Stepwise Synthesis of Robust Metal–Organic Frameworks via Postsynthetic Metathesis and Oxidation of Metal Nodes in a Single-Crystal to Single-Crystal Transformation

2014 ◽  
Vol 136 (22) ◽  
pp. 7813-7816 ◽  
Author(s):  
Tian-Fu Liu ◽  
Lanfang Zou ◽  
Dawei Feng ◽  
Ying-Pin Chen ◽  
Stephen Fordham ◽  
...  
Keyword(s):  
Single Crystal ◽  
Metal Organic Frameworks ◽  
Stepwise Synthesis ◽  
Crystal Transformation ◽  
Metal Organic

Single crystal to single crystal transformation of spin-crossover coordination polymers from 3D frameworks to 2D layers

2021 ◽  
Vol 9 (15) ◽  
pp. 5082-5087
Author(s):  
Yu Gong ◽  
Wang-Kang Han ◽  
Hui-Shu Lu ◽  
Qing-Tao Hu ◽  
Huan Tu ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Single Crystal ◽  
Coordination Polymers ◽  
Ligand Exchange ◽  
Spin Crossover ◽  
Metal Organic Frameworks ◽  
Crystal Transformation ◽  
Metal Organic

New Hofmann-type metal–organic frameworks display rare and complete ligand exchange induced single crystal to single crystal transformations from 3D frameworks to 2D layers, accompanied by magnetic properties transition from two-step SCO behavior to hysteretic SCO behavior.

Stepwise synthesis of Zr-based metal-organic frameworks: Incorporating trinuclear zirconocene-based metallo-pyridine ligand

CrystEngComm ◽  
2021 ◽  
Author(s):  
Juan Zhu ◽  
Zhao-Yang Liu ◽  
Shuangbao Li ◽  
He Huang ◽  
Bao-Xu Jiang ◽  
...  
Keyword(s):  
Single Crystal ◽  
Metal Organic Frameworks ◽  
Pyridine Ligand ◽  
Stepwise Synthesis ◽  
X Ray ◽  
Metal Organic

Two isostructural heterometallic ZrMOFs (denoted as ZrMOF-Co/Ni) were obtained by stepwise sysnthesis approach. Single-crystal X-ray structural analyses indicate that two ZrMOFs are both built from trinuclear zirconocene-based metallo-pyridine buliding blocks,...

A series of two-dimensional microporous triazole-functionalized metal–organic frameworks with the new multi-dentate ligand 1-(4-aminobenzyl)-1,2,4-triazole: single-crystal-to-single-crystal transformation, structural diversity and luminescent sensing

RSC Advances ◽  
2015 ◽  
Vol 5 (44) ◽  
pp. 35238-35251 ◽  
Author(s):  
You You Wang ◽  
Qing Jin ◽  
Shi Xin Liu ◽  
Chao Guo ◽  
Yuan Yuan Liu ◽  
...  
Keyword(s):  
Single Crystal ◽  
Metal Organic Frameworks ◽  
Structural Diversity ◽  
Two Dimensional ◽  
Crystal Transformation ◽  
Metal Organic ◽  
Luminescent Sensing

A new flexible multi-dentate 1-(4-aminobenzyl)-1,2,4-triazole (abtz) ligand has been synthesized, and a series of two-dimensional triazole-functionalized metal–organic frameworks has been isolated.

Metal-organic frameworks displaying single crystal-to-single crystal transformation through postsynthetic uptake of metal clusters

2013 ◽  
Vol 4 (8) ◽  
pp. 3232 ◽  
Author(s):  
Jia Li ◽  
Peng Huang ◽  
Xue-Ru Wu ◽  
Jun Tao ◽  
Rong-Bin Huang ◽  
...  
Keyword(s):  
Single Crystal ◽  
Metal Clusters ◽  
Metal Organic Frameworks ◽  
Crystal Transformation ◽  
Metal Organic
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