Enantioselective Photoredox Catalysis Enabled by Proton-Coupled Electron Transfer: Development of an Asymmetric Aza-Pinacol Cyclization

2013 ◽  
Vol 135 (47) ◽  
pp. 17735-17738 ◽  
Author(s):  
Lydia J. Rono ◽  
Hatice G. Yayla ◽  
David Y. Wang ◽  
Michael F. Armstrong ◽  
Robert R. Knowles
Keyword(s):  
Electron Transfer ◽  
Photoredox Catalysis ◽  
Proton Coupled Electron Transfer

scholarly journals Chemistry With N-Centered Radicals Generated by Single-Electron Transfer-Oxidation Using Photoredox Catalysis

CCS Chemistry ◽  
2019 ◽  
pp. 38-49 ◽  
Author(s):  
Heng Jiang ◽  
Armido Studer
Keyword(s):  
Electron Transfer ◽  
Recent Literature ◽  
Bond Cleavage ◽  
Photoredox Catalysis ◽  
Proton Coupled Electron Transfer ◽  
Cascade Processes ◽  
Reactive N ◽  
Radical Generation ◽  
Cleavage Reactions ◽  
Oxidative Generation

This review covers the recent literature on oxidative generation of N-centered radicals using photoredox catalysis. The concept of proton-coupled electron transfer is briefly discussed. Applications of such reactive N-centered radicals in cascade processes comprising arene amidation, alkene amidation, C—C bond cleavage reactions, and remote C—H functionalization are addressed. In addition, novel reagents allowing for clean oxidative N-radical generation are discussed.

ChemInform Abstract: Enantioselective Photoredox Catalysis Enabled by Proton-Coupled Electron Transfer: Development of an Asymmetric Aza-Pinacol Cyclization.

ChemInform ◽  
2014 ◽  
Vol 45 (23) ◽  
pp. no-no
Author(s):  
Lydia J. Rono ◽  
Hatice G. Yayla ◽  
David Y. Wang ◽  
Michael F. Armstrong ◽  
Robert R. Knowles
Keyword(s):  
Electron Transfer ◽  
Photoredox Catalysis ◽  
Proton Coupled Electron Transfer

scholarly journals Electron–Nuclear Dynamics Accompanying Proton-Coupled Electron Transfer

2021 ◽  
Vol 143 (8) ◽  
pp. 3104-3112
Author(s):  
Yusuke Yoneda ◽  
S. Jimena Mora ◽  
James Shee ◽  
Brian L. Wadsworth ◽  
Eric A. Arsenault ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Nuclear Dynamics ◽  
Proton Coupled Electron Transfer

Facile proton-coupled electron transfer enabled by coordination-induced E–H bond weakening to boron

2021 ◽  
Author(s):  
Anthony Wong ◽  
Arunavo Chakraborty ◽  
Deependra Bawari ◽  
Guang Wu ◽  
Roman Dobrovetsky ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Proton Coupled Electron Transfer

Coordination induced bond weakening (CIBW) leads to facile PCET at various E–H bonds.

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