scholarly journals 18O Kinetic Isotope Effects in Non-Heme Iron Enzymes: Probing the Nature of Fe/O2Intermediates

2008 ◽  
Vol 130 (26) ◽  
pp. 8122-8123 ◽  
Author(s):  
Liviu M. Mirica ◽  
Kevin P. McCusker ◽  
Jeffrey W. Munos ◽  
Hung-wen Liu ◽  
Judith P. Klinman
Keyword(s):  
Isotope Effects ◽  
Kinetic Isotope Effects ◽  
Heme Iron ◽  
Kinetic Isotope ◽  
Non Heme Iron ◽  
Iron Enzymes

scholarly journals Oxygen-18 Kinetic Isotope Effects of Nonheme Iron Enzymes HEPD and MPnS Support Iron(III) Superoxide as the Hydrogen Abstraction Species

2015 ◽  
Vol 137 (33) ◽  
pp. 10448-10451 ◽  
Author(s):  
Hui Zhu ◽  
Spencer C. Peck ◽  
Florence Bonnot ◽  
Wilfred A. van der Donk ◽  
Judith P. Klinman
Keyword(s):  
Isotope Effects ◽  
Hydrogen Abstraction ◽  
Kinetic Isotope Effects ◽  
Nonheme Iron ◽  
Nonheme Iron Enzymes ◽  
Kinetic Isotope ◽  
Iron Enzymes

Theoretical Simulations of Heavy-Atom Kinetic Isotope Effects in Aliphatic Claisen Rearrangement

2020 ◽  
Vol 124 (51) ◽  
pp. 10678-10686
Author(s):  
Yuqing Xu ◽  
Kin-Yiu Wong ◽  
Meishan Wang ◽  
Desheng Liu ◽  
Wenkai Zhao ◽  
...  
Keyword(s):  
Claisen Rearrangement ◽  
Isotope Effects ◽  
Heavy Atom ◽  
Kinetic Isotope Effects ◽  
Kinetic Isotope ◽  
Theoretical Simulations

Direct dynamics calculations of reaction rate and kinetic isotope effects in enzyme catalysed reactions

2002 ◽  
Vol 122 ◽  
pp. 223-242 ◽  
Author(s):  
Gary Tresadern ◽  
Sara Nunez ◽  
Paul F. Faulder ◽  
Hong Wang ◽  
Ian H. Hillier ◽  
...  
Keyword(s):  
Reaction Rate ◽  
Isotope Effects ◽  
Kinetic Isotope Effects ◽  
Direct Dynamics ◽  
Kinetic Isotope

Interpretation of Transient-State Kinetic Isotope Effects†

Biochemistry ◽  
1996 ◽  
Vol 35 (1) ◽  
pp. 83-88 ◽  
Author(s):  
Harvey F. Fisher ◽  
Swapan K. Saha
Keyword(s):  
Isotope Effects ◽  
Transient State ◽  
Kinetic Isotope Effects ◽  
Kinetic Isotope ◽  
State Kinetic
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