Nanoscale Organization of Thiol and Arylsulfonic Acid on Silica Leads to a Highly Active and Selective Bifunctional, Heterogeneous Catalyst

2008 ◽  
Vol 130 (40) ◽  
pp. 13442-13449 ◽  
Author(s):  
Eric L. Margelefsky ◽  
Anissa Bendjériou ◽  
Ryan K. Zeidan ◽  
Véronique Dufaud ◽  
Mark E. Davis
Keyword(s):  
Heterogeneous Catalyst ◽  
Highly Active ◽  
Arylsulfonic Acid

Synthesis of carbonate esters by carboxymethylation using NaAlO2 as a highly active heterogeneous catalyst

2018 ◽  
Author(s):  
Sreerangappa Ramesh ◽  
Kiran Indukuri ◽  
Olivier Riant ◽  
Damien Debecker
Keyword(s):  
Heterogeneous Catalyst ◽  
Dimethyl Carbonate ◽  
Sodium Aluminate ◽  
High Yield ◽  
Solid Catalyst ◽  
Highly Active ◽  
Aromatic Alcohols ◽  
Green Conditions ◽  
Mixed Carbonate

<p>Sodium aluminate is presented as a highly active heterogeneous catalyst able to convert a range of alcohols into the corresponding mixed carbonate esters, in high yield and under green conditions. The reaction is carried out using dimethyl carbonate both as a reactant and solvent, at 90°C. Allylic, aliphatic and aromatic alcohols are converted in good yields. The solid catalyst is shown to be truly heterogeneous, resistant to leaching, and recyclable. </p>

A readily available urea based MOF that act as a highly active heterogeneous catalyst for Friedel-Crafts reaction of indoles and nitrostryenes

2018 ◽  
Vol 104 ◽  
pp. 123-127 ◽  
Author(s):  
Chengfeng Zhu ◽  
Qingqing Mao ◽  
De Li ◽  
Changda Li ◽  
Yiyang Zhou ◽  
...  
Keyword(s):  
Heterogeneous Catalyst ◽  
Highly Active

Cyclopropanation on a highly active heterogeneous catalyst: CuO/TiO2-Al2O3

2003 ◽  
Vol 239 (1-2) ◽  
pp. 279-286 ◽  
Author(s):  
Xiang Liu ◽  
Yan Liu ◽  
Xiaohong Li ◽  
Song Xiang ◽  
Yiliang Zhang ◽  
...  
Keyword(s):  
Heterogeneous Catalyst ◽  
Highly Active

A new superacid hafnium-based metal–organic framework as a highly active heterogeneous catalyst for the synthesis of benzoxazoles under solvent-free conditions

2017 ◽  
Vol 7 (19) ◽  
pp. 4346-4350 ◽  
Author(s):  
Linh H. T. Nguyen ◽  
The T. Nguyen ◽  
Ha L. Nguyen ◽  
Tan L. H. Doan ◽  
Phuong Hoang Tran
Keyword(s):  
Heterogeneous Catalyst ◽  
Metal Organic Framework ◽  
Solvent Free ◽  
Highly Active ◽  
Solvent Free Conditions ◽  
Metal Organic ◽  
Efficient Heterogeneous Catalyst ◽  
Organic Framework

A new superacid Hf-based MOF, termed VNU-11-P-SO4, was used as an efficient heterogeneous catalyst for solvent-free 2-arylbenzoxazole synthesis.

A novel carbon-coated Fe-C/N composite as a highly active heterogeneous catalyst for the degradation of Acid Red 73 by persulfate

2019 ◽  
Vol 213 ◽  
pp. 447-455 ◽  
Author(s):  
Cui Wang ◽  
Qiangqiang Yang ◽  
Zhenhong Li ◽  
Kun-Yi Andrew Lin ◽  
Shaoping Tong
Keyword(s):  
Heterogeneous Catalyst ◽  
Highly Active ◽  
Carbon Coated ◽  
Acid Red 73

Rhodium nanoparticles supported on covalent triazine-based frameworks as re-usable catalyst for benzene hydrogenation and hydrogen evolution reaction

2019 ◽  
Vol 7 (19) ◽  
pp. 11934-11943 ◽  
Author(s):  
Marvin Siebels ◽  
Carsten Schlüsener ◽  
Jörg Thomas ◽  
Yu-Xuan Xiao ◽  
Xiao-Yu Yang ◽  
...  
Keyword(s):  
Heterogeneous Catalyst ◽  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Solvent Free ◽  
Benzene Hydrogenation ◽  
Rhodium Nanoparticles ◽  
Highly Active ◽  
Solvent Free Conditions

Rh@CTF-1 nanomaterial is a highly active (TOF ∼ 31 000 h−1) heterogeneous catalyst for the efficient hydrogenation of benzene under mild and solvent-free conditions.

scholarly journals Cu nanoparticles immobilized on montmorillonite by biquaternary ammonium salts: a highly active and stable heterogeneous catalyst for cascade sequence to indole-2-carboxylic esters

RSC Advances ◽  
2017 ◽  
Vol 7 (23) ◽  
pp. 13754-13759 ◽  
Author(s):  
Wencheng Lang ◽  
Qin Yang ◽  
Xueping Song ◽  
Mengyun Yin ◽  
Limei Zhou
Keyword(s):  
High Activity ◽  
Heterogeneous Catalyst ◽  
Ammonium Salts ◽  
Cu Nanoparticles ◽  
Highly Active ◽  
Modified Montmorillonite ◽  
Carboxylic Esters

Cu-Q-MMT catalyst was prepared by immobilizing Cu nanoparticals on the biquaternary ammonium salts modified montmorillonite and exhibited high activity for cascade sequence to indole-2-carboxylic esters.

scholarly journals Nickel-metalated porous organic polymer for Suzuki–Miyaura cross-coupling reaction

RSC Advances ◽  
2019 ◽  
Vol 9 (35) ◽  
pp. 20266-20272 ◽  
Author(s):  
Ying Dong ◽  
Jing-Jing Jv ◽  
Yue Li ◽  
Wen-Han Li ◽  
Yun-Qi Chen ◽  
...  
Keyword(s):  
Heterogeneous Catalyst ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Organic Polymer ◽  
Porous Organic Polymer ◽  
Highly Active ◽  
Cross Coupling Reaction

A porous organic polymer with Ni(ii) α-diimine moiety, which can be a highly active reusable heterogeneous catalyst to promote the Suzuki–Miyaura coupling reaction, was reported.

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