Ligand Noninnocence of Thiolate/Disulfide in Dinuclear Copper Complexes: Solvent-Dependent Redox Isomerization and Proton-Coupled Electron Transfer

2013 ◽  
Vol 135 (50) ◽  
pp. 18912-18919 ◽  
Author(s):  
Andrew M. Thomas ◽  
Bo-Lin Lin ◽  
Erik C. Wasinger ◽  
T. Daniel P. Stack
Keyword(s):  
Electron Transfer ◽  
Copper Complexes ◽  
Dinuclear Copper ◽  
Proton Coupled Electron Transfer ◽  
Redox Isomerization

scholarly journals Recent advances in photocatalyzed reactions using well-defined copper(I) complexes

2020 ◽  
Vol 16 ◽  
pp. 451-481 ◽  
Author(s):  
Mingbing Zhong ◽  
Xavier Pannecoucke ◽  
Philippe Jubault ◽  
Thomas Poisson
Keyword(s):  
Electron Transfer ◽  
Energy Transfer ◽  
Copper Complexes ◽  
Transfer Reactions ◽  
Proton Coupled Electron Transfer ◽  
Recent Advances

This review summarizes the recent advances in photocatalysis using copper complexes. Their applications in various reactions, such as ATRA, reduction, oxidation, proton-coupled electron transfer, and energy transfer reactions are discussed.

scholarly journals Electron–Nuclear Dynamics Accompanying Proton-Coupled Electron Transfer

2021 ◽  
Vol 143 (8) ◽  
pp. 3104-3112
Author(s):  
Yusuke Yoneda ◽  
S. Jimena Mora ◽  
James Shee ◽  
Brian L. Wadsworth ◽  
Eric A. Arsenault ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Nuclear Dynamics ◽  
Proton Coupled Electron Transfer

Facile proton-coupled electron transfer enabled by coordination-induced E–H bond weakening to boron

2021 ◽  
Author(s):  
Anthony Wong ◽  
Arunavo Chakraborty ◽  
Deependra Bawari ◽  
Guang Wu ◽  
Roman Dobrovetsky ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Proton Coupled Electron Transfer

Coordination induced bond weakening (CIBW) leads to facile PCET at various E–H bonds.

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