Unexpected Reactivity of Amidogen Radical in the Gas Phase Degradation of Nitric Acid

2014 ◽  
Vol 136 (19) ◽  
pp. 6834-6837 ◽  
Author(s):  
Josep M. Anglada ◽  
Santiago Olivella ◽  
Albert Solé
Keyword(s):  
1990 ◽  
Vol 112 (3) ◽  
pp. 1014-1018 ◽  
Author(s):  
Fulvio Cacace ◽  
Marina Attina ◽  
Giulia De Petris ◽  
Maurizio Speranza

1982 ◽  
Vol 18 (1) ◽  
pp. 39-46 ◽  
Author(s):  
R.H. Clark ◽  
D. Husain ◽  
J.Y. Jezequel
Keyword(s):  

1982 ◽  
Vol 20 ◽  
Author(s):  
Sophia R. Su ◽  
Daniel W. Oblas

ABSTRACTGas-phase intercalation of graphite by nitric acid is a one-step process. The weight uptake of the sample is a function of nitric acid vapor pressure. A pure second stage compound was formed when the HNO3 reservoir was maintained at 17°C. Only a fourth stage compound was formed when the acid was kept at 0°C. The product gases due to intercalation and gas species evolved during deintercalation were analyzed by mass spectrometry. NO2 and H2O were the major components detected from the intercalation product gases. A small amount of oxygen was also present. The existence of O2 is probably due to the photo-chemical decomposition of nitric acid. As such, the photodecomposition of nitric acid is not a contributory factor in the intercalation chemistry.


2013 ◽  
Vol 15 (2) ◽  
pp. 448-458 ◽  
Author(s):  
S. G. Moussa ◽  
A. C. Stern ◽  
J. D. Raff ◽  
C. W. Dilbeck ◽  
D. J. Tobias ◽  
...  

2014 ◽  
Vol 304 (1) ◽  
pp. 425-428 ◽  
Author(s):  
S. A. Kulyukhin ◽  
A. Yu. Shadrin ◽  
Y. A. Voskresenskaya ◽  
A. A. Bessonov ◽  
O. A. Ustinov

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