Synthetic Control of the Pore Dimension and Surface Area in Conjugated Microporous Polymer and Copolymer Networks

2008 ◽  
Vol 130 (24) ◽  
pp. 7710-7720 ◽  
Author(s):  
Jia-Xing Jiang ◽  
Fabing Su ◽  
Abbie Trewin ◽  
Colin D. Wood ◽  
Hongjun Niu ◽  
...  
Keyword(s):  
Surface Area ◽  
Synthetic Control ◽  
Pore Dimension ◽  
Conjugated Microporous Polymer ◽  
Microporous Polymer

scholarly journals Metal-Free Pyrene-Based Conjugated Microporous Polymer Catalyst Bearing N- and S-Sites for Photoelectrochemical Oxygen Evolution Reaction

2021 ◽  
Vol 9 ◽  
Author(s):  
Sabuj Kanti Das ◽  
Sanjib Shyamal ◽  
Manisha Das ◽  
Saptarsi Mondal ◽  
Avik Chowdhury ◽  
...  
Keyword(s):  
Surface Area ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Magic Angle Spinning ◽  
Bandgap Energy ◽  
Magic Angle ◽  
Low Bandgap ◽  
Metal Free ◽  
Conjugated Microporous Polymer ◽  
Microporous Polymer

The development of an efficient, sustainable, and inexpensive metal-free catalyst for oxygen evolution reaction (OER) via photoelectrochemical water splitting is very demanding for energy conversion processes such as green fuel generators, fuel cells, and metal-air batteries. Herein, we have developed a metal-free pyrene-based nitrogen and sulfur containing conjugated microporous polymer having a high Brunauer-Emmett-Teller surface area (761 m2 g−1) and a low bandgap of 2.09 eV for oxygen evolution reaction (OER) in alkaline solution. The π-conjugated as-synthesized porous organic material (PBTDZ) has been characterized by Fourier transform infrared spectroscopy (FT-IR), solid-state 13C (cross-polarization magic angle spinning-nuclear magnetic resonance) CP-MAS NMR, N2 adsorption/desorption analysis, field-emission scanning electron microscope (FESEM), high-resolution transmission electron microscopy (HRTEM), X-ray photoelectron spectroscopy (XPS) and thermogravimetric analysis (TGA) experiments. The material acts as an efficient catalyst for photoelectrochemical OER with a current density of 80 mA/cm2 at 0.8 V vs. Ag/AgCl and delivered 104 µmol of oxygen in a 2 h run. The presence of low bandgap energy, π-conjugated conducting polymeric skeleton bearing donor heteroatoms (N and S), and higher specific surface area associated with inherent microporosity are responsible for this admirable photoelectrocatalytic activity of PBTDZ catalyst.

A novel metalloporphyrin-based conjugated microporous polymer for capture and conversion of CO2

RSC Advances ◽  
2015 ◽  
Vol 5 (40) ◽  
pp. 31664-31669 ◽  
Author(s):  
Xingfeng Sheng ◽  
Hongchen Guo ◽  
Yusheng Qin ◽  
Xianhong Wang ◽  
Fosong Wang
Keyword(s):  
Carbon Dioxide ◽  
Catalytic Activity ◽  
Specific Surface ◽  
Surface Area ◽  
Pore Volume ◽  
Cyclic Carbonate ◽  
Conjugated Microporous Polymer ◽  
Microporous Polymer ◽  
Bet Specific Surface Area ◽  
Good Catalytic Activity

A novel conjugated microporous polymer was solvothermally synthesized, which had high BET specific surface area and pore volume, and displayed excellent capacity to capture carbon dioxide and good catalytic activity for cyclic carbonate synthesis.

Porphyrin and pyrene-based conjugated microporous polymer for efficient sequestration of CO2 and iodine and photosensitization for singlet oxygen generation

RSC Advances ◽  
2016 ◽  
Vol 6 (79) ◽  
pp. 75478-75481 ◽  
Author(s):  
Kyoung Chul Park ◽  
Jinhee Cho ◽  
Chang Yeon Lee
Keyword(s):  
Singlet Oxygen ◽  
Surface Area ◽  
High Efficiency ◽  
Bet Surface Area ◽  
Oxygen Generation ◽  
Singlet Oxygen Generation ◽  
Conjugated Microporous Polymer ◽  
Sequestration Of Co2 ◽  
Microporous Polymer

A novel porphyrin and pyrene-based conjugated microporous polymer (Por-Py-CMP) was synthesized. It exhibited a high BET surface area (1014 m2 g−1) and excellent capacity for capturing CO2 and I2. It also showed high efficiency for 1O2 generation.

Synthesis of high-performance conjugated microporous polymer/TiO2 photocatalytic antibacterial nanocomposites

2021 ◽  
Vol 126 ◽  
pp. 112121
Author(s):  
Yunfeng Wu ◽  
Yu Zang ◽  
Liang Xu ◽  
Jianjun Wang ◽  
Hongge Jia ◽  
...  
Keyword(s):  
High Performance ◽  
Conjugated Microporous Polymer ◽  
Microporous Polymer

Flexible Ionic Conjugated Microporous Polymer Membranes for Fast and Selective Ion Transport

2021 ◽  
pp. 2108672
Author(s):  
Zongyao Zhou ◽  
Digambar B. Shinde ◽  
Dong Guo ◽  
Li Cao ◽  
Reham Al Nuaimi ◽  
...  
Keyword(s):  
Ion Transport ◽  
Polymer Membranes ◽  
Conjugated Microporous Polymer ◽  
Microporous Polymer

scholarly journals Ni-Co single atomic anchored conjugated microporous polymer for high-performance photocatalytic hydrogen evolution

2021 ◽  
Author(s):  
Chen Yang ◽  
Zhonghua Cheng ◽  
Giorgio Divitini ◽  
Cheng Qian ◽  
Bo Hou ◽  
...  
Keyword(s):  
Hydrogen Evolution ◽  
High Performance ◽  
Efficient Production ◽  
Gaseous Diffusion ◽  
Photocatalytic Hydrogen Evolution ◽  
Conjugated Microporous Polymer ◽  
Microporous Polymer ◽  
Production Of Hydrogen ◽  
Simple Pathway

The fabrication of single atomic photocatalysts via a simple pathway is a crucial challenge to enable efficient production of hydrogen. Herein, we demonstrate a gaseous diffusion strategy to construct single...

The high performance photoelectrochemical sensor for specific detection of H2O2 and glucose based on an organic conjugated microporous polymer

2021 ◽  
Author(s):  
Qiqi Sun ◽  
Qi Liu ◽  
Wen Gao ◽  
Chuanwang Xing ◽  
Jingshun Shen ◽  
...  
Keyword(s):  
High Performance ◽  
Low Cost ◽  
Specific Detection ◽  
Sensing Applications ◽  
Conjugated Microporous Polymer ◽  
Microporous Polymer ◽  
Photoelectrochemical Sensor

The cathodic photoelectrochemical (PEC) biosensor, is one of ideal systems for sensing applications owing to its advantages in the low-cost, simplicity of the detection and miniaturization of the sensors with...

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