Redox-Induced Ion Pairing of Anionic Surfactants with Ferrocene-Terminated Self-Assembled Monolayers: Faradaic Electrochemistry and Surfactant Aggregation at the Monolayer/Liquid Interface

2013 ◽  
Vol 135 (46) ◽  
pp. 17457-17468 ◽  
Author(s):  
Eric R. Dionne ◽  
Tania Sultana ◽  
Lana L. Norman ◽  
Violeta Toader ◽  
Antonella Badia
Keyword(s):  
Anionic Surfactants ◽  
Ion Pairing ◽  
Liquid Interface ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Self Assembled

Supramolecular chemistry of helical foldamers at the solid–liquid interface: self-assembled monolayers and anion recognition

2019 ◽  
Vol 55 (58) ◽  
pp. 8426-8429 ◽  
Author(s):  
Catherine Adam ◽  
Lara Faour ◽  
Valérie Bonnin ◽  
Tony Breton ◽  
Eric Levillain ◽  
...  
Keyword(s):  
Supramolecular Chemistry ◽  
Anion Recognition ◽  
Liquid Interface ◽  
Self Assembled Monolayers ◽  
Guest Binding ◽  
Assembled Monolayers ◽  
Self Assembled ◽  
Solid Liquid Interface ◽  
Solid Liquid

Helical foldamers were incorporated in self-assembled monolayers that successfully transduce host–guest binding events.

Redox and ion-pairing thermodynamics in self-assembled monolayers

Langmuir ◽  
1991 ◽  
Vol 7 (10) ◽  
pp. 2307-2312 ◽  
Author(s):  
Gary K. Rowe ◽  
Stephen E. Creager
Keyword(s):  
Ion Pairing ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Self Assembled

Nanobubbles on a Very Flat Hydrophobic Surface Prepared by Self-Assembled Monolayers

2013 ◽  
Author(s):  
Takashi Nishiyama ◽  
Koji Takahashi ◽  
Yasuyuki Takata
Keyword(s):  
Heat Transfer ◽  
Gaseous Phase ◽  
Hydrophobic Surface ◽  
Bubble Nucleation ◽  
Liquid Interface ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Self Assembled ◽  
Solid Liquid Interface ◽  
Solid Liquid

Boiling is one of the most effective heat transfer methods due to its high heat transfer coefficient. Therefore, boiling heat transfer plays a very important role for various applications in many technological and industrial areas. However, a very complex mechanism of boiling, especially bubble nucleation, is still not sufficiently understood. On the other hand, numerous experiments have revealed the existence of soft domains that called nanobubbles at the solid-liquid interface. In this study, to investigate the influence of the solid-liquid interface nanobubbles on the bubble nucleation, an atomic force microscope (AFM) is used to characterize the morphology of nanobubbles. In order to separate the effect of wettability of a solid surface from that of surface structure, a very flat hydrophobic surface was prepared. 1H,1H,2H,2H-Perfluoro-n-octylphosphonic acid (FOPA) formed the interface of hydrophobic self-assembled monolayers (SAMs). As the result of AFM measurement, many nanobubbles about 100 nm in diameter and 30 nm thick are observed at the interface of the FOPA surface and the pure water. In addition, to prove the existence of gaseous phase, the heat conductance measurement by time-domain thermoreflectance method (TDTR) was introduced. TDTR is an ultrafast optical pump probe technique well suited for thermal measurement of thin films. It enables to resolve the thermal conductivity of the thin film and the thermal conductance of the interface. If nanobubbles are the gaseous phase, the big change of interface heat thermal resistance will be seen and the TDTR signal should also change. The effectiveness of a TDTR to confirm the existence of nanobubbles is shown by the model simulation of TDTR. A clear difference is seen in TDTR signal by the existence of only 1 nm gaseous phase. After confirming the existence of nanobubbles by AFM measurement, it can be proved that the nanobubbles are truly gaseous phase of the TDTR measurement.

Nitroxyl radical self assembled monolayers: Ion pairing investigation in organic and aqueous media

2010 ◽  
Vol 12 (1) ◽  
pp. 79-82 ◽  
Author(s):  
Christelle Gautier ◽  
Olivier Alévêque ◽  
Fawzia Seladji ◽  
Marylène Dias ◽  
Tony Breton ◽  
...  
Keyword(s):  
Nitroxyl Radical ◽  
Aqueous Media ◽  
Ion Pairing ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Self Assembled

Role of Ion Pairing in Double-Layer Effects at Self-Assembled Monolayers Containing a Simple Redox Couple

1997 ◽  
Vol 101 (15) ◽  
pp. 2884-2894 ◽  
Author(s):  
Rafael Andreu ◽  
Juan Jose Calvente ◽  
W. Ronald Fawcett ◽  
Miguel Molero
Keyword(s):  
Double Layer ◽  
Ion Pairing ◽  
Redox Couple ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Self Assembled
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