Lewis Acid-Assisted Formic Acid Dehydrogenation Using a Pincer-Supported Iron Catalyst

2014 ◽  
Vol 136 (29) ◽  
pp. 10234-10237 ◽  
Author(s):  
Elizabeth A. Bielinski ◽  
Paraskevi O. Lagaditis ◽  
Yuanyuan Zhang ◽  
Brandon Q. Mercado ◽  
Christian Würtele ◽  
...  
Keyword(s):  
Formic Acid ◽  
Lewis Acid ◽  
Iron Catalyst ◽  
Formic Acid Dehydrogenation ◽  
Supported Iron

scholarly journals Additive‐Free Formic Acid Dehydrogenation Using a Pincer‐Supported Iron Catalyst

ChemCatChem ◽  
2020 ◽  
Vol 12 (7) ◽  
pp. 1934-1938 ◽  
Author(s):  
Julia B. Curley ◽  
Wesley H. Bernskoetter ◽  
Nilay Hazari
Keyword(s):  
Formic Acid ◽  
Iron Catalyst ◽  
Formic Acid Dehydrogenation ◽  
Supported Iron

Efficient H 2 production from formic acid by a supported iron catalyst on silica

2015 ◽  
Vol 498 ◽  
pp. 176-184 ◽  
Author(s):  
Panagiota Stathi ◽  
Yiannis Deligiannakis ◽  
George Avgouropoulos ◽  
Maria Louloudi
Keyword(s):  
Formic Acid ◽  
Iron Catalyst ◽  
Supported Iron

scholarly journals Additive-Free Formic Acid Dehydrogenation Catalyzed by a Cobalt Complex

2021 ◽  
Author(s):  
Nicolas Lentz ◽  
Alicia Aloisi ◽  
Pierre Thuéry ◽  
Emmanuel Nicolas ◽  
Thibault Cantat
Keyword(s):  
Formic Acid ◽  
Cobalt Complex ◽  
Formic Acid Dehydrogenation

CdS Nanorods Anchored with Crystalline FeP Nanoparticles for Efficient Photocatalytic Formic Acid Dehydrogenation

2021 ◽  
Author(s):  
Taotao Wang ◽  
Lechen Yang ◽  
Daochuan Jiang ◽  
Hongyun Cao ◽  
Antony Charles Minja ◽  
...  
Keyword(s):  
Formic Acid ◽  
Cds Nanorods ◽  
Formic Acid Dehydrogenation

scholarly journals Synthesis of palladium-rhodium bimetallic nanoparticles for formic acid dehydrogenation

2021 ◽  
Vol 52 ◽  
pp. 301-309
Author(s):  
Ilaria Barlocco ◽  
Sofia Capelli ◽  
Elisa Zanella ◽  
Xiaowei Chen ◽  
Juan J. Delgado ◽  
...  
Keyword(s):  
Formic Acid ◽  
Bimetallic Nanoparticles ◽  
Formic Acid Dehydrogenation

Versatile Rh- and Ir-Based Catalysts for CO2 Hydrogenation, Formic Acid Dehydrogenation, and Transfer Hydrogenation of Quinolines

2018 ◽  
Vol 57 (22) ◽  
pp. 14186-14198 ◽  
Author(s):  
Jairo Fidalgo ◽  
Margarita Ruiz-Castañeda ◽  
Gabriel García-Herbosa ◽  
Arancha Carbayo ◽  
Félix A. Jalón ◽  
...  
Keyword(s):  
Formic Acid ◽  
Co2 Hydrogenation ◽  
Transfer Hydrogenation ◽  
Formic Acid Dehydrogenation

scholarly journals Additive-Free Formic Acid Dehydrogenation Catalyzed by a Cobalt Complex

2020 ◽  
Author(s):  
Nicolas Lentz ◽  
Alicia Aloisi ◽  
Pierre Thuéry ◽  
Emmanuel Nicolas ◽  
Thibault Cantat
Keyword(s):  
Formic Acid ◽  
Cobalt Complex ◽  
Intermediate Formation ◽  
Mechanistic Study ◽  
Catalytic Dehydrogenation ◽  
Turnover Number ◽  
Promising Solution ◽  
The Common ◽  
Safe Transport ◽  
Formic Acid Dehydrogenation

The reversible storage of hydrogen through the intermediate formation of Formic Acid (FA) is a promising solution to its safe transport and distribution. However, the common necessity of using bases or additives in the catalytic dehydrogenation of FA is a limitation. In this context, two new cobalt complexes (<b>1</b> and <b>2</b>) were synthesized with a pincer PP(NH)P ligand containing a phosphoramine moiety. Their reaction with an excess FA yields a cobalt(I)-hydride complex (<b>3</b>). We report here the unprecedented catalytic activity of <b>3</b> in the dehydrogenation of FA, with a turnover frequency (TOF) of 4000 h<sup>-1</sup> and a turnover number (TON) of 454, without the need for bases or additives. A mechanistic study reveals that the ligand has a non-innocent behaviour due to intermolecular hydrogen bonding, which is influenced by the concentration of formic acid

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