An Intermediate Cobalt(IV) Nitrido Complex and its N-Migratory Insertion Product

2014 ◽  
Vol 136 (42) ◽  
pp. 15072-15078 ◽  
Author(s):  
Eva M. Zolnhofer ◽  
Martina Käß ◽  
Marat M. Khusniyarov ◽  
Frank W. Heinemann ◽  
Laurent Maron ◽  
...  
Keyword(s):  
Insertion Product ◽  
Migratory Insertion

scholarly journals 1,2- and 1,1-Migratory Insertion Reactions of Silylated Germylene Adducts

Molecules ◽  
2020 ◽  
Vol 25 (3) ◽  
pp. 686
Author(s):  
Małgorzata Walewska ◽  
Judith Baumgartner ◽  
Christoph Marschner
Keyword(s):  
Insertion Reactions ◽  
Insertion Product ◽  
Migratory Insertion ◽  
Chloride Elimination ◽  
Related Reaction

The reactions of the PMe3 adduct of the silylated germylene [(Me3Si)3Si]2Ge: with GeCl2·dioxane were found to yield 1,1-migratory insertion products of GeCl2 into one or two Ge–Si bonds. In a related reaction, a germylene was inserted with tris(trimethylsilyl)silyl and vinyl substituents into a Ge–Cl bond of GeCl2. This was followed by intramolecular trimethylsilyl chloride elimination to another cyclic germylene PMe3 adduct. The reaction of the GeCl2 mono-insertion product (Me3Si)3SiGe:GeCl2Si(SiMe3)3 with Me3SiC≡CH gave a mixture of alkyne mono- and diinsertion products. While the reaction of a divinylgermylene with GeCl2·dioxane only results in the exchange of the dioxane of GeCl2 against the divinylgermylene as base, the reaction of [(Me3Si)3Si]2Ge: with one GeCl2·dioxane and three phenylacetylenes gives a trivinylated germane with a chlorogermylene attached to one of the vinyl units.

NO Migratory Insertion into Ruthenium–Aryl Bond with a Hydridotris(pyrazolyl)borato Ligand

2021 ◽  
Vol 40 (3) ◽  
pp. 302-305
Author(s):  
Yasuhiro Arikawa ◽  
Motoki Yamada ◽  
Nobuko Takemoto ◽  
Shinnosuke Horiuchi ◽  
Eri Sakuda ◽  
...  
Keyword(s):  
Migratory Insertion

CO and Ethylene Migratory Insertion Reactions and Copolymerization Involving Palladium Complexes of a NiN2S2Metallodithiolate Ligand

2007 ◽  
Vol 26 (4) ◽  
pp. 783-792 ◽  
Author(s):  
Marilyn V. Rampersad ◽  
Erik Zuidema ◽  
Jan Meine Ernsting ◽  
Piet W. N. M. van Leeuwen ◽  
Marcetta Y. Darensbourg
Keyword(s):  
Palladium Complexes ◽  
Insertion Reactions ◽  
Migratory Insertion

PX3-induced migratory insertion reactions of half-sandwich-type carbenerhodium(I) complexes

2001 ◽  
Vol 25 (3) ◽  
pp. 396-399 ◽  
Author(s):  
Ulrich Herber ◽  
Rita Guerrero Sanchez ◽  
Olaf Gevert ◽  
Matthias Laubender ◽  
Helmut Werner
Keyword(s):  
Insertion Reactions ◽  
Migratory Insertion ◽  
Sandwich Type ◽  
Half Sandwich
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