ◽

Cyclization Process ◽

Acid Catalyzed

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Room Temperature Intramolecular Hydro-O-alkylation of Aldehydes: sp3 C—H Functionalization via a Lewis Acid Catalyzed Tandem 1,5-Hydride Transfer/Cyclization.

ChemInform ◽

10.1002/chin.200614137 ◽

2006 ◽

Vol 37 (14) ◽

Author(s):

Stefan J. Pastine ◽

Dalibor Sames

Keyword(s):

Lewis Acid ◽

Room Temperature ◽

Hydride Transfer ◽

Acid Catalyzed

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ChemInform Abstract: Lewis Acid Catalyzed Benzylic C-H Bond Functionalization of Azaarenes: Addition to Enones.

ChemInform ◽

10.1002/chin.201127159 ◽

2011 ◽

Vol 42 (27) ◽

pp. no-no

Author(s):

Hirotomo Komai ◽

Tatsuhiko Yoshino ◽

Shigeki Matsunaga ◽

Motomu Kanai

Keyword(s):

Lewis Acid ◽

Bond Functionalization ◽

Acid Catalyzed

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Highly Diastereoselective Synthesis of Tetralin-fused Spirooxindoles via Lewis Acid-catalyzed C(sp3)–H Bond Functionalization

Chemistry Letters ◽

10.1246/cl.180275 ◽

2018 ◽

Vol 47 (7) ◽

pp. 868-871 ◽

Cited By ~ 10

Author(s):

Mizuki Machida ◽

Keiji Mori

Keyword(s):

Lewis Acid ◽

Diastereoselective Synthesis ◽

Bond Functionalization ◽

Acid Catalyzed

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Lewis Acid Catalyzed Cyclization Reactions of Ethenetricarboxylates via Intramolecular Hydride Transfer

The Journal of Organic Chemistry ◽

10.1021/acs.joc.7b00895 ◽

2017 ◽

Vol 82 (13) ◽

pp. 6748-6763 ◽

Cited By ~ 11

Author(s):

Shoko Yamazaki ◽

Taku Naito ◽

Mamiko Niina ◽

Kiyomi Kakiuchi

Keyword(s):

Lewis Acid ◽

Hydride Transfer ◽

Cyclization Reactions ◽

Acid Catalyzed

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ChemInform Abstract: Lewis Acid Catalyzed Formation of 3-Amino-3-carboxy-tetrahydroquinoline Derivatives via Tandem 1,5-Hydride Transfer/Cyclization Process.

ChemInform ◽

10.1002/chin.201350186 ◽

2013 ◽

Vol 44 (50) ◽

pp. no-no

Author(s):

Wen-Yong Han ◽

Jian Zuo ◽

Zhi-Jun Wu ◽

Xiao-Mei Zhang ◽

Wei-Cheng Yuan

Keyword(s):

Lewis Acid ◽

Hydride Transfer ◽

Cyclization Process ◽

Acid Catalyzed

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Concise Route to 3-Arylisoquinoline Skeleton by Lewis Acid Catalyzed C(sp3)–H Bond Functionalization and Its Application to Formal Synthesis of (±)-Tetrahydropalmatine

Organic Letters ◽

10.1021/ol300180w ◽

2012 ◽

Vol 14 (6) ◽

pp. 1436-1439 ◽

Cited By ~ 60

Author(s):

Keiji Mori ◽

Taro Kawasaki ◽

Takahiko Akiyama

Keyword(s):

Lewis Acid ◽

Formal Synthesis ◽

Bond Functionalization ◽

Acid Catalyzed

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