Chirality Driven Metallic versus Semiconducting Behavior in a Complete Series of Radical Cation Salts Based on Dimethyl-Ethylenedithio-Tetrathiafulvalene (DM-EDT-TTF)

2013 ◽  
Vol 135 (45) ◽  
pp. 17176-17186 ◽  
Author(s):  
Flavia Pop ◽  
Pascale Auban-Senzier ◽  
Arkadiusz Frąckowiak ◽  
Krzysztof Ptaszyński ◽  
Iwona Olejniczak ◽  
...  
Keyword(s):  
Radical Cation ◽  
Complete Series ◽  
Radical Cation Salts ◽  
Semiconducting Behavior

scholarly journals New Radical Cation Salts Based on BDH-TTP Donor: Two Stable Molecular Metals with a Magnetic [ReF6]2− Anion and a Semiconductor with a [ReO4]− Anion

2021 ◽  
Vol 7 (4) ◽  
pp. 54
Author(s):  
Nataliya D. Kushch ◽  
Gennady V. Shilov ◽  
Lev I. Buravov ◽  
Eduard B. Yagubskii ◽  
Vladimir N. Zverev ◽  
...  
Keyword(s):  
Radical Cation ◽  
Low Temperatures ◽  
Ac Susceptibility ◽  
Slow Relaxation ◽  
Organic Radical ◽  
Inorganic Anion ◽  
Distinctive Features ◽  
Metallic Character ◽  
Radical Cation Salts ◽  
Partial Population

Three radical cation salts of BDH-TTP with the paramagnetic [ReF6]2− and diamagnetic [ReO4]− anions have been synthesized: κ-(BDH-TTP)4ReF6 (1), κ-(BDH-TTP)4ReF6·4.8H2O (2) and pseudo-κ″-(BDH-TTP)3(ReO4)2 (3). The crystal and band structures, as well as the conducting properties of the salts, have been studied. The structures of the three salts are layered and characterized by alternating κ-(1, 2) and κ″-(3) type organic radical cation layers with inorganic anion sheets. Similar to other κ-salts, the conducting layers in the crystals of 1 and 2 are formed by BDH-TTP dimers. The partial population of positions of Re atoms and disorder in the anionic layers of 1–3 are their distinctive features. Compounds 1 and 2 show the metallic character of conductivity down to low temperatures, while 3 is a semiconductor. The ac susceptibility of crystals 1 was investigated in order to test the possible slow relaxation of magnetization associated with the [ReF6]2− anion.

ChemInform Abstract: Tetrathiafulvalene-Based Radical Cation Salts with Transition Metal Bis(dicarbollide) Anions

ChemInform ◽  
2016 ◽  
Vol 47 (11) ◽  
pp. no-no
Author(s):  
Vladimir I. Bregadze ◽  
Oleg A. Dyachenko ◽  
Olga N. Kazheva ◽  
Andrey V. Kravchenko ◽  
Igor B. Sivaev ◽  
...  
Keyword(s):  
Transition Metal ◽  
Radical Cation ◽  
Radical Cation Salts

Molecular metals based on radical cation salts of ET and some its analogues with the photochromic nitroprusside anion, [Fe(CN)5NO]2−

1999 ◽  
Vol 102 (1-3) ◽  
pp. 1646-1649 ◽  
Author(s):  
L. Kushch ◽  
L. Buravov ◽  
V. Tkacheva ◽  
E. Yagubskii ◽  
L. Zorina ◽  
...  
Keyword(s):  
Radical Cation ◽  
Radical Cation Salts ◽  
Nitroprusside Anion
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