Thermal Signature of Hydrophobic Hydration Dynamics

2008 ◽  
Vol 130 (31) ◽  
pp. 10345-10353 ◽  
Author(s):  
Johan Qvist ◽  
Bertil Halle
Keyword(s):  
Hydrophobic Hydration ◽  
Thermal Signature ◽  
Hydration Dynamics

scholarly journals Curvature Dependence of Hydrophobic Hydration Dynamics

2015 ◽  
Vol 114 (18) ◽  
Author(s):  
R. Gregor Weiß ◽  
Matthias Heyden ◽  
Joachim Dzubiella
Keyword(s):  
Hydrophobic Hydration ◽  
Curvature Dependence ◽  
Hydration Dynamics

Temperature Dependence of Hydrophobic Hydration Dynamics: From Retardation to Acceleration

2014 ◽  
Vol 118 (6) ◽  
pp. 1574-1583 ◽  
Author(s):  
Elise Duboué-Dijon ◽  
Aoife C. Fogarty ◽  
Damien Laage
Keyword(s):  
Temperature Dependence ◽  
Hydrophobic Hydration ◽  
Hydration Dynamics

Hydrophobic hydration at the level of primitive models

1999 ◽  
Vol 96 (8) ◽  
pp. 1237-1248 ◽  
Author(s):  
MILAN PREDOTA, IVO NEZBEDA
Keyword(s):  
Hydrophobic Hydration

Application of Lock-in Thermography on PCB for Fault Localization and Validation of Failure Mechanism Due to External Discrete Component Variation

2010 ◽  
Author(s):  
William Ng ◽  
Kevin Weaver ◽  
Zachary Gemmill ◽  
Herve Deslandes ◽  
Rudolf Schlangen
Keyword(s):  
Failure Mechanism ◽  
Integrated Circuit ◽  
Printed Circuit Board ◽  
Hot Spot ◽  
Circuit Board ◽  
Discrete Component ◽  
Printed Circuit ◽  
Thermal Signature ◽  
Lock In

Abstract This paper demonstrates the use of a real time lock-in thermography (LIT) system to non-destructively characterize thermal events prior to the failing of an integrated circuit (IC) device. A case study using a packaged IC mounted on printed circuit board (PCB) is presented. The result validated the failing model by observing the thermal signature on the package. Subsequent analysis from the backside of the IC identified a hot spot in internal circuitry sensitive to varying value of external discrete component (inductor) on PCB.

scholarly journals Characterization of microbial antifreeze protein with intermediate activity suggests that a bound-water network is essential for hyperactivity

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
N. M.-Mofiz Uddin Khan ◽  
Tatsuya Arai ◽  
Sakae Tsuda ◽  
Hidemasa Kondo
Keyword(s):  
Crystal Structure ◽  
Basal Plane ◽  
Molecular Mechanisms ◽  
Bound Water ◽  
Hydrophobic Hydration ◽  
Water Network ◽  
Molecular Scaffold ◽  
Intermediate Activity ◽  
Mold Fungus ◽  
Antifreeze Activity

AbstractAntifreeze proteins (AFPs) inhibit ice growth by adsorbing onto specific ice planes. Microbial AFPs show diverse antifreeze activity and ice plane specificity, while sharing a common molecular scaffold. To probe the molecular mechanisms responsible for AFP activity, we here characterized the antifreeze activity and crystal structure of TisAFP7 from the snow mold fungus Typhula ishikariensis. TisAFP7 exhibited intermediate activity, with the ability to bind the basal plane, compared with a hyperactive isoform TisAFP8 and a moderately active isoform TisAFP6. Analysis of the TisAFP7 crystal structure revealed a bound-water network arranged in a zigzag pattern on the surface of the protein’s ice-binding site (IBS). While the three AFP isoforms shared the water network pattern, the network on TisAFP7 IBS was not extensive, which was likely related to its intermediate activity. Analysis of the TisAFP7 crystal structure also revealed the presence of additional water molecules that form a ring-like network surrounding the hydrophobic side chain of a crucial IBS phenylalanine, which might be responsible for the increased adsorption of AFP molecule onto the basal plane. Based on these observations, we propose that the extended water network and hydrophobic hydration at IBS together determine the TisAFP activity.

scholarly journals Using Graphene-Based Composite Materials to Boost Anti-Corrosion and Infrared-Stealth Performance of Epoxy Coatings

Nanomaterials ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 1603
Author(s):  
Meng-Jey Youh ◽  
Yu-Ren Huang ◽  
Cheng-Hsiung Peng ◽  
Ming-Hsien Lin ◽  
Ting-Yu Chen ◽  
...  
Keyword(s):  
Electrochemical Impedance ◽  
Graphene Nanosheets ◽  
Salt Spray ◽  
Corrosion Current ◽  
Filler Concentration ◽  
Epoxy Coatings ◽  
Corrosion Properties ◽  
Water Contact ◽  
Different Temperatures ◽  
Thermal Signature

Corrosion prevention and infrared (IR) stealth are conflicting goals. While graphene nanosheets (GN) provide an excellent physical barrier against corrosive agent diffusion, thus lowering the permeability of anti-corrosion coatings, they have the side-effect of decreasing IR stealth. In this work, the anti-corrosion properties of 100-μm-thick composite epoxy coatings with various concentrations (0.01–1 wt.%) of GN fillers thermally reduced at different temperatures (300 °C, 700 °C, 1100 °C) are first compared. The performance was characterized by potentiodynamic polarization scanning, electrochemical impedance spectroscopy, water contact angle and salt spray tests. The corrosion resistance for coatings was found to be optimum at a very low filler concentration (0.05 wt.%). The corrosion current density was 4.57 × 10−11 A/cm2 for GN reduced at 1100 °C, showing no degradation after 500 h of salt-spray testing: a significant improvement over the anti-corrosion behavior of epoxy coatings. Further, to suppress the high IR thermal signature of GN and epoxy, Al was added to the optimized composite at different concentrations. The increased IR emissivity due to GN was not only eliminated but was in fact reduced relative to the pure epoxy. These optimized coatings of Al-GN-epoxy not only exhibited greatly reduced IR emissivity but also showed no sign of corrosion after 500 h of salt spray test.

Effect of Forced Convection on the Skin Thermal Expression of Breast Cancer

2004 ◽  
Vol 126 (2) ◽  
pp. 204-211 ◽  
Author(s):  
Lu Hu ◽  
Ashish Gupta ◽  
Jay P. Gore ◽  
Lisa X. Xu
Keyword(s):  
Forced Convection ◽  
Conjugate Heat Transfer ◽  
Transfer Problem ◽  
Skin Surface ◽  
Bioheat Transfer ◽  
Image Subtraction ◽  
Steady State Temperature ◽  
Parametric Studies ◽  
Airflow Field ◽  
Thermal Signature

A bioheat-transfer-based numerical model was utilized to study the energy balance in healthy and malignant breasts subjected to forced convection in a wind tunnel. Steady-state temperature distributions on the skin surface of the breasts were obtained by numerically solving the conjugate heat transfer problem. Parametric studies on the influences of the airflow on the skin thermal expression of tumors were performed. It was found that the presence of tumor may not be clearly shown due to the irregularities of the skin temperature distribution induced by the airflow field. Nevertheless, image subtraction techniques could be employed to eliminate the effects of the flow field and thermal noise and significantly improve the thermal signature of the tumor on the skin surface. Inclusion of the possible skin vascular response to cold stress caused by the airflow further enhances the signal, especially for deeply embedded tumors that otherwise may not be detectable.

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